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    • 1. 发明申请
    • FIBER OR FOIL FROM POLYMERS WITH HIGH TG AND PROCESS FOR THEIR MANUFACTURE
    • 来自聚合物的纤维或纤维与高TG及其制造方法
    • WO2010043705A1
    • 2010-04-22
    • PCT/EP2009/063572
    • 2009-10-16
    • SOLVAY ADVANCED POLYMERS, L.L.C.HERMANUTZ, FrankREICHMANN, Mark, G.
    • HERMANUTZ, FrankREICHMANN, Mark, G.
    • D01D5/06D01F6/66D01F6/74
    • D01D5/06D01F6/665D01F6/74D01F6/76
    • The invention relates to a process for the manufacture of a fiber or foil comprising at least one optionally functionalized polymer with a high Tg selected from the group consisting of poly(aryl ether sulfone) (PAES), poly(aryl ether ketone) (PAEK) and aromatic polyimide, comprising the steps of (aa) providing a solution comprising at least 45 wt. %, based upon the weight of the solution, of the polymer, and at least 20 wt. %, based upon the weight of the solution, of at least one halogen-free organic solvent (S1) for the polymer; (bb) pushing the solution through a nozzle; and (cc) introducing the solution into a coagulation bath comprising (cc1) at least one liquid (L1) in which the polymer is insoluble, and optionally (cc2) at least one organic solvent (S2) for the polymer, identical to or different from the organic solvent (S1), to form a fiber or foil. The invention moreover relates to a fiber or foil obtained by this process as well as to fibers or foils with specific porosity features and/or mechanical properties.
    • 本发明涉及一种制造纤维或箔片的方法,该方法包括至少一种选自聚(芳基醚砜)(PAES),聚(芳基醚酮)(PAEK))的高Tg的任选官能化聚合物, 和芳族聚酰亚胺,包括以下步骤:(aa)提供包含至少45重量% 基于溶液的重量,聚合物的至少20重量%。 基于溶液的重量的至少一种用于聚合物的无卤素有机溶剂(S1); (bb)通过喷嘴推动溶液; 和(cc)将溶液引入包含(cc1)其中聚合物不溶的至少一种液体(L1)和任选(cc2)聚合物的至少一种有机溶剂(S2)的凝结浴,相同或不同 从有机溶剂(S1)中形成纤维或箔。 此外,本发明涉及通过该方法获得的纤维或箔以及具有特定孔隙特征和/或机械性能的纤维或箔。