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1. 发明授权

US07897261B2 Surface active additives for coatings 有权
标题翻译：涂料用表面活性剂
公开(公告)号：US07897261B2
公开(公告)日：2011-03-01
申请号：US11178548
申请日：2005-07-11
申请人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
发明人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
IPC分类号： B32B27/32 , C08F2/00
CPC分类号： C09D143/00 , C08L33/068 , C08L2312/00 , Y10T428/31504 , Y10T428/31855 , Y10T428/31938 , C08L2666/04
摘要： A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.
摘要翻译：提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度涂层。该组合物可用于含有两层或多层涂层的多层复合材料。

2. 发明申请

US20090221748A1 COATING COMPOSITIONS COMPRISING A POLYMER CONTAINING AN OLIGOMERIC MACROMONOMER 有权
标题翻译：包含含有低聚物的聚合物的涂料组合物
公开(公告)号：US20090221748A1
公开(公告)日：2009-09-03
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08L33/08
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

3. 发明授权

US08071679B2 Coating compositions comprising a polymer containing an oligomeric macromonomer 有权
标题翻译：包含含有低聚大分子单体的聚合物的涂料组合物
公开(公告)号：US08071679B2
公开(公告)日：2011-12-06
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08F8/00 , C08G63/91
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

4. 发明申请

US20090023862A1 SOLVENTBORNE THERMOSETTING COMPOSITIONS CONTAINING COPOLYMERS OF ISOBUTYLENE TYPE MONOMERS 审中-公开
标题翻译：含有异丁烯类单体的共聚物的溶剂热稳定剂组合物
公开(公告)号：US20090023862A1
公开(公告)日：2009-01-22
申请号：US11778820
申请日：2007-07-17
申请人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
发明人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
IPC分类号： C08F8/00 , C08J3/20
CPC分类号： C08F220/28 , C08F212/08 , C09D133/06
摘要： The present invention is directed to a solventborne thermosetting composition comprising:(a) a polymeric binder comprising a copolymer, said copolymer being a polymerization product of: (i) 10 to 30 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having the following structure (I): wherein R1 comprises linear or branched C1 to C4 alkyl, and R2 comprises methyl, linear, cyclic or branched C1 to C20 alkyl or alkenyl; (ii) 5 to 25 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having aromatic functionality; (iii) 0 to 60 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing secondary hydroxyl groups; and (iv) 15 to 50 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing primary hydroxyl groups; (b) an aminoplast curing agent; and(c) a compound comprising a capped isocyanate-functional material.
摘要翻译：本发明涉及一种溶剂型热固性组合物，其包含：（a）包含共聚物的聚合物粘合剂，所述共聚物是聚合产物，其聚合产物为：（i）基于用于制备的单体总重量的10至30重量％该共聚物具有以下结构（I）的单体：其中R 1包含直链或支链C 1至C 4烷基，R 2包括甲基，直链，环状或支链C 1至C 20烷基或链烯基; （ii）基于用于制备共聚物的单体的总重量，5至25重量％的具有芳族官能团的单体; （iii）基于用于制备共聚物的单体的总重量，0至60重量％的含有仲羟基的烯属不饱和单体; 和（iv）基于用于制备共聚物的单体的总重量为15〜50重量％的含有伯羟基的烯属不饱和单体; （b）氨基塑料固化剂; 和（c）包含封端的异氰酸酯官能材料的化合物。

5. 发明授权

US07776959B2 Coatings comprising terpene 失效
标题翻译：包含萜烯的涂料
公开(公告)号：US07776959B2
公开(公告)日：2010-08-17
申请号：US11564570
申请日：2006-11-29
申请人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
发明人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
IPC分类号： C08L33/04 , C08L99/00 , C08G65/34
CPC分类号： C09D4/00 , C08F289/00 , C08F291/00 , C09D151/003 , C09D151/08 , C08L2666/02
摘要： Coatings comprising a polymer comprising a terpene and a monomer polymerized with terpene by free radical polymerization are disclosed. Coatings comprising terpene in greater than 30 wt % are also disclosed as are coatings comprising a terpene and a urea. Copolymers with terpene are also disclosed.
摘要翻译：公开了包含由萜烯和通过自由基聚合与萜烯聚合的单体的聚合物的涂料。包含大于30wt％的萜烯的涂层也被公开为包含萜烯和脲的涂层。还公开了与萜烯的共聚物。

6. 发明申请

US20090221757A1 POLYMERS CONTAINING AN OLIGOMERIC MACROMONOMER 审中-公开
标题翻译：含有低分子大分子的聚合物
公开(公告)号：US20090221757A1
公开(公告)日：2009-09-03
申请号：US12040371
申请日：2008-02-29
申请人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
发明人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
IPC分类号： C08F2/00 , C08F289/00
CPC分类号： C08F290/00 , C08F265/04 , C08F283/12 , C08F289/00 , C08F290/06 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02
摘要： The present invention is directed to a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30.0, and wherein the core is
摘要翻译：本发明涉及包含低聚大分子单体和寡聚大分子单体延伸的核心的聚合物，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30.0，并且其中所述核心为<10重量％总聚合物重量的百分比。本发明还涉及其制造方法。

7. 发明授权

US07125931B2 Thermosetting compositions containing alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US07125931B2
公开(公告)日：2006-10-24
申请号：US10887733
申请日：2004-07-09
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

8. 发明授权

US06992137B2 Alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US06992137B2
公开(公告)日：2006-01-31
申请号：US10697413
申请日：2003-10-30
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： C09D201/02 , C08F8/00 , C08F10/00 , C08F20/00
摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

9. 发明授权

US06900279B2 Compositions containing copolymers of post-polymerization reacted (meth) acrylate monomers 失效
标题翻译：含有后聚合反应的（甲基）丙烯酸酯单体的共聚物的组合物
公开(公告)号：US06900279B2
公开(公告)日：2005-05-31
申请号：US10348367
申请日：2003-01-21
申请人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
发明人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
IPC分类号： B05D7/24 , B05D1/00 , B05D3/02 , B05D3/06 , B05D7/00 , B32B27/30 , C08F8/00 , C08F210/00 , C08F210/10 , C08F210/14 , C08F220/10 , C08F290/04 , C08G18/62 , C08G18/79 , C08G18/80 , C08K5/092 , C08L23/20 , C08L23/22 , C08L33/06 , C08L33/14 , C08L63/00 , C08L101/00 , C09D7/12 , C09D109/00 , C09D109/02 , C09D123/22 , C09D133/00 , C09D133/02 , C09D133/06 , C09D133/08 , C09D133/14 , C09D133/24 , C09D157/04 , C09D163/00 , C09D167/00 , C09D175/04 , C09D201/00 , C08F120/54 , C08F120/10
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A composition that includes a non-gelled copolymer that includes one or more residues of a first polymerizable ethylenically unsaturated monomer containing a pendant amide, ester or carboxylic acid group. The nearest neighboring monomer residues of the majority of the first monomer residues along the copolymer molecule do not contain pendant carbonyl functional groups. The amide, ester or carboxylic acid group of the residues of the first monomer are the post polymerization transesterification, transamidification or hydrolysis reaction product of a C1-C4 alkyl ester group in the unreacted first monomer with a compound selected from amine functional compounds and hydroxy functional compounds. The reacted copolymer is substantially free of cyclical structures resulting from the transesterification, transamidification or hydrolysis reaction. The compositions may be thermosetting compositions useful in multi-layer composite coatings.
摘要翻译：包含非凝胶共聚物的组合物，其包含含有侧酰胺，酯或羧酸基团的第一可聚合烯属不饱和单体的一个或多个残基。沿着共聚物分子的大部分第一单体残基的最邻近的单体残基不含有羰基官能团。第一单体的残基的酰胺，酯或羧酸基是C 1 -C 4烷基酯基的后聚合酯交换，转酰胺化或水解反应产物在未反应的第一单体中与选自胺官能化合物和羟基官能化合物的化合物反应。反应的共聚物基本上不含由酯交换，酰胺化或水解反应产生的循环结构。组合物可以是可用于多层复合涂层的热固性组合物。

10. 发明授权

US06677422B2 Method of making alternating copolymers of isobutylene type monomers 失效
标题翻译：制备异丁烯型单体的交替共聚物的方法
公开(公告)号：US06677422B2
公开(公告)日：2004-01-13
申请号：US10077559
申请日：2002-02-15
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F1000
CPC分类号： C08F220/12
摘要： A method of making a copolymer composition containing a copolymer, which includes the steps of (a) providing a donor monomer composition that includes an isobutylene type monomer; (b) mixing the donor monomer composition with an ethylenically unsaturated monomer composition that includes one or more ethylenically unsaturated acceptor monomers, and is substantially free of maleate type monomers and fumarate type monomers, and (c) polymerizing the mixture resulting from step (b) in the presence of a free radical polymerization initiator. The polymerization is carried out in the substantial absence of Lewis acids and/or transition metals. The isobutylene type monomer is present at a molar excess of at least 10 mol % based on the molar concentration of monomers in the ethylenically unsaturated monomer composition. The ethylenically unsaturated acceptor monomers are present in an amount of at least 15 mol % of the total monomer composition.
摘要翻译：一种制备含有共聚物的共聚物组合物的方法，其包括以下步骤：（a）提供包含异丁烯型单体的供体单体组合物; （b）将供体单体组合物与包含一种或多种烯键式不饱和受体单体的烯属不饱和单体组合物混合，并且基本上不含马来酸盐型单体和富马酸盐型单体，和（c）将由步骤（b）得到的混合物聚合，在自由基聚合引发剂存在下进行。基本上不存在路易斯酸和/或过渡金属进行聚合。基于烯属不饱和单体组合物中单体的摩尔浓度，异丁烯型单体的摩尔过量为至少10摩尔％。烯属不饱和受体单体的存在量为总单体组合物的至少15摩尔％。

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