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    • 1. 发明授权
    • Photographic compounds
    • 摄影化合物
    • US4946964A
    • 1990-08-07
    • US131911
    • 1987-12-11
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • C07D257/04G03C7/305G03C8/00
    • C07D257/04G03C7/30511G03C8/00Y02P20/55
    • There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound represented by the formula ##STR1## wherein R is --OH, --OR.sub.4, --NH.sub.2 --NHR.sub.5 or --NR.sub.4 R.sub.6 ; R.sub.1 is hydrogen, --NH.sub.2, alkyl, substituted alkyl, aryl or substituted aryl; R.sub.2 and R.sub.3 each independently is hydrogen, alkyl, aralkyl or aryl; R.sub.4 is a protecting group which can be removed in the presence of a base; R.sub.5 is an activating group which can render the neighboring hydrogen atom acidic; R.sub.6 is an electron withdrawing group which is capable of stabilizing the negative charge on the nitrogen atom which is produced upon removal of R.sub.4 upon contact with alkali; and PHOTO is a photographically useful group.The compounds provide controlled release of the photographically useful group by a base-catalyzed elimination when contacted by the aqueous alkaline processing composition.
    • 描述了一种摄影系统,其中用碱性照相显影组合物水溶液曝光的感光元件的显影是在下式表示的化合物的存在下进行:其中R是-OH,-OR4,-NH2-NHR5或 - NR4R6; R 1是氢,-NH 2,烷基,取代的烷基,芳基或取代的芳基; R2和R3各自独立地是氢,烷基,芳烷基或芳基; R4是可以在碱存在下除去的保护基; R5是可使相邻氢原子呈酸性的活化基团; R6是能够稳定在与碱接触时除去R4时产生的氮原子上的负电荷的吸电子基团; 而PHOTO是一个摄影有用的组。 当通过碱性水溶液处理组合物接触时,这些化合物通过碱催化消除提供对照相有用基团的控制释放。