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    • 8. 发明授权
    • Hydrogel-forming polymer compositions for use in absorbent structures
    • 用于吸收结构的形成水凝胶的聚合物组合物
    • US4654039A
    • 1987-03-31
    • US746152
    • 1985-06-18
    • Kerryn A. BrandtStephen A. GoldmanThomas A. Inglin
    • Kerryn A. BrandtStephen A. GoldmanThomas A. Inglin
    • A61F13/15A61F13/472A61F13/49A61F13/53A61L15/60B01D15/00C08F8/44C08F20/52C08F220/58C08L33/00C08L33/02C08L77/00A61F13/16
    • A61F13/53A61L15/60Y10S526/93
    • The present invention relates to improved hydrogel-forming polymer compositions which can be used as absorbents in absorbent structures and absorbent articles such as diapers, sanitary napkins and the like. Such hydrogel-forming polymer compositions are substantially water-insoluble, slightly cross-linked, partially neutralized polymers which are prepared from unsaturated polymerizable, acid group-containing monomers and cross-linking agents. These hydrogel-forming polymer materials, upon imbibing fluids, form hydrogels. Such polymer materials have relatively high gel volume and relatively high gel strength as measured by shear modulus of the hydrogel which forms therefrom. Such polymer materials also contain relatively low levels of extractable polymer material which can be extracted therefrom by contact with synthetic urine. Preferred hydrogel-forming polymers having these characteristics can be prepared by polymerizing the acid group-containing monomers in their free acid form at relatively low monomer concentrations, preferably using relatively low polymerization temperatures. Absorbent structures and absorbent articles containing these dried hydrogel-forming polymer materials are also disclosed.
    • 本发明涉及可用作吸收结构中的吸收剂和诸如尿布,卫生巾等吸收制品的改进的水凝胶形成聚合物组合物。 这种形成水凝胶的聚合物组合物是由不饱和可聚合的含酸基团的单体和交联剂制备的基本上不溶于水的,轻微交联的部分中和的聚合物。 这些形成水凝胶的聚合物材料在吸入流体时形成水凝胶。 这样的聚合物材料具有相对较高的凝胶体积和相对高的凝胶强度,其通过由其形成的水凝胶的剪切模量来测量。 这种聚合物材料还含有相对低水平的可提取聚合物材料,其可以通过与合成尿接触而从其中提取。 具有这些特征的优选的形成水凝胶的聚合物可以通过以相对低的单体浓度聚合含游离酸形式的含酸基团的单体,优选使用相对低的聚合温度来制备。 还公开了含有这些干燥的水凝胶形成聚合物材料的吸收结构和吸收制品。