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1. 发明授权

US07087546B2 Process for regenerating and rejuvenating additive-based catalysts 有权
公开(公告)号：US07087546B2
公开(公告)日：2006-08-08
申请号：US10289058
申请日：2002-11-06
申请人： Sonja Eijsbouts , Franciscus Wilhelmus Houtert , Marcel Adriaan Jansen , Tetsuro Kamo , Frans Lodewijk Plantenga
发明人： Sonja Eijsbouts , Franciscus Wilhelmus Houtert , Marcel Adriaan Jansen , Tetsuro Kamo , Frans Lodewijk Plantenga
IPC分类号： B01J20/34
CPC分类号： C10G45/08 , B01J21/04 , B01J23/94 , B01J31/0202 , B01J31/0204 , B01J31/0205 , B01J31/0237 , B01J31/0258 , B01J31/0271 , B01J31/06 , B01J31/1616 , B01J31/28 , B01J31/34 , B01J31/4015 , B01J31/403 , B01J31/4092 , B01J38/12 , B01J38/20 , B01J38/52 , B01J38/62 , B01J2231/641 , C10G45/04 , Y10S502/514
摘要： The present invention pertains to a process for regenerating and rejuvenating an additive-based hydrotreating catalyst containing Group VIB and Group VIII hydrogenation metals. The process comprises the steps of regenerating the catalyst by contacting it with an oxygen-containing gas at a maximum temperature of 500° C., followed by rejuvenating the catalyst by contacting it with an organic additive comprising an organic compound, other than a compound that the catalyst is contacted with in the course of its use as a catalyst prior to regeneration and rejuvenation. The organic additive is incorporated into the catalyst. If necessary, the catalyst may then be dried at such a temperature that at least 50% of the additive is maintained in the catalyst. The process according to the invention makes it possible to restore the activity of a used additive-based hydrotreating catalyst to its original level, or even to improve it to above that level.

2. 发明授权

US06635596B1 Process for regenerating additive-based catalysts 有权
标题翻译：再生添加剂催化剂的工艺
公开(公告)号：US06635596B1
公开(公告)日：2003-10-21
申请号：US09609126
申请日：2000-07-03
申请人： Sonja Eijsbouts , Franciscus Wilhelmus Houtert , Marcel Adriaan Jansen , Tetsuro Kamo , Frans Lodewijk Plantenga
发明人： Sonja Eijsbouts , Franciscus Wilhelmus Houtert , Marcel Adriaan Jansen , Tetsuro Kamo , Frans Lodewijk Plantenga
IPC分类号： B01J2034
CPC分类号： C10G45/08 , B01J21/04 , B01J23/94 , B01J31/0202 , B01J31/0204 , B01J31/0205 , B01J31/0237 , B01J31/0258 , B01J31/0271 , B01J31/06 , B01J31/1616 , B01J31/28 , B01J31/34 , B01J31/4015 , B01J31/403 , B01J31/4092 , B01J38/12 , B01J38/20 , B01J38/52 , B01J38/62 , B01J2231/641 , C10G45/04 , Y10S502/514
摘要： The present invention pertains to a process for regenerating a used additive-based catalyst comprising the step of regenerating the catalyst by contacting it with an oxygen-containing gas at a maximum temperature of 500° C. Preferably, the maximum catalyst temperature during the regeneration step is 300-500° C., more preferably 320-475° C., even more preferably 350-425° C. The regenerated additive-based catalyst obtained with the process according to the invention has a higher activity than an additive-based catalyst regenerated at a higher temperature. Additionally, its activity is also higher than that of a corresponding catalyst, which never contained an additive.
摘要翻译：本发明涉及再生使用的添加剂型催化剂的方法，其包括通过使催化剂与最高温度为500℃的含氧气体接触来再生催化剂的步骤。优选地，再生步骤期间的最大催化剂温度为300-500℃，更优选为320-475℃，甚至更优选为350-425℃。用本发明方法获得的再生添加剂基催化剂具有比添加剂催化剂更高的活性在较高温度下再生。另外，其活性也高于不含有添加剂的相应催化剂的活性。

3. 发明授权

US06753291B2 Process for sulfiding an additive-containing catalyst 有权
标题翻译：用于硫化含添加剂的催化剂的方法
公开(公告)号：US06753291B2
公开(公告)日：2004-06-22
申请号：US09829638
申请日：2001-04-10
申请人： Sonja Eijsbouts , Frans Lodewijk Plantenga , Pierre Dufresne , Franck Labruyere , Leendert Arie Gerritsen
发明人： Sonja Eijsbouts , Frans Lodewijk Plantenga , Pierre Dufresne , Franck Labruyere , Leendert Arie Gerritsen
IPC分类号： B01J2702
CPC分类号： B01J31/0254 , B01J23/85 , B01J27/188 , B01J31/0202 , B01J31/0205 , B01J31/0218 , B01J31/0237 , B01J37/20 , C10G45/08 , C10G2300/705
摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40%, preferably less than about 35%, more preferably less than about 25%, most preferably less than about 15%, of the sulfur present in the sulfided catalyst is added with the organic liquid. The process of the present invention makes it possible to use additive-containing catalysts without loss of activity in units which cannot effect gas phase start-up or are required to carry out a pressure test. The organic liquid may be a hydrocarbon with a boiling range of about 150-500° C., preferably gasoline, white spirit, diesel, gas oil, mineral lube oil, or white oil. The step of contacting the catalyst with hydrogen and a sulfur-containing compound may take place in one step at a temperature of about 150-450° C. It may also take place in two steps, with the first step being performed at a temperature which is lower than that of the second step, with the first step being carried out at a temperature of about 100-250° C. and the second step at a temperature of about 150-450° C.
摘要翻译：本发明涉及一种硫化催化剂组合物的方法，该催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族氢化金属组分和一种有机添加剂，其中催化剂组合物首先与有机液体接触，催化剂在气相中与氢气和含硫化合物接触，其中少于约40％，优选小于约35％，更优选小于约25％，最优选小于约15％的硫存在于硫化催化剂中的有机液体中加入。本发明的方法使得可以在不能实现气相启动或需要进行压力试验的单位中使用不含活性的添加剂的催化剂。有机液体可以是沸点为约150-500℃的烃，优选汽油，白酒，柴油，瓦斯油，矿物润滑油或白油。使催化剂与氢气和含硫化合物接触的步骤可以在约150-450℃的温度下在一个步骤中进行。它也可以在两个步骤中进行，第一步是在低于第二步骤，第一步骤在约100-250℃的温度下进行，第二步在约150-450℃的温度下进行。

4. 发明授权

US06566296B2 Process for preparing an additive-based mixed metal catalyst, its composition and use 有权
标题翻译：制备添加剂型混合金属催化剂的方法，其组成和用途
公开(公告)号：US06566296B2
公开(公告)日：2003-05-20
申请号：US09904316
申请日：2001-07-12
申请人： Frans Lodewijk Plantenga , Sonja Eijsbouts , Marinus Bruce Cerfontain
发明人： Frans Lodewijk Plantenga , Sonja Eijsbouts , Marinus Bruce Cerfontain
IPC分类号： B01J3100
CPC分类号： B01J23/8878 , B01J23/85 , B01J23/8885 , B01J31/0202 , B01J31/0209 , B01J31/04 , B01J37/0018 , B01J37/0236 , B01J37/03 , C10G45/08 , C10G49/04
摘要： The present invention pertains to a process for preparing a catalyst composition wherein at least one Group VIII non-noble metal component and at least two Group VIB metal components are combined and reacted in the presence of a protic liquid, after which the resulting composition is isolated and dried, the total of the Group VIII and Group VIB metal components, calculated as oxides, making up at least about 70 wt. % of the catalyst composition, calculated on dry weight. An organic oxygen-containing additive is added prior to, during, or subsequent to the combining and reacting of the metal components in such an amount that the molar ratio of the total amount of additive added to the total amount of Group VIII and Group VIB metal components is at least about 0.01. The invention also pertains to additive-containing catalysts obtained by this process, and to their use in hydroprocessing.
摘要翻译：本发明涉及一种制备催化剂组合物的方法，其中将至少一种第VIII族非贵金属组分和至少两种第VIB族金属组分在质子液体存在下合并并反应，然后将所得组合物分离并干燥，以氧化物计算的第VIII族和第VIB族金属组分的总和至少约70wt。催化剂组合物的％，按干重计算。在金属组分的组合和反应之前，期间或之后加入有机含氧添加剂，其量为加入的总添加量与VIII族和VIB族金属的总量的摩尔比组分至少约0.01。本发明还涉及通过该方法获得的含添加剂催化剂及其在加氢处理中的用途。

5. 发明授权

US06860987B2 Process for the hydroprocessing of hydrocarbon feedstocks 有权
标题翻译：烃原料加氢处理工艺
公开(公告)号：US06860987B2
公开(公告)日：2005-03-01
申请号：US10413870
申请日：2003-04-15
申请人： Frans Lodewijk Plantenga , Sonja Eijsbouts , Marinus Bruce Cerfontain
发明人： Frans Lodewijk Plantenga , Sonja Eijsbouts , Marinus Bruce Cerfontain
IPC分类号： B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J31/02 , B01J31/04 , B01J37/00 , B01J37/02 , B01J37/03 , C10G45/08 , C10G49/04 , C10G45/04 , C07C5/02 , C07C5/10 , C07C5/22 , C10G47/02
CPC分类号： B01J23/8878 , B01J23/85 , B01J23/8885 , B01J31/0202 , B01J31/0209 , B01J31/04 , B01J37/0018 , B01J37/0236 , B01J37/03 , C10G45/08 , C10G49/04
摘要： The present invention pertains to a process for the hydroprocessing of hydrocarbon feedstocks wherein said hydrocarbon feedstocks are contacted, at hydroprocessing conditions, with a catalyst composition comprising at least one Group VIII non-noble metal component and at least two Group VIB metal components. The catalyst composition further comprises at least about 0.01 mole of an organic oxygen-containing additive per mole of the total of Group VIB metals and Group VIII non-noble metals present in the catalyst composition. The total of the Group VIII and Group VIB metal components, calculated as oxides, make up at least about 50 wt. % of the catalyst composition, calculated on dry weight.
摘要翻译：本发明涉及烃原料的加氢处理方法，其中所述烃原料在加氢处理条件下与包含至少一种第八族非贵金属组分和至少两种VIB族金属组分的催化剂组合物接触。催化剂组合物还包含每摩尔催化剂组合物中存在的VIB族金属和VIII族非贵金属的总量至少约0.01摩尔的有机含氧添加剂。以氧化物计算的VIII族和VIB族金属组分的总和至少约为50重量％催化剂组合物的％，按干重计算。

6. 发明授权

US09701594B2 Hydrodeoxygenation of pyrolysis oil in presence of admixed alcohol 有权
公开(公告)号：US09701594B2
公开(公告)日：2017-07-11
申请号：US13883089
申请日：2011-08-30
申请人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Pronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenwinkel
发明人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Pronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenwinkel
IPC分类号： C07C1/22 , C10G3/00 , B01J37/20 , B01J23/85 , B01J23/883
CPC分类号： C07C1/22 , B01J23/85 , B01J23/883 , B01J37/20 , C10G3/46 , C10G3/50 , C10G2300/4006 , C10G2300/4081 , C10G2300/42 , Y02P30/20
摘要： The present invention relates to the hydrodeoxygenation of pyrolysis oils in the presence of an alcohol.

7. 发明申请

US20110319505A1 BULK SULFIDIC MIXED METAL CATALYST AND METHODS FOR ITS MANUFACTURE AND USE IN CONVERTING SYNGAS TO ALCOHOL 有权
标题翻译：大容量硫化金属催化剂及其制造方法及其在酒精转化中的应用
公开(公告)号：US20110319505A1
公开(公告)日：2011-12-29
申请号：US13203845
申请日：2010-03-05
申请人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
发明人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
IPC分类号： C07C27/00 , B01J27/051
CPC分类号： B01J27/0515 , B01J23/8872 , B01J37/0009 , B01J37/20 , C07C29/1518 , Y02P20/52 , C07C31/08 , C07C31/04
摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.
摘要翻译：硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

8. 发明授权

US07922894B2 HPC process using a mixture of catalysts 有权
标题翻译：使用催化剂混合物的HPC方法
公开(公告)号：US07922894B2
公开(公告)日：2011-04-12
申请号：US10730433
申请日：2003-12-08
申请人： Frans Lodewijk Plantenga , Katsuhisa Fujita , Satoshi Abe
发明人： Frans Lodewijk Plantenga , Katsuhisa Fujita , Satoshi Abe
IPC分类号： C10G45/04 , C10G47/02
CPC分类号： B01J35/10 , B01J21/04 , B01J21/12 , B01J23/85 , B01J23/883 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , C10G45/08 , C10G49/04
摘要： The present invention pertains to a process for hydroprocessing a heavy hydrocarbon oil, comprising contacting a heavy hydrocarbon oil in the presence of hydrogen with a mixture of hydroprocessing catalyst I and hydroprocessing catalyst II. The process of the invention combines high contaminant removal with high conversion, low sediment formation, and high process flexibility.
摘要翻译：本发明涉及一种用于加氢处理重质烃油的方法，包括在氢气存在下使重质烃油与加氢处理催化剂I和加氢处理催化剂II的混合物接触。本发明的方法结合了高污染物去除，高转化率，低沉积物形成和高过程灵活性。

9. 发明申请

US20100248945A1 BULK CATALYST COMPOSITION COMPRISING BULK METAL OXIDE PARTICLES 审中-公开
标题翻译：包含大块金属氧化物颗粒的大块催化剂组合物
公开(公告)号：US20100248945A1
公开(公告)日：2010-09-30
申请号：US12743153
申请日：2008-12-04
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J23/883 , B01J23/24 , B01J21/16 , B01J23/20 , B01J27/236 , B01J27/049 , B01J23/755 , B01J27/051
CPC分类号： B01J23/8885 , B01J21/16 , B01J23/85 , B01J23/888 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/20 , C10G49/04
摘要： The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.
摘要翻译：本发明涉及一种制备本体金属氧化物颗粒的方法，包括以下步骤：在反应混合物中混合（i）分散在液体中的尺寸小于约1μm的可分散纳米颗粒，（ii）至少一种VIII族非贵金属化合物，（iii）至少一种VIB族金属化合物，和（iv）质子液体; 并在所述纳米颗粒存在下使所述至少一种第VIII族非贵金属化合物和所述至少一种第ⅥB族金属反应。它还涉及通过这种方法获得的散装金属加氢处理催化剂。

10. 发明授权

US09708548B2 Hydrocarbon hydroprocessing using bulk catalyst composition 有权
公开(公告)号：US09708548B2
公开(公告)日：2017-07-18
申请号：US12315272
申请日：2008-12-02
申请人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk-Jan Tromp
发明人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk-Jan Tromp
IPC分类号： C10G45/10 , C10G49/04 , B01J21/16 , B01J23/85 , B01J23/888 , B01J35/00 , B01J37/20 , B01J37/00
CPC分类号： C10G45/10 , B01J21/16 , B01J23/85 , B01J23/8885 , B01J35/0013 , B01J37/0009 , B01J37/20 , C10G49/04 , C10G2300/301 , C10G2300/4018
摘要： The invention relates to a method for hydroprocessing hydrocarbon feedstocks, said process comprising contacting a hydrocarbon feedstock under hydroprocessing conditions with a bulk catalyst composition comprising bulk metal particles that comprise at least one Group VIII non-noble metal, at least one Group VIB metal and nanoparticles. The bulk metal catalyst composition comprises bulk metal particles that may be prepared by a manufacturing process comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles.

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