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1. 发明授权

US08206464B2 Blue polymeric hair dyes 有权
标题翻译：蓝色聚合染发剂
公开(公告)号：US08206464B2
公开(公告)日：2012-06-26
申请号：US12812781
申请日：2009-01-07
申请人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Fröhling
发明人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Fröhling
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： C09B69/10 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/101 , C09B69/106
摘要： Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了具有h = 210°至330°的色相值为h = 210°至330°的阳离子聚合物染料，其包含：a）聚合物主链，b）有机染料的残基，和c）任选无色的有机基团，其中（b）和（c）共价结合到聚合物主链（a），并且其中阳离子电荷可以独立地是染料或无色有机基团的一部分。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

2. 发明授权

US08097045B2 Polymeric hair dyes 有权
公开(公告)号：US08097045B2
公开(公告)日：2012-01-17
申请号：US12812778
申请日：2009-01-07
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Fröhling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Fröhling
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
摘要： Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

3. 发明授权

US07731761B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US07731761B2
公开(公告)日：2010-06-08
申请号：US12309300
申请日：2007-07-09
申请人： Sophie Marquais-Bienewald , Olof Wallquist , Christian Cremer , Beate Fröhling , Andreas Möck
发明人： Sophie Marquais-Bienewald , Olof Wallquist , Christian Cremer , Beate Fröhling , Andreas Möck
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： A61K8/84 , A61K8/8152 , A61K8/8158 , A61K8/86 , A61K8/898 , A61K2800/43 , A61K2800/5426 , A61K2800/57 , A61K2800/594 , A61Q5/02 , A61Q5/065 , A61Q5/12 , C09B69/105 , C09B69/106 , C09B69/107 , C09B69/109
摘要： Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1000; n is a number from O to 1000; and p is a number from 1 to 1000; wherein the sum of m+n+p≧3.
摘要翻译：公开了式（1a）的聚合染料; （1b）; 或（1c）; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-C1-C10亚烷基 - 的连接基团; -C 2 -C 12亚烯基 -C 5 -C 10环亚烷基 - C5-C10亚芳基 -C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ; -C（O） - ; - （CH 2 CH 2 -O）1-5-; -C（O）O-; -OCO-; -N（R 1） - ; -CON（R 1） - ; - （R1）NC（O） - ; -0-; -S-; -所以）-; -S（O）2 - ; -S（O）2 -N（R 1 R 2）; 或直接债券; R1和R2彼此独立地是氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2中的至少一个是有机染料的残基; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到1000的数字; n是从0到1000的数字; p是从1到1000的数字; 其中m + n +p≥3的和。

4. 发明申请

US20090255063A1 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US20090255063A1
公开(公告)日：2009-10-15
申请号：US12309300
申请日：2007-07-09
申请人： Sophie Marquais-Bienewald , Olof Wallquist , Christian Cremer , Beate Fröhling , Andreas Möck
发明人： Sophie Marquais-Bienewald , Olof Wallquist , Christian Cremer , Beate Fröhling , Andreas Möck
IPC分类号： A61K8/42 , A61Q5/10 , C08G73/04 , C08F283/12 , C08F283/04
CPC分类号： A61K8/84 , A61K8/8152 , A61K8/8158 , A61K8/86 , A61K8/898 , A61K2800/43 , A61K2800/5426 , A61K2800/57 , A61K2800/594 , A61Q5/02 , A61Q5/065 , A61Q5/12 , C09B69/105 , C09B69/106 , C09B69/107 , C09B69/109
摘要： Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1000; n is a number from O to 1000; and p is a number from 1 to 1000; wherein the sum of m+n+p≧3.
摘要翻译：公开了式（1a）的聚合染料; （1b）; 或（1c）; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-C1-C10亚烷基 - 的连接基团; -C 2 -C 12亚烯基 -C 5 -C 10环亚烷基 - C5-C10亚芳基 -C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ; -C（O） - ; - （CH 2 CH 2 -O）1-5-; -C（O）O-; -OCO-; -N（R 1） - ; -CON（R1） - ; - （R1）NC（O） - ; -0-; -S-; -所以）-; -S（O）2 - ; -S（O）2 -N（R 1 R 2）; 或直接债券; R1和R2彼此独立地是氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2中的至少一个是有机染料的残基; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到1000的数字; n是从0到1000的数字; p是从1到1000的数字; 其中m + n + p> = 3的和。

5. 发明授权

US08118883B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US08118883B2
公开(公告)日：2012-02-21
申请号：US12812785
申请日：2009-01-07
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Robert Hochberg
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Robert Hochberg
IPC分类号： A61Q5/10 , C07D213/09
CPC分类号： C09B69/106 , A61K8/4946 , A61K8/69 , A61K8/84 , A61K2800/57 , A61Q5/02 , A61Q5/065 , A61Q5/12
摘要： Disclosed are polymeric dyes obtained by the reaction of (a) a basic polycondensate with (b) an electrophilic dye of formula (2) P—X—Ya+ Ana+; wherein the basic polycondensate (a) is obtained by the reaction of (a1) an amine of formula (I) in the presence of an anhydrous solvent with an ammonium salt (a2) with a cyanamide: Wherein P, X, Y, a+, a, a1, a2, An, R1, R2, R3, R4, R5, R6 and A are defined in the claims and in the disclosure. The present invention also relates to compositions comprising these polymeric dyes, to a process for their use for dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides.
摘要翻译：公开了通过（a）碱性缩聚物与（b）式（2）的亲电子染料P-X-Ya + Ana +的反应获得的聚合染料; 其中碱性缩聚物（a）通过（a1）式（I）的胺在无水溶剂与铵盐（a2）的存在下与氨基氰反应而获得：其中P，X，Y，a +， a，a1，a2，an，R1，R2，R3，R4，R5，R6和A在权利要求书和本公开内容中定义。本发明还涉及包含这些聚合染料的组合物，其用于染色有机材料如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺的方法。

6. 发明申请

US20110107525A1 POLYMERIC HAIR DYES 有权
公开(公告)号：US20110107525A1
公开(公告)日：2011-05-12
申请号：US12812778
申请日：2009-01-07
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
IPC分类号： A61K8/89 , C08G73/04 , C08G77/38 , A61K8/84 , A61Q5/10
CPC分类号： C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
摘要： Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

7. 发明申请

US20110088173A1 POLYMERIC HAIR DYES 有权
公开(公告)号：US20110088173A1
公开(公告)日：2011-04-21
申请号：US12812785
申请日：2009-01-07
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Roberg Hochberg
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Roberg Hochberg
IPC分类号： A61K8/41 , A61Q5/10 , C09B44/16
CPC分类号： C09B69/106 , A61K8/4946 , A61K8/69 , A61K8/84 , A61K2800/57 , A61Q5/02 , A61Q5/065 , A61Q5/12
摘要： Disclosed are polymeric dyes obtained by the reaction of (a) a basic polycondensate with (b) an electrophilic dye of formula (2) P—X—Ya+ Ana−; wherein the basic polycondensate (a) is obtained by the reaction of (a1) an amine of formula (I) in the presence of an anhydrous solvent with an ammonium salt (a2) with a cyanamide; wherein R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl, which may be substituted by amino, hydroxy, cyano or C1-C4alkoxy; A is C2-C20alkylene, which may be substituted or interrupted by one or more than one hetero atoms; P is a reactive grouping capable of reacting with a nitrogen nucleophile; X is a linkage group selected from C1-C30alkylene, C2-C12alkenylene, C5-C10arylene, C5-C10cycloalkylene and C1-C10alkylene(C5-C10arylene) which may be interrupted and/or terminated at one or both ends by one or more than one —O—, —S—, —N═, —N(R5)—, —S(O)—, SO2, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OC(O)—, (II), —CON(R5)—, —C(NR5R6)2—, —(R5)NC(O)—, —C(S)R5— or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic bivalent radical optionally comprising at least one heteroatom; —O—; —S—; —N(R5)—; —S(O)—; —SO2—; —(CH2CH2—O)1-5—; —C(O)—; —C(O)O—, —OC(O)—; (III); —CON(R5)—; —SO2N(R5)—; —C(NR5R6)2—; —(R5)NC(O)—; —C(S)R5—; saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical optionally comprising at least one heteroatom; which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), halogen or hydroxy; or the direct bond; Y is a residue of an organic dye; R5 and R6 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted d-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); a is 1, 2 or 3; and An is an anion. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

8. 发明申请

US20110061179A1 BLUE POLYMERIC HAIR DYES 有权
标题翻译：蓝色聚合物染发剂
公开(公告)号：US20110061179A1
公开(公告)日：2011-03-17
申请号：US12812781
申请日：2009-01-07
申请人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Frohling
发明人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Frohling
IPC分类号： A61K8/81 , C08F8/34 , C08F8/30 , A61K8/84 , A61Q5/10
CPC分类号： C09B69/10 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/101 , C09B69/106
摘要： Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了具有h = 210°至330°的色相值为h = 210°至330°的阳离子聚合物染料，其包含：a）聚合物主链，b）有机染料的残基，和c）任选无色的有机基团，其中（b）和（c）共价结合到聚合物主链（a），并且其中阳离子电荷可以独立地是染料或无色有机基团的一部分。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

9. 发明授权

US08221508B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US08221508B2
公开(公告)日：2012-07-17
申请号：US13133234
申请日：2009-12-04
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Xian-Zhi Zhou , Barbara Wagner
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Xian-Zhi Zhou , Barbara Wagner
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： A61K8/64 , A61K8/645 , A61K8/65 , A61K2800/4322 , A61Q5/065 , C09B69/10 , C09B69/101 , C09B69/106
摘要： Polymeric dye comprising oligo and polypeptides selected from natural or synthetic aminoacids bearing at least one covalently bounded cationic dye. Very good dyeing results on human hair are obtained with these dyes.
摘要翻译：包含寡核苷酸和多肽的聚合染料选自具有至少一种共价结合阳离子染料的天然或合成氨基酸。用这些染料获得人毛发上的非常好的染色结果。

10. 发明授权

US08118882B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US08118882B2
公开(公告)日：2012-02-21
申请号：US12812782
申请日：2009-01-07
申请人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist
发明人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist
IPC分类号： A61Q5/10 , C07D213/09
CPC分类号： C09B69/101 , C09B1/32 , C09B1/34 , C09B69/106
摘要： Disclosed are cationic oligomeric dye, comprising a low molecular weight polyamine comprising the repeating units (1a) or (1b), wherein at least 90% of the polyamine molecules are selected from tetramines, pentamines and hexamines; and R is the residue of a cationic dye, which is covalently bonded, optionally via a linker, to the nitrogen atoms of the polyamine; or hydrogen; wherein the polyamine repeating units (1a) and (1b) comprise at least one carionic dye residue; and n is a number from 3-12. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了阳离子低聚染料，其包含包含重复单元（1a）或（1b）的低分子量多胺，其中至少90％的多胺分子选自四胺，五胺和六胺; 并且R是阳离子染料的残基，其任选地经由接头共价键合到多胺的氮原子上; 或氢; 其中所述多胺重复单元（1a）和（1b）包含至少一个卡莲染料残基; n是3-12的数字。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

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