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    • 2. 发明授权
    • Photographic compounds
    • 摄影化合物
    • US4946964A
    • 1990-08-07
    • US131911
    • 1987-12-11
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • C07D257/04G03C7/305G03C8/00
    • C07D257/04G03C7/30511G03C8/00Y02P20/55
    • There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound represented by the formula ##STR1## wherein R is --OH, --OR.sub.4, --NH.sub.2 --NHR.sub.5 or --NR.sub.4 R.sub.6 ; R.sub.1 is hydrogen, --NH.sub.2, alkyl, substituted alkyl, aryl or substituted aryl; R.sub.2 and R.sub.3 each independently is hydrogen, alkyl, aralkyl or aryl; R.sub.4 is a protecting group which can be removed in the presence of a base; R.sub.5 is an activating group which can render the neighboring hydrogen atom acidic; R.sub.6 is an electron withdrawing group which is capable of stabilizing the negative charge on the nitrogen atom which is produced upon removal of R.sub.4 upon contact with alkali; and PHOTO is a photographically useful group.The compounds provide controlled release of the photographically useful group by a base-catalyzed elimination when contacted by the aqueous alkaline processing composition.
    • 描述了一种摄影系统,其中用碱性照相显影组合物水溶液曝光的感光元件的显影是在下式表示的化合物的存在下进行:其中R是-OH,-OR4,-NH2-NHR5或 - NR4R6; R 1是氢,-NH 2,烷基,取代的烷基,芳基或取代的芳基; R2和R3各自独立地是氢,烷基,芳烷基或芳基; R4是可以在碱存在下除去的保护基; R5是可使相邻氢原子呈酸性的活化基团; R6是能够稳定在与碱接触时除去R4时产生的氮原子上的负电荷的吸电子基团; 而PHOTO是一个摄影有用的组。 当通过碱性水溶液处理组合物接触时,这些化合物通过碱催化消除提供对照相有用基团的控制释放。
    • 6. 发明授权
    • Heat and radiation-sensitive imaging medium, and processes for use thereof
    • 热和辐射敏感成像介质及其使用方法
    • US06258505B1
    • 2001-07-10
    • US09518045
    • 2000-03-02
    • Jayprakash C. BhattDaoshen BiF. Richard CottrellRong C. LiangWilliam C. SchwarzelTung F. Yeh
    • Jayprakash C. BhattDaoshen BiF. Richard CottrellRong C. LiangWilliam C. SchwarzelTung F. Yeh
    • G03F7021
    • B41M5/34B41M5/30
    • An imaging medium comprises a substrate carrying a color-change layer. This color-change layer comprises two layers or phases comprising two color-forming reagents which react upon heating to cause a change in the color of the layer. The color-change layer is deactivated by exposure to actinic radiation such that after deactivation it no longer undergoes its thermal color-change. The color-change layer is detachable from the substrate by heating to a temperature lower than required to cause the color change, so that upon contact of the imaging medium with a receiving sheet each individual pixel of the color-change layer may be left attached to the substrate, transferred to the receiving sheet but left uncolored, or transferred to the receiving sheet and colored to a color level determined by the energy used in the associated thermal print head element. The medium may be imaged by imagewise heating, followed by blanket exposure to deactivating actinic radiation, or by imagewise exposure to the actinic radiation, followed by heating of the whole color-change layer.
    • 成像介质包括承载着色层的基板。 该变色层包括两层或两层,包括两种成色试剂,其在加热时反应以引起层的颜色变化。 通过暴露于光化辐射来使变色层失活,使得在去激活之后它不再经受其热变色。 变色层通过加热到低于引起颜色变化所需的温度的温度而与基板分离,使得当成像介质与接收片接触时,可以将变色层的每个像素附着到 将基底转移到接收片材上,但保持未着色,或转移到接收片材并着色至由相关热敏打印头元件中使用的能量确定的色彩水平。 介质可以通过图像加热成像,然后通过毯式曝光去活化光化辐射,或通过成像曝光于光化辐射,然后加热整个颜色变化层来成像。
    • 7. 发明授权
    • Low-volatility, substituted 2-phenyl-4,6-bis (halomethyl)-1,3,5-triazine
for lithographic printing plates
    • 用于平版印刷版的低挥发性取代的2-苯基-4,6-双(卤代甲基)-1,3,5-三嗪
    • US5561029A
    • 1996-10-01
    • US430461
    • 1995-04-28
    • Maurice J. FitzgeraldFrederick R. KearneyRong-Chang LiangWilliam C. SchwarzelDonna J. GuarreraJohn M. HardinJohn C. Warner
    • Maurice J. FitzgeraldFrederick R. KearneyRong-Chang LiangWilliam C. SchwarzelDonna J. GuarreraJohn M. HardinJohn C. Warner
    • C08F2/44C08F2/50G03F7/028G03F7/029G03F7/031
    • G03F7/0295Y10S430/12Y10S430/121Y10S430/127
    • The present invention sets forth the incorporation of a substituted 2-phenyl-4,6-bis (trichloromethyl)-1,3,5-triazine in photoresists of lithographic printing plates for the purpose of promoting their shelf-life, room light stability, and developability. The present invention provides a photocurable composition comprising at least a photopolymerizable ethylenically unsaturated monomer having at least one terminal ethylenic group and capable of forming a polymer upon exposure to actinic radiation; and an s-triazine capable of initiating free radical polymerization of the photopolymerizable ethylenically unsaturated monomer and being represented by the following general formula [I]: ##STR1## wherein R.sub.1 is either OR.sub.4 or NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 may or may not be identical with each other, either R.sub.5 or R.sub.6 may represent hydrogen, and wherein R.sub.4 and at least one of R.sub.5 and R.sub.6 represent a ballast group capable of preventing the substantial volatilization of the s-triazine from the photoresist composition, the ballast group being a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, the substituted or unsubstituted alkyl group having at least 4 carbon atoms, the substituted or unsubstituted aryl group having at least 6 carbon atoms; R.sub.2 and R.sub.3 may or may not be identical with each other and each represent hydrogen, halogen, phenyl, a substituted or unsubstituted alkyl group, or an alkoxyl group; X and Y may or may not be identical with each other and each represent chlorine or bromine; and m and n may or may not be identical with each other and are each an integer of 0, 1, or 2. Desirable compositions will further comprise at least one photooxidizable leuco triarylmethane dye.
    • 本发明阐述了取代的2-苯基-4,6-双(三氯甲基)-1,3,5-三嗪在平版印刷版的光致抗蚀剂中的引入,以促进其保质期,室内光稳定性, 和可开发性。 本发明提供一种可光固化组合物,其包含至少一种具有至少一个末端烯属基并可在暴露于光化辐射时形成聚合物的可光聚合的烯属不饱和单体; 和能够引发可光聚合的烯键式不饱和单体的自由基聚合并由以下通式[I]表示的均三嗪:其中R 5或R 6可以彼此相同或不同,R 5或R 6可以 表示氢,并且其中R 4和R 5和R 6中的至少一个表示能够防止光刻胶组合物中s-三嗪显着挥发的压载基团,该镇流基为取代或未取代的烷基,或取代或未取代的 具有至少4个碳原子的取代或未取代的烷基,取代或未取代的具有至少6个碳原子的芳基; R 2和R 3可以彼此相同或不同,分别代表氢,卤素,苯基,取代或未取代的烷基或烷氧基; X和Y可以相同也可以不相同,分别表示氯或溴; 并且m和n可以彼此相同也可以不相同,并且各自为0,1或2的整数。期望的组合物还将包含至少一种可光氧化的无色三芳基甲烷染料。
    • 8. 发明授权
    • Heat and radiation-sensitive imaging medium, and processes for use
thereof
    • 热和辐射敏感成像介质及其使用方法
    • US6054246A
    • 2000-04-25
    • US108624
    • 1998-07-01
    • Jayprakash C. BhattDaoshen BiF. Richard CottrellRong C. LiangWilliam C. SchwarzelTung F. Yeh
    • Jayprakash C. BhattDaoshen BiF. Richard CottrellRong C. LiangWilliam C. SchwarzelTung F. Yeh
    • B41M5/323B41M5/30B41M5/34B41M5/382G03C5/18
    • B41M5/34B41M5/30
    • An imaging medium comprises a substrate carrying a color-change layer. This color-change layer comprises two layers or phases comprising two color-forming reagents which react upon heating to cause a change in the color of the layer. The color-change layer is deactivated by exposure to actinic radiation such that after deactivation it no longer undergoes its thermal color-change. The color-change layer is detachable from the substrate by heating to a temperature lower than required to cause the color change, so that upon contact of the imaging medium with a receiving sheet each individual pixel of the color-change layer may be left attached to the substrate, transferred to the receiving sheet but left uncolored, or transferred to the receiving sheet and colored to a color level determined by the energy used in the associated thermal print head element. The medium may be imaged by imagewise heating, followed by blanket exposure to deactivating actinic radiation, or by imagewise exposure to the actinic radiation, followed by heating of the whole color-change layer.
    • 成像介质包括承载着色层的基板。 该变色层包括两层或两层,包括两种成色试剂,其在加热时反应以引起层的颜色变化。 通过暴露于光化辐射来使变色层失活,使得在去激活之后它不再经受其热变色。 变色层通过加热到低于引起颜色变化所需的温度的温度而与基板分离,使得当成像介质与接收片接触时,可以将变色层的每个像素附着到 将基底转移到接收片材上,但保持未着色,或转移到接收片材并着色至由相关热敏打印头元件中使用的能量确定的色彩水平。 介质可以通过图像加热成像,然后通过毯式曝光去活化光化辐射,或通过成像曝光于光化辐射,然后加热整个颜色变化层来成像。