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1. 发明授权

US3939097A Exhaust gas cleaning catalysts and method of producing same 失效
标题翻译：废气净化催化剂及其制造方法
公开(公告)号：US3939097A
公开(公告)日：1976-02-17
申请号：US422356
申请日：1973-12-06
申请人： So Takeoka , Hideya Inaba , Masayoshi Ichiki
发明人： So Takeoka , Hideya Inaba , Masayoshi Ichiki
IPC分类号： B01D53/60 , B01D53/94 , B01J23/74 , B01J23/755 , B01J23/76 , B01J23/86 , B01J25/00 , B01J21/04 , B01J23/84
CPC分类号： B01D53/945 , B01D53/60 , B01D53/9459 , B01J23/74 , B01J23/755 , B01J23/76 , B01J23/868 , B01J25/00 , B01D2255/20753 , B01D2255/20761 , B01D2255/20784 , B01D2255/2092 , Y02T10/22
摘要： Exhaust gas cleaning catalysts are produced by alloying copper and aluminum with at least one of the elements, nickel and chromium, and eluting by alkali or acid means aluminum from the cooled alloy surface. Small amounts of other metals from the fourth or fifth period V.about. VIII groups, may be added to the catalysts by alloying, or by impregnation, for enhanced catalytic properties. The catalysts exhibit improved reduction of NO and oxidation of CO in an exhaust gas stream, in the presence of Pb, SO.sub.2, moisture and hydrocarbons (H.C) and at relatively low temperatures.
摘要翻译：废气净化催化剂是通过将铜和铝与镍和铬中的至少一种元素合金制成的，并且通过碱或酸来表示从冷却的合金表面出来的铝。可以通过合金化或通过浸渍将来自第四或第五阶段V DIFFERENCE VIII基团的少量其它金属加入到催化剂中以提高催化性能。在Pb，SO2，水分和碳氢化合物（H.C）和相对低的温度下，催化剂表现出废气流中NO的减少和CO的氧化降低。

2. 发明授权

US4293447A Process for repairing plate-shaped denitrating catalysts 失效
标题翻译：板状脱硝催化剂修复工艺
公开(公告)号：US4293447A
公开(公告)日：1981-10-06
申请号：US129204
申请日：1980-03-11
申请人： Hideya Inaba , Kenichi Nagai , Masayoshi Ichiki , Yasumi Kamino , Kazuo Maeda
发明人： Hideya Inaba , Kenichi Nagai , Masayoshi Ichiki , Yasumi Kamino , Kazuo Maeda
IPC分类号： B01J35/02 , B01D53/94 , B01J35/04 , B01J37/02 , F01N3/28 , B01J21/06
CPC分类号： F01N3/281 , B01D53/9418 , B01J35/04 , B01J37/024 , F01N3/2807 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20769 , Y10T428/24149
摘要： A plate-shaped denitrating catalyst comprising a metal net, a finely divided porous carrier retained on the metal net with a binder and covering the metal net, and an active component supported on the carrier.
摘要翻译：一种板状脱硝催化剂，其包括金属网，用粘合剂保持在金属网上并覆盖金属网的细碎多孔载体以及负载在载体上的活性组分。

3. 发明授权

US4040981A Process for producing denitrating catalysts 失效
标题翻译：脱硝催化剂生产工艺
公开(公告)号：US4040981A
公开(公告)日：1977-08-09
申请号：US699472
申请日：1976-06-24
申请人： Hideya Inaba , Masayoshi Ichiki , Yoshinori Wakiyama
发明人： Hideya Inaba , Masayoshi Ichiki , Yoshinori Wakiyama
IPC分类号： B01D53/94 , B01J23/74 , B01J25/00 , B01J35/02 , B01J37/02 , B01J21/04 , B01J23/86
CPC分类号： B01J37/0215 , B01D53/9418 , B01J25/00 , B01J35/02 , B01D2251/2062 , B01D2255/20738 , B01D2255/20753 , B01D2255/9027
摘要： A denitrating catalyst is produced by plating the surface of unactivated metal with aluminum and immersing the resulting layered product in an aqueous aluminum-dissolving solution to dissolve out the aluminum into the aqueous solution and to thereby activate the surface of the metal.
摘要翻译：通过用铝将未活化金属的表面电镀并将所得层压体浸渍在铝水溶液中以将铝溶解到水溶液中并由此活化金属的表面来制备脱硝催化剂。

4. 发明授权

US4383941A Catalyst structure including glass fiber product 失效
标题翻译：催化剂结构包括玻璃纤维制品
公开(公告)号：US4383941A
公开(公告)日：1983-05-17
申请号：US316050
申请日：1981-10-28
申请人： Hideya Inaba , Masayoshi Ichiki
发明人： Hideya Inaba , Masayoshi Ichiki
IPC分类号： B01J8/02 , B01J35/02 , B01J35/06
CPC分类号： B01J35/02 , B01J35/06 , B01J8/02 , B01J2208/00061 , B01J2208/00088 , B01J2208/00212 , B01J2208/00407
摘要： A catalyst structure comprises a shape retaining metal core of the desired shape, a particle holding layer attached to the core and made of a glass fiber product and catalyst particles held in the layer.
摘要翻译：催化剂结构包括具有所需形状的形状保持金属芯，附着到芯上并由玻璃纤维产物和保持在该层中的催化剂颗粒制成的颗粒保持层。

5. 发明授权

US4206081A Process for producing highly active denitrating catalysts 失效
标题翻译：生产高活性脱硝催化剂的方法
公开(公告)号：US4206081A
公开(公告)日：1980-06-03
申请号：US848235
申请日：1977-11-03
申请人： Hideya Inaba , Kazuo Maeda , Yasumi Kamino , Toshio Hama , Kenichi Nagai , Masayoshi Ichiki
发明人： Hideya Inaba , Kazuo Maeda , Yasumi Kamino , Toshio Hama , Kenichi Nagai , Masayoshi Ichiki
IPC分类号： B01D53/94 , B01J23/22 , B01J37/02 , B01J21/04 , B01J23/74 , B01J25/00 , B01J27/02
CPC分类号： B01J37/0207 , B01D53/9418 , B01J23/22 , B01D2251/2062 , B01D2255/20723 , B01D2255/20738 , B01D2255/20753 , B01D2255/20769 , B01D2255/20776
摘要： A highly active denitrating catalyst is produced by converting the surface layer of steel material to an aluminum alloy, treating the resulting steel material with an aluminum dissolving solution to dissolve out the aluminum and to render the surface layer porous, and immersing the steel material having the porous surface layer in a solution containing a vanadium compound to cause the porous surface layer to support the vanadium compound.
摘要翻译：通过将钢材表面层转化为铝合金制成高活性脱硝催化剂，用铝溶解液处理得到的钢材，使铝溶解，使表层多孔，并浸渍具有在含有钒化合物的溶液中的多孔表面层，以使多孔表面层支持钒化合物。

6. 发明授权

US4176091A Denitrating catalysts having porous coating and process for producing same 失效
标题翻译：具有多孔涂层的脱硝催化剂及其制造方法
公开(公告)号：US4176091A
公开(公告)日：1979-11-27
申请号：US927096
申请日：1978-07-24
申请人： Hideya Inaba , Hisao Ogiyama , Masayoshi Ichiki , Yasumi Kamino , Nobuo Matsumoto , Kenichi Nagai , Masami Suzuki
发明人： Hideya Inaba , Hisao Ogiyama , Masayoshi Ichiki , Yasumi Kamino , Nobuo Matsumoto , Kenichi Nagai , Masami Suzuki
IPC分类号： B01D53/86 , B01J37/02 , B01J21/08 , B01J23/22 , B01J23/26 , B01J23/72
CPC分类号： B01D53/8628 , B01J37/024
摘要： A denitrating catalyst having a porous coating is produced by immersing a catalyst base of porous metal in a silica-containing coating bath, drying the catalyst base to form a carrier having a porour silica coating, immersing the carrier in a solution containing an active component and drying the resulting carrier to cause the carrier to support the active component thereon.
摘要翻译：通过将多孔金属的催化剂基底浸渍在含二氧化硅的涂布浴中，干燥催化剂基底以形成具有多孔二氧化硅涂层的载体，将载体浸入含有活性组分的溶液中并制备具有多孔涂层的脱硝催化剂，干燥所得载体以使载体在其上负载活性组分。

7. 发明申请

US20080248943A1 Method of Regenerating Thermally Deteriorated Catalyst 审中-公开
标题翻译：再生热劣化催化剂的方法
公开(公告)号：US20080248943A1
公开(公告)日：2008-10-09
申请号：US10572310
申请日：2004-09-21
申请人： Atsushi Fukuju , Masayoshi Ichiki , Kazuhiro Yano
发明人： Atsushi Fukuju , Masayoshi Ichiki , Kazuhiro Yano
IPC分类号： B01J38/68
CPC分类号： B01J23/22 , B01D53/96 , B01D2255/20723 , B01J23/30 , B01J23/92 , B01J38/60 , B01J38/66 , B01J38/68
摘要： A catalyst that is used for a method of reduction removal of NOx in a exhaust gas by using ammonia as a reducing agent and has been deteriorated in activity by aggregation of vanadium oxide as an active component through long term use at a high temperature is washed with an acid aqueous solution having pH of 6 or less, and preferably 4 or less. The washing operation dissolves and removes away mainly the vanadium oxide as the aggregated active component, and then vanadium oxide as the active component is re-deposited thereon. The method of the invention enables regeneration of a thermally deteriorated catalyst, which has conventionally been impossible. The washing operation with the acid aqueous solution or an alkali aqueous solution does not influence the mechanical strength of the catalyst.
摘要翻译：一种催化剂，其用于通过使用氨作为还原剂还原除去废气中的NO x的方法，并且通过长期凝聚氧化钒作为活性成分而使活性降低在高温下使用的pH为6以下，优选为4以下的酸性水溶液洗涤。洗涤操作主要溶解并除去作为聚集的活性组分的氧化钒，然后将作为活性组分的氧化钒再沉积在其上。本发明的方法能够再生传统上不可能的热劣化催化剂。用酸性水溶液或碱性水溶液进行洗涤操作不影响催化剂的机械强度。

8. 发明授权

US06171372B2 Nitrogen dioxide absorbent 有权
标题翻译：二氧化氮吸收剂
公开(公告)号：US06171372B2
公开(公告)日：2001-01-09
申请号：US09168860
申请日：1998-10-08
申请人： Masayoshi Ichiki , Yuki Sairyo , Atsushi Fukuju
发明人： Masayoshi Ichiki , Yuki Sairyo , Atsushi Fukuju
IPC分类号： B01D5304
CPC分类号： B01J20/20 , B01D53/02 , B01D53/565 , B01D2257/404 , B01J20/0211 , B01J20/0222 , B01J20/0225 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/165 , B01J20/28004 , B01J20/28028 , B01J20/28033 , B01J20/28045 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3248 , B01J20/3251 , B01J20/3289 , B01J20/3293 , B01J2220/42 , B01J2220/4831 , B01J2220/64 , Y02A50/2345 , Y10S95/90
摘要： The present invention provides a nitrogen dioxide absorbent for the exhaust gas purifying facility designed to remove by absorption or adsorption of NO2 from a gas (such as ventilation gas from road tunnels) containing NOx in low concentrations. The absorbent is composed of a porous carrier and a basic amino acid and/or organic amine compound supported thereon. The absorbent is produced by impregnating a porous carrier sequentially with two aqueous solutions each containing in an amount of, for example, 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound, or impregnating a porous carrier with a solution containing 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and/or 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound.
摘要翻译：本发明提供了一种废气净化设备的二氧化氮吸收剂，其设计用于通过吸收或吸附低浓度的NOx的气体（例如来自道路隧道的通风气体）来除去NO 2。吸收剂由多孔载体和负载在其上的碱性氨基酸和/或有机胺化合物组成。吸收剂通过依次用两种水溶液浸渍多孔载体来制备，每种水溶液含有例如0.5-3.0mol / l（优选1.0-2.0mol / l）碱性氨基酸和0.5-3.0mol / l （优选1.0-2.0mol / l）有机胺化合物，或者用含有0.5-3.0mol / l（优选1.0-2.0mol / l）碱性氨基酸和/或0.5-3.0mol / l的溶液浸渍多孔载体， l（优选1.0-2.0mol / l）有机胺化合物。

9. 发明申请

US20070032373A1 Method of regenerating deteriorated catalyst 审中-公开
标题翻译：再生劣化催化剂的方法
公开(公告)号：US20070032373A1
公开(公告)日：2007-02-08
申请号：US10572311
申请日：2004-09-21
申请人： Nobuo Matsumoto , Tetsuo Kodama , Atsushi Fukuju , Masayoshi Ichiki , Kazuhiro Yano
发明人： Nobuo Matsumoto , Tetsuo Kodama , Atsushi Fukuju , Masayoshi Ichiki , Kazuhiro Yano
IPC分类号： B01J38/00
CPC分类号： B01J38/60 , B01D53/8628 , B01D53/96 , B01D2255/20723 , B01D2255/20776 , B01J23/92
摘要： The invention is to provide a method for regenerating a deteriorated denitration catalyst by an easy and simple procedure. A catalyst that is used for reduction removal of NOx contained in a exhaust gas by using ammonia as a reducing agent and has been deteriorated in activity through long term use is washed with an acid aqueous solution having pH of 4 or less, and preferably 2 or less, containing vanadium and/or tungsten. The washing operation dissolves away mainly an alkali metal, an alkaline earth metal, arsenic and sulfur, which are deteriorating components, and vanadium and tungsten having been deteriorated in activity, and simultaneously vanadium and/or tungsten as an active component is deposited thereon. Examples of the alkali metal include potassium and sodium, and examples of the alkaline earth metal include calcium.
摘要翻译：本发明提供一种通过简单且简单的方法再生劣化脱硝催化剂的方法。通过使用氨作为还原剂并且通过长期使用而使活性劣化的用于还原除去废气中的NO x的催化剂用pH为 4以下，优选为2以下，含有钒和/或钨。洗涤操作主要消除作为劣化组分的碱金属，碱土金属，砷和硫，活性劣化的钒和钨，同时沉积作为活性组分的钒和/或钨。碱金属的实例包括钾和钠，碱土金属的实例包括钙。

10. 发明授权

US06423283B1 Method for removing NOx 有权
标题翻译： NOx去除方法
公开(公告)号：US06423283B1
公开(公告)日：2002-07-23
申请号：US09623797
申请日：2000-09-08
申请人： Masayoshi Ichiki , Masaki Akiyama , Atsushi Fukuju
发明人： Masayoshi Ichiki , Masaki Akiyama , Atsushi Fukuju
IPC分类号： B01J800
CPC分类号： B01D53/8625 , Y02A50/2345 , Y02C20/10
摘要： The invention provides a process for removing NOx which is free of impairment in denitration efficiency at a reaction temperature of up to 300° C. even when the component molar ratio of NOx in the gas to be treated is NO2>NO. For use in removing NOx from the gas to be treated and containing NO2 in a larger amount than NO, that is, having a (NO2)/NOx ratio in excess of 0.5, by selective reduction with use of ammonia serving as a main reducing agent in the presence of a denitration catalyst, the process of the invention for removing NOx comprises adding to the denitration reaction system a substance for removing an excess of oxygen accumulating on catalyst active sites by selectively reducing the oxygen at not higher than 300° C., for example, at 300 to 150° C., in other words, a substance which reacts with the excess of oxygen on the catalyst active sites and becomes oxidized at not higher than 300° C.
摘要翻译：本发明提供一种除去在300℃以下的反应温度下脱硝效率不受损害的NOx的方法，即使待处理气体中的NOx的成分摩尔比为NO2> NO。用于从待处理的气体中除去NO含量大于NO的NO 2，即NO 2 / NOx比超过0.5时，通过使用氨作为主要还原剂进行选择性还原在脱硝催化剂的存在下，本发明除去NOx的方法包括向脱硝反应体系中加入一种物质，用于通过选择性地将氧气在不高于300℃下还原，除去积聚在催化剂活性位上的过量氧，例如，在300〜150℃，换句话说，与催化剂活性部位上的过量氧反应并在不高于300℃下氧化的物质。

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