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    • 2. 发明授权
    • Sintered metal bodies and manufacturing method therefor
    • 烧结金属体及其制造方法
    • US5427601A
    • 1995-06-27
    • US767889
    • 1991-09-30
    • Takashi HaradaYoshihiro FujiwaraFumio AbeTsuneaki OhashiHiroshige MizunoKevin R. BrundageSrinivas H. SwaroopDavid F. ThompsonRaja R. WusirikaDavid S. Weiss
    • Takashi HaradaYoshihiro FujiwaraFumio AbeTsuneaki OhashiHiroshige MizunoKevin R. BrundageSrinivas H. SwaroopDavid F. ThompsonRaja R. WusirikaDavid S. Weiss
    • B22F1/00B01D53/94B01J23/86B22F3/11B22F5/00C22C32/00C22C33/02C22C38/00C22C29/12B22F3/00
    • C22C32/0026B01D53/945B01J23/862C22C33/0285Y02T10/22Y10T428/12611
    • A sintered metal body is disclosed of composition consisting essentially of in weight percent about 5 to 40 Cr, about 2 to 30 Al, 0 to about 5 special metal, 0 to about 4 rare earth oxide additive, and the balance Fe group metal and unavoidable impurities,the composition including at least one component selected from component A and/or component B, component A being special metal, and component B being at least an effective amount of rare earth oxide additive,the special metal being a first special metal component, and optionally, a second special metal component when rare earth oxide additive is 0, the first special metal component consisting of at least one of: Y, lanthanides, Zr, Hf, Ti, Si, and B, and the second special metal component consisting of at least one of: alkaline earth metal, Cu, and Sn, and the special metal being a third special metal component when rare earth oxide additive is >0, the third special metal component consisting of at least one of Y, lanthanides, Zr, Hf, Ti, Si, alkaline earth metal, B, Cu, and Sn.The body is excellent in oxidation resistance at high temperatures, heat resistance, and corrosion resistance, and can be suitably used by itself as a carrier for catalysts, for exhaust gas purification, etc., or as a monolith catalyst comprising catalyst carrier and catalyst supported thereon, and as a heater or catalytic converter by providing electrodes on the body.
    • 公开了一种烧结金属体,其组成主要包括重量百分比约5至40 Cr,约2至30种Al,0至约5种特殊金属,0至约4种稀土氧化物添加剂,余量为Fe族金属,不可避免 杂质,所述组合物包含选自组分A和/或组分B中的至少一种组分,组分A为特殊金属,组分B为至少有效量的稀土氧化物添加剂,所述特殊金属为第一特殊金属组分, 以及任选地,当稀土氧化物添加剂为0时的第二特殊金属组分,所述第一特殊金属组分由以下中的至少一种组成:Y,镧系元素,Zr,Hf,Ti,Si和B,并且所述第二特殊金属组分 的碱土金属,Cu和Sn中的至少一种,当稀土氧化物添加剂为> 0时,特殊金属是第三种特殊金属组分,第三种特殊金属组分由Y,镧系元素,Zr中的至少一种组成 , H f,Ti,Si,碱土金属,B,Cu和Sn。 本体在高温下的耐氧化性,耐热性和耐腐蚀性优异,可以适合用作催化剂载体,废气净化等,或作为包含催化剂载体和催化剂的整料催化剂 以及作为加热器或催化转化器,通过在主体上设置电极。
    • 9. 发明授权
    • Thermally stable chromium-exchanged zeolites and method of making same
    • 热稳定的铬交换沸石及其制备方法
    • US5234876A
    • 1993-08-10
    • US963602
    • 1992-10-20
    • Srinivas H. SwaroopRaja R. Wusirika
    • Srinivas H. SwaroopRaja R. Wusirika
    • B01J29/072B01J29/14
    • B01J29/146B01J29/072
    • Thermally stable Cr-zeolites and Cu-Cr-zeolites, and methods of making same are disclosed. The zeolites have a SiO.sub.2 to Al.sub.2 O.sub.3 mole ratio of about 3 to about 200, and an initial alkali content of less than about about 0.5% by weight based on the alkali oxide. Chromium ions are exchanged into the zeolite to produce Cr-zeolite in which the Cr level is greater than about 0.5% by weight. Copper and chromium ions are provided exchanged on a zeolite to produce Cu-Cr-zeolite. The respective Cr-exchanged zeolites are heat-treated to produce the thermally stable zeolites wherein the BET surface area upon exposure to temperatures of up to about 1000.degree. C. is at least about 50% of the BET surface area of the respective thermally stable zeolites at about room temperature, prior to the exposure to temperatures of up to about 1000.degree. C.
    • 公开了热稳定的Cr-沸石和Cu-Cr-沸石及其制备方法。 沸石的SiO 2与Al 2 O 3摩尔比为约3至约200,初始碱含量小于约0.5重量%,基于碱金属氧化物。 将铬离子交换到沸石中以产生其中Cr含量大于约0.5重量%的Cr-沸石。 在沸石上交换铜和铬离子以产生Cu-Cr-沸石。 相应的Cr交换的沸石被热处理以产生热稳定的沸石,其中暴露于高达约1000℃的温度下的BET表面积为相应热稳定沸石的BET表面积的至少约50% 在约室温下,暴露于高达约1000℃的温度之前。