专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US08598248B2 Flexible polyurethane foams made from alkoxylated natural oil 有权
标题翻译：由烷氧基化天然油制成的柔性聚氨酯泡沫
公开(公告)号：US08598248B2
公开(公告)日：2013-12-03
申请号：US12837561
申请日：2010-07-16
申请人： Stanley L. Hager , Edward P. Browne , Jack R. Reese , Don S. Wardius , Micah N. Moore
发明人： Stanley L. Hager , Edward P. Browne , Jack R. Reese , Don S. Wardius , Micah N. Moore
IPC分类号： C08G18/00
CPC分类号： C08J9/04 , C08G18/4812 , C08G18/4866 , C08G18/4891 , C08G2101/0008 , C08G2101/0083 , C08J2205/06 , C08J2375/04
摘要： The present invention provides flexible conventional polyurethane foams made from at least one polyisocyanate and at least one vegetable oil alkoxylated in the presence of a double metal cyanide (DMC) catalyst, optionally at least one non-vegetable oil-based polyol, generally in the presence of a blowing agent and optionally in the presence of a surfactant, pigment, flame retardant, catalyst or filler. The alkoxylated natural oil must have (a) an ethylene oxide content in the alkoxylated segment greater than 20% by weight, (b) a primary hydroxyl group content of at least 10%, with the sum of (a)+(b) being at least 30% but no greater than 60%, The alkoxylated natural oils are environmentally-friendly, bio-based polyols which can be used to increase the “green” content of polyurethane foams without having detrimental effects on foam properties.
摘要翻译：本发明提供由至少一种多异氰酸酯制成的柔性常规聚氨酯泡沫和至少一种在双金属氰化物（DMC）催化剂，任选的至少一种非植物油基多元醇存在下烷氧基化的植物油，通常在存在下的发泡剂，并且任选地在表面活性剂，颜料，阻燃剂，催化剂或填料的存在下。烷氧基化天然油必须具有（a）烷氧基化链段中的环氧乙烷含量大于20重量％，（b）伯羟基含量至少为10％，（a）+（b）之和为至少30％但不大于60％。烷氧基化天然油是环保的生物基多元醇，其可用于增加聚氨酯泡沫的“绿色”含量，而不会对泡沫性质产生不利影响。

2. 发明申请

US20120016048A1 FLEXIBLE POLYURETHANE FOAMS MADE FROM ALKOXYLATED NATURAL OIL 有权
标题翻译：来自烷基天然油的柔性聚氨酯泡沫
公开(公告)号：US20120016048A1
公开(公告)日：2012-01-19
申请号：US12837561
申请日：2010-07-16
申请人： Stanley L. Hager , Edward P. Browne , Jack R. Reese , Don S. Wardius , Micah N. Moore
发明人： Stanley L. Hager , Edward P. Browne , Jack R. Reese , Don S. Wardius , Micah N. Moore
IPC分类号： C08J9/04 , C08L75/04
CPC分类号： C08J9/04 , C08G18/4812 , C08G18/4866 , C08G18/4891 , C08G2101/0008 , C08G2101/0083 , C08J2205/06 , C08J2375/04
摘要： The present invention provides flexible conventional polyurethane foams made from at least one polyisocyanate and at least one vegetable oil alkoxylated in the presence of a double metal cyanide (DMC) catalyst, optionally at least one non-vegetable oil-based polyol, generally in the presence of a blowing agent and optionally in the presence of a surfactant, pigment, flame retardant, catalyst or filler. The alkoxylated natural oil must have (a) an ethylene oxide content in the alkoxylated segment greater than 20% by weight, (b) a primary hydroxyl group content of at least 10%, with the sum of (a)+(b) being at least 30% but no greater than 60%, The alkoxylated natural oils are environmentally-friendly, bio-based polyols which can be used to increase the “green” content of polyurethane foams without having detrimental effects on foam properties.
摘要翻译：本发明提供由至少一种多异氰酸酯制成的柔性常规聚氨酯泡沫和至少一种在双金属氰化物（DMC）催化剂，任选的至少一种非植物油基多元醇存在下烷氧基化的植物油，通常在存在下的发泡剂，并且任选地在表面活性剂，颜料，阻燃剂，催化剂或填料的存在下。烷氧基化天然油必须具有（a）烷氧基化链段中的环氧乙烷含量大于20重量％，（b）伯羟基含量至少为10％，（a）+（b）之和为至少30％但不大于60％。烷氧基化天然油是环保的生物基多元醇，其可用于增加聚氨酯泡沫的“绿色”含量，而不会对泡沫性质产生不利影响。

3. 发明授权

US07323605B2 Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters 有权
标题翻译：来自含硼起始剂的双金属氰化物催化的低不饱和聚醚
公开(公告)号：US07323605B2
公开(公告)日：2008-01-29
申请号：US11270100
申请日：2005-11-09
申请人： Jose F. Pazos , Kenneth G. McDaniel , Edward P. Browne , George G. Combs , Don S. Wardius
发明人： Jose F. Pazos , Kenneth G. McDaniel , Edward P. Browne , George G. Combs , Don S. Wardius
IPC分类号： C07C41/03
CPC分类号： C08G65/2639 , C08G18/283 , C08G65/2606 , C08G65/2663 , C10L1/1985
摘要： The present invention provides a process for the double metal cyanide (DMC)-catalyzed production of low unsaturation polyethers from boron-containing starters. The polyethers produced by the inventive process may be reacted with one or more isocyanates to provide polyurethane products including coatings, adhesives, sealants, elastomers, foams and the like. The inventive process may be used to prepare fuel additives from C9-C30 boron-containing polyethers, more particularly from C13 alcohols.
摘要翻译：本发明提供了一种双金属氰化物（DMC）催化从含硼起始剂生产低不饱和聚醚的方法。通过本发明方法制备的聚醚可以与一种或多种异氰酸酯反应以提供包括涂料，粘合剂，密封剂，弹性体，泡沫等的聚氨酯产品。本发明的方法可以用于从C 9 -C 30 - 含硼聚醚，更特别是C 13-30醇制备燃料添加剂。

4. 发明申请

US20080021191A1 High water content tolerant process for the production of polyethers 审中-公开
标题翻译：用于生产聚醚的高耐水含量方法
公开(公告)号：US20080021191A1
公开(公告)日：2008-01-24
申请号：US11490303
申请日：2006-07-20
申请人： Jack R. Reese , Edward P. Browne , Jose F. Pazos
发明人： Jack R. Reese , Edward P. Browne , Jose F. Pazos
IPC分类号： C08G18/00
CPC分类号： C08G18/4866 , C08G65/2663 , C08G65/2696
摘要： The present invention provides a process for the production of a polyether involving establishing oxyalkylation conditions in an oxyalkylation reactor in the presence of from about 5 ppm to about 1,000 ppm, based on the final polyether weight, of a double metal cyanide (DMC) catalyst, continuously introducing into the reactor at least one alkylene oxide and a low molecular weight starter having a number average molecular weight of less than about 300 Daltons (Da) containing from about 200 ppm to about 5,000 ppm water and acidified with from about 10 ppm to about 2,000 ppm of at least one of an inorganic protic mineral acid and an organic acid, and recovering a polyether product having a number average molecular weight of from about 200 Da to about 4,000 Da, wherein the ppm (parts per million) of water and acid are based on the weight of the low molecular weight starter. The inventive process may allow for the use of low molecular weight starters containing higher levels of water at lower DMC catalyst levels than current processes.
摘要翻译：本发明提供了一种制备聚醚的方法，包括在烷氧基化反应器中，在最终的聚醚重量为约5ppm至约1,000ppm的情况下，制备双金属氰化物（DMC）催化剂，连续向反应器中引入至少一种数均分子量小于约300道尔顿（Da）的环氧烷和低分子量起始物，其含有约200ppm至约5,000ppm的水并用约10ppm至约 2,000ppm的无机质子性无机酸和有机酸中的至少一种，并回收数均分子量为约200Da至约4,000Da的聚醚产物，其中ppm（ppm / ppm）的水和酸基于低分子量起始物的重量。本发明的方法可以允许使用含有比当前方法更低的DMC催化剂水平的较高水平的水的低分子量起动器。

5. 发明申请

US20100234647A1 STARTER FEED STREAM ACIDIFICATION IN DMC-CATALYZED PROCESS 有权
标题翻译： DMC催化过程中起动机进料流化学反应
公开(公告)号：US20100234647A1
公开(公告)日：2010-09-16
申请号：US12786628
申请日：2010-05-25
申请人： Edward P. Browne
发明人： Edward P. Browne
IPC分类号： C07C41/01
CPC分类号： C08G65/2696 , B01J27/26 , C08G65/2663
摘要： The process of the present invention provides for the manufacture of lower molecular weight DMC-catalyzed polyols than is possible using non-acidified continuous addition of starter (CAOS) feeds, by adding excess acid to a starter feed stream over that required for mere neutralization of the basicity of the starter. The benefits of the invention also extend to starters which do not contain basicity. Polyether polyols made by the inventive process may be used to produce improved polyurethane products such as coatings, adhesives, sealants, elastomers, foams and the like.
摘要翻译：本发明的方法提供了比使用非酸化连续添加起动剂（CAOS）进料可能制备低分子量DMC-催化的多元醇，通过向起始物原料流中加入过量的酸，超过纯中和所需的起始者的基本性。本发明的优点还扩展到不包含碱性的起动器。通过本发明方法制备的聚醚多元醇可用于生产改进的聚氨酯产品，例如涂料，粘合剂，密封剂，弹性体，泡沫等。

6. 发明申请

US20100324340A1 SHORT CHAIN POLYETHER POLYOLS PREPARED FROM ULTRA-LOW WATER-CONTENT STARTERS VIA DMC CATALYSIS 审中-公开
标题翻译：通过DMC催化分析从超低水含量起动器制备的短链聚醚多元醇
公开(公告)号：US20100324340A1
公开(公告)日：2010-12-23
申请号：US12489522
申请日：2009-06-23
申请人： Jose F. Pazos , Edward P. Browne , Anthony Loveday
发明人： Jose F. Pazos , Edward P. Browne , Anthony Loveday
IPC分类号： C07C43/10 , C07C41/03
CPC分类号： C08G65/2663 , C08G65/2696
摘要： The present invention provides a process for the polyoxyalkylation of a starter involving establishing oxyalkylation conditions in an oxyalkylation reactor in the presence of a double metal cyanide (DMC) catalyst, continuously introducing into the reactor at least one alkylene oxide and an acidified, ultra-low water content starter, in which the starter contains greater than about 100 ppm and less than or equal to about 500 ppm water, based on the weight of the starter, and recovering an oxyalkylated low molecular weight starter polyether product. The inventive process allows the production of short chain polyether polyols which have hydroxyl numbers of from greater than 250 up to about 500, from hygroscopic initiators, such as glycerin, without DMC catalyst deactivation.
摘要翻译：本发明提供了一种引发剂的聚氧化烷基化方法，其涉及在双重金属氰化物（DMC）催化剂的存在下在烷氧基化反应器中建立烷氧基化条件，连续向反应器中引入至少一种烯化氧和酸化的超低水含量起动器，其中起动器基于起动器的重量包含大于约100ppm且小于或等于约500ppm的水，并且回收烷氧基化的低分子量引发剂聚醚产物。本发明的方法允许生产具有大于250至约500的羟值的短链聚醚多元醇，来自吸湿性引发剂如甘油，没有DMC催化剂失活。

7. 发明授权

US07001634B2 Process for suppressing the foaming of an aqueous system 有权
标题翻译：抑制水性体系发泡的方法
公开(公告)号：US07001634B2
公开(公告)日：2006-02-21
申请号：US10289579
申请日：2002-11-07
申请人： Edward P. Browne
发明人： Edward P. Browne
IPC分类号： A23L1/03
CPC分类号： B01D19/0404
摘要： The present invention relates to a process for suppressing the foaming of an aqueous system which involves combining water and at least one defoamer composition which has a hydroxyl equivalent molecular weight of at least 4000 Da and a cloud point less than or equal to 30° C. in 1% aqueous solution.The high hydroxyl equivalent molecular weight defoamers of the present invention exhibit excellent defoaming properties at a low cloud point. Additionally, defoamers of the present invention exhibit defoaming properties which are better than those of defoamers having the same cloud point which are based on polyoxyalkylene copolymers prepared in the presence of potassium hydroxide.The superior defoaming properties of the defoamers of the present invention are particularly useful in the manufacture or processing of food items.
摘要翻译：本发明涉及一种抑制含水体系发泡的方法，该方法包括将水和至少一种具有至少4000Da的羟基当量分子量和浊点小于或等于30℃的消泡剂组合物组合。在1％水溶液中。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式