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1. 发明授权

US08071679B2 Coating compositions comprising a polymer containing an oligomeric macromonomer 有权
标题翻译：包含含有低聚大分子单体的聚合物的涂料组合物
公开(公告)号：US08071679B2
公开(公告)日：2011-12-06
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08F8/00 , C08G63/91
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

2. 发明申请

US20090221757A1 POLYMERS CONTAINING AN OLIGOMERIC MACROMONOMER 审中-公开
标题翻译：含有低分子大分子的聚合物
公开(公告)号：US20090221757A1
公开(公告)日：2009-09-03
申请号：US12040371
申请日：2008-02-29
申请人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
发明人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
IPC分类号： C08F2/00 , C08F289/00
CPC分类号： C08F290/00 , C08F265/04 , C08F283/12 , C08F289/00 , C08F290/06 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02
摘要： The present invention is directed to a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30.0, and wherein the core is
摘要翻译：本发明涉及包含低聚大分子单体和寡聚大分子单体延伸的核心的聚合物，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30.0，并且其中所述核心为<10重量％总聚合物重量的百分比。本发明还涉及其制造方法。

3. 发明申请

US20090221748A1 COATING COMPOSITIONS COMPRISING A POLYMER CONTAINING AN OLIGOMERIC MACROMONOMER 有权
标题翻译：包含含有低聚物的聚合物的涂料组合物
公开(公告)号：US20090221748A1
公开(公告)日：2009-09-03
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08L33/08
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

4. 发明授权

US07776959B2 Coatings comprising terpene 失效
标题翻译：包含萜烯的涂料
公开(公告)号：US07776959B2
公开(公告)日：2010-08-17
申请号：US11564570
申请日：2006-11-29
申请人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
发明人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
IPC分类号： C08L33/04 , C08L99/00 , C08G65/34
CPC分类号： C09D4/00 , C08F289/00 , C08F291/00 , C09D151/003 , C09D151/08 , C08L2666/02
摘要： Coatings comprising a polymer comprising a terpene and a monomer polymerized with terpene by free radical polymerization are disclosed. Coatings comprising terpene in greater than 30 wt % are also disclosed as are coatings comprising a terpene and a urea. Copolymers with terpene are also disclosed.
摘要翻译：公开了包含由萜烯和通过自由基聚合与萜烯聚合的单体的聚合物的涂料。包含大于30wt％的萜烯的涂层也被公开为包含萜烯和脲的涂层。还公开了与萜烯的共聚物。

5. 发明授权

US06485788B1 Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical 失效
标题翻译：含有使用原子转移自由基聚合制备的环氧官能聚合物的热固性组合物
公开(公告)号：US06485788B1
公开(公告)日：2002-11-26
申请号：US09934384
申请日：2001-08-21
申请人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
发明人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
IPC分类号： C08G5932
CPC分类号： C08L53/00 , C08F8/26 , C08F293/005 , C08F2438/01 , C08G59/3209 , C08K5/0025 , C09D153/00 , Y10T428/31511 , C08L33/12 , C08L2666/02
摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with epoxides; and (b) a non-gelled, epoxy functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x— or —{(G)q—(M)p}x— wherein M is a residue, that is free of epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the epoxy functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.
摘要翻译：提供一种热固性组合物，其包括：（a）具有至少两个与环氧化物反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的环氧官能聚合物。聚合物含有至少一种以下聚合物链结构：或其中M是不含环氧官能团的至少一种烯属不饱和自由基聚合单体的残基; G是具有至少一个烯属不饱和自由基聚合单体的具有环氧官能度的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得环氧官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和通过这些方法涂覆的基材，以及彩色 - 透明复合涂层。

6. 发明授权

US06319967B1 Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical polymerization 有权
标题翻译：含有使用原子转移自由基聚合制备的环氧官能聚合物的热固性组合物
公开(公告)号：US06319967B1
公开(公告)日：2001-11-20
申请号：US09375021
申请日：1999-08-16
申请人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
发明人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
IPC分类号： C08G5932
CPC分类号： C08L53/00 , C08F8/26 , C08F293/005 , C08F2438/01 , C08G59/3209 , C08K5/0025 , C09D153/00 , Y10T428/31511 , C08L33/12 , C08L2666/02
摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with epoxides; and (b) a non-gelled, epoxy functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x—or —{(G)q—(M)p}x— wherein M is a residue, that is free of epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the epoxy functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.
摘要翻译：提供一种热固性组合物，其包括：（a）具有至少两个与环氧化物反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的环氧官能聚合物。聚合物含有至少一种以下聚合物链结构：其中M是至少一种烯属不饱和可自由基聚合单体的残基，不含环氧官能团; G是具有至少一个烯属不饱和自由基聚合单体的具有环氧官能度的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得环氧官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和通过这些方法涂覆的基材，以及彩色 - 透明复合涂层。

7. 发明授权

US07897261B2 Surface active additives for coatings 有权
标题翻译：涂料用表面活性剂
公开(公告)号：US07897261B2
公开(公告)日：2011-03-01
申请号：US11178548
申请日：2005-07-11
申请人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
发明人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
IPC分类号： B32B27/32 , C08F2/00
CPC分类号： C09D143/00 , C08L33/068 , C08L2312/00 , Y10T428/31504 , Y10T428/31855 , Y10T428/31938 , C08L2666/04
摘要： A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.
摘要翻译：提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度涂层。该组合物可用于含有两层或多层涂层的多层复合材料。

8. 发明申请

US20090023862A1 SOLVENTBORNE THERMOSETTING COMPOSITIONS CONTAINING COPOLYMERS OF ISOBUTYLENE TYPE MONOMERS 审中-公开
标题翻译：含有异丁烯类单体的共聚物的溶剂热稳定剂组合物
公开(公告)号：US20090023862A1
公开(公告)日：2009-01-22
申请号：US11778820
申请日：2007-07-17
申请人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
发明人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
IPC分类号： C08F8/00 , C08J3/20
CPC分类号： C08F220/28 , C08F212/08 , C09D133/06
摘要： The present invention is directed to a solventborne thermosetting composition comprising:(a) a polymeric binder comprising a copolymer, said copolymer being a polymerization product of: (i) 10 to 30 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having the following structure (I): wherein R1 comprises linear or branched C1 to C4 alkyl, and R2 comprises methyl, linear, cyclic or branched C1 to C20 alkyl or alkenyl; (ii) 5 to 25 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having aromatic functionality; (iii) 0 to 60 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing secondary hydroxyl groups; and (iv) 15 to 50 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing primary hydroxyl groups; (b) an aminoplast curing agent; and(c) a compound comprising a capped isocyanate-functional material.
摘要翻译：本发明涉及一种溶剂型热固性组合物，其包含：（a）包含共聚物的聚合物粘合剂，所述共聚物是聚合产物，其聚合产物为：（i）基于用于制备的单体总重量的10至30重量％该共聚物具有以下结构（I）的单体：其中R 1包含直链或支链C 1至C 4烷基，R 2包括甲基，直链，环状或支链C 1至C 20烷基或链烯基; （ii）基于用于制备共聚物的单体的总重量，5至25重量％的具有芳族官能团的单体; （iii）基于用于制备共聚物的单体的总重量，0至60重量％的含有仲羟基的烯属不饱和单体; 和（iv）基于用于制备共聚物的单体的总重量为15〜50重量％的含有伯羟基的烯属不饱和单体; （b）氨基塑料固化剂; 和（c）包含封端的异氰酸酯官能材料的化合物。

9. 发明授权

US06841641B2 Copolymers comprising low surface tension (meth) acrylates 失效
标题翻译：包含低表面张力（甲基）丙烯酸酯的共聚物
公开(公告)号：US06841641B2
公开(公告)日：2005-01-11
申请号：US10237357
申请日：2002-09-09
申请人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
发明人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
IPC分类号： C08F220/10 , C08F20/22 , C08F220/22 , C08F230/08
CPC分类号： C08F220/10
摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.
摘要翻译：本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。共聚物的多分散指数小于2.5。本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。

10. 发明申请

US20080255307A1 Copolymers comprising low surface tension (meth)acrylates 审中-公开
标题翻译：包含低表面张力（甲基）丙烯酸酯的共聚物
公开(公告)号：US20080255307A1
公开(公告)日：2008-10-16
申请号：US12132928
申请日：2008-06-04
申请人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
发明人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
IPC分类号： C08G63/00
CPC分类号： C08F220/10
摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.
摘要翻译：本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。共聚物的多分散指数小于2.5。本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。

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