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1. 发明授权

US06723469B1 Alkaline battery without mercury and electronic apparatus powered thereby 失效
标题翻译：无汞的碱性电池和电子设备由此供电
公开(公告)号：US06723469B1
公开(公告)日：2004-04-20
申请号：US08593266
申请日：1996-01-29
申请人： Shunji Watanabe , Tsugio Sakai , Hideo Sakamoto
发明人： Shunji Watanabe , Tsugio Sakai , Hideo Sakamoto
IPC分类号： H01M442
CPC分类号： H01M6/045 , H01M4/06 , H01M4/42 , H01M4/62 , H01M4/628 , H01M4/66 , H01M6/06 , H01M10/26
摘要： An alkaline battery comprises a negative electrode having an active material comprised of mercuryless zinc powder, and an electrolyte. In one embodiment, the electrolyte contains one or more indium compounds selected from the group consisting of indium sulfate, indium sulfamate and indium chloride. In another embodiment, the negative electrode contains one or more indium compounds selected from the group consisting of indium sulfate, indium sulfamate and indium chloride. An improved alkaline battery is achieved which does not pose environmental problems, in which corrosion of the zinc powder by the electrolyte during storage of the battery is suppressed, and in which a good discharge performance of the battery is maintained.
摘要翻译：碱性电池包括具有由无汞锌粉末和电解质构成的活性物质的负极。在一个实施方案中，电解质含有一种或多种选自硫酸铟，氨基磺酸钠和氯化铟的铟化合物。在另一个实施方案中，负极含有一种或多种选自硫酸铟，氨基磺酸钠和氯化铟的铟化合物。实现了改善的碱性电池，其不会引起环境问题，其中抑制了电池储存期间电解液对锌粉的腐蚀，并且其中保持了良好的电池放电性能。

2. 发明授权

US06586139B1 Alkaline battery without mercury and electronic apparatus powered thereby 失效
标题翻译：无汞的碱性电池和电子设备由此供电
公开(公告)号：US06586139B1
公开(公告)日：2003-07-01
申请号：US08476235
申请日：1995-06-07
申请人： Shunji Watanabe , Tsugio Sakai , Hideo Sakamoto
发明人： Shunji Watanabe , Tsugio Sakai , Hideo Sakamoto
IPC分类号： H01M618
CPC分类号： H01M6/045 , H01M4/06 , H01M4/42 , H01M4/62 , H01M4/628 , H01M4/66 , H01M6/06 , H01M10/26
摘要： An alkaline battery comprises a negative electrode having an active material comprised of mercuryless zinc powder containing a gelling agent. In one embodiment, the alkaline battery comprises a current collector having an outermost surface coated with a layer of zinc or a metal having a hydrogen overvoltage higher than that of zinc, and an electrolyte containing one or more compounds selected from the group consisting of an indium compound, lead oxide; a hydroxide of alkaline earth metal and a surfactant having polyethylene oxide. In another embodiment, the negative electrode active material contains one or more species of materials selected from the group consisting of an indium compound, lead oxide, a hydroxide of alkaline earth metal and a surfactant having polyethylene oxide, and a current collector having an outermost surface coated with a layer of zinc or a metal having a hydrogen overvoltage higher than that of zinc. An improved alkaline battery is achieved which does not pose environmental problems, and which corrosion of the zinc powder of the battery is suppressed, and in which a good discharge performance of the battery is maintained.
摘要翻译：碱性电池包括具有由含有胶凝剂的无汞锌粉末构成的活性物质的负极。在一个实施方案中，碱性电池包括具有涂覆有锌层或具有高于锌的氢过电压的金属的最外表面的集电器，以及含有一种或多种选自铟的化合物的电解质化合物，氧化铅; 碱土金属的氢氧化物和具有聚环氧乙烷的表面活性剂。在另一个实施方案中，负极活性物质包含选自铟化合物，氧化铅，碱土金属氢氧化物和具有聚环氧乙烷的表面活性剂中的一种或多种材料，以及具有最外表面的集电体涂覆有一层具有高于锌的氢过电压的锌或金属。实现了不会产生环境问题的改进的碱性电池，并且抑制了电池的锌粉的腐蚀，并且保持了电池的良好的放电性能。

3. 发明授权

US07311995B2 Electrochemical cell 有权
标题翻译：电化学电池
公开(公告)号：US07311995B2
公开(公告)日：2007-12-25
申请号：US10844290
申请日：2004-05-12
申请人： Yoshibumi Nakamura , Kensuke Tahara , Shunji Watanabe , Tsugio Sakai , Hideharu Onodera
发明人： Yoshibumi Nakamura , Kensuke Tahara , Shunji Watanabe , Tsugio Sakai , Hideharu Onodera
IPC分类号： H01M2/08
CPC分类号： H01M2/0426 , H01M2/0207 , H01M2/0217 , H01M2/0275 , H01M2/30
摘要： An electrochemical cell has an outer case formed of one of ceramics and glass. An electrochemical cell element is hermetically sealed in the outer case. The electrochemical cell element contains a positive pole, a negative pole, and a non-aqueous electrolyte containing an organic solvent. A metal layer is formed on an edge of the outer case. A sealing plate is resistance welded to the metal layer. The sealing plate is made of an alloy containing, in weight percentage, Co by 1 to 50%, Ni by 1 to 70%, Fe by 20% or higher, Cr by 10% or lower, Mn by 2.0% or lower, Si by 1.0% or lower and C by 1.0% or lower.
摘要翻译：电化学电池具有由陶瓷和玻璃之一形成的外壳。电化学电池元件气密地密封在外壳中。电化学电池元件包含正极，负极和含有机溶剂的非水电解质。金属层形成在外壳的边缘上。密封板与金属层电阻焊接。密封板由以下组成的合金制成：Co：1〜50％，Ni：1〜70％，Fe：20％以上，Cr：10％以下，Mn：2.0％以下，Si：2.0％ 1.0％以下，1.0％以下。

4. 发明授权

US06733544B2 Method of producing electrical double layer capacitor and method of mounting electrical double layer capacitor on a circuit substrate 失效
标题翻译：双电层电容器的制造方法以及在电路基板上安装双电层电容器的方法
公开(公告)号：US06733544B2
公开(公告)日：2004-05-11
申请号：US09975194
申请日：2001-10-10
申请人： Shinichi Takasugi , Yoshimi Kanno , Shunji Watanabe , Tsugio Sakai , Yoshibumi Nakamura , Hideharu Onodera
发明人： Shinichi Takasugi , Yoshimi Kanno , Shunji Watanabe , Tsugio Sakai , Yoshibumi Nakamura , Hideharu Onodera
IPC分类号： H01G900
CPC分类号： H01G9/155 , Y02E60/13 , Y10T29/417
摘要： A method for producing an electrical double layer capacitor comprising the steps of assembling together components comprised of a positive electrode, a negative electrode, a non-aqueous solvent, an electrolyte containing a supporting salt, a separator, and a gasket to form a coin- or button-type electrical double layer capacitor, heating the assembled coin- or button-type electrical double layer capacitor so that a temperature profile of the heating step is approximately the same as a temperature profile of reflow soldering, and welding an outer connection terminal to the heated assembled coin- or button-type electrical double layer capacitor after the heating step.
摘要翻译：一种双电层电容器的制造方法，其特征在于，将由正极，负极，非水溶剂，含有支持盐的电解质，隔膜，垫圈构成的组件组装在一起，或按钮型双电层电容器，加热组装的硬币或按钮式双电层电容器，使得加热步骤的温度分布与回流焊接的温度分布大致相同，并且将外部连接端子焊接到在加热步骤之后加热组装的硬币或按钮式双电层电容器。

5. 发明申请

US20050167474A1 Soldering method of nonaqueous-electrolyte secondary-battery 失效
标题翻译：非水电解质二次电池的焊接方法
公开(公告)号：US20050167474A1
公开(公告)日：2005-08-04
申请号：US11031361
申请日：2005-01-07
申请人： Yoshimi Kanno , Agasa Egashira , Hiroaki Ishikawa , Shunji Watanabe , Tsugio Sakai
发明人： Yoshimi Kanno , Agasa Egashira , Hiroaki Ishikawa , Shunji Watanabe , Tsugio Sakai
IPC分类号： H05K3/34 , B23K20/10 , B23K31/02 , H01M2/02 , H01M2/08 , H01M2/10 , H01M6/16 , H01M10/05 , H01M10/44
CPC分类号： H01M10/44 , B23K20/10 , H01M2/0222 , H01M2/08 , H01M10/0525 , H01M10/448 , H01M10/615 , H01M2300/0037 , H05K3/341 , Y10T29/49108 , Y10T29/4911 , Y10T29/49112 , Y10T29/49114 , Y10T29/49115
摘要： In a nonaqueous-electrolyte secondary-battery that is soldered to a circuit board by a reflow soldering process, there has been a problem that when a secondary battery that requires discharging a after assembling the battery that requires discharging after assembling the battery is subjected to reflow, battery characteristics degrade due to heat treatment. Discharge voltage at the end of the discharging is made to be higher than a discharge voltage value that is an inflectional value at the end of a voltage plateau region indicating a cell reaction in a discharge curve (discharge capacity in abscissa and discharge voltage in ordinate) of initial discharge, thereby degradation of the battery characteristics due to the reflow hear treatment can be suppressed.
摘要翻译：在通过回流焊接方法焊接到电路板的非水电解质二次电池中，存在如下问题：当组装电池后需要放电的电池需要放电的二次电池经受回流，电池特性由于热处理而降低。使放电结束时的放电电压高于表示放电曲线中的电池反应（横坐标放电容量，放电电压纵坐标）的电压平台区末端的折回值的放电电压值，的初始放电，由此可以抑制由于回流听觉处理引起的电池特性的劣化。

6. 发明授权

US06489062B1 Non-aqueous electrolyte secondary battery having heat-resistant electrodes 失效
标题翻译：具有耐热电极的非水电解质二次电池
公开(公告)号：US06489062B1
公开(公告)日：2002-12-03
申请号：US09465078
申请日：1999-12-16
申请人： Shunji Watanabe , Shinichi Takasugi , Hideharu Onodera , Toyoo Harada , Tsugio Sakai
发明人： Shunji Watanabe , Shinichi Takasugi , Hideharu Onodera , Toyoo Harada , Tsugio Sakai
IPC分类号： H01M440
CPC分类号： H01M4/131 , H01M2/0413 , H01M2/16 , H01M4/485 , H01M6/166 , H01M10/0525 , H01M2004/027
摘要： A non-aqueous electrolyte secondary battery capable of withstanding a reflow temperature has a positive electrode having a conductive material, a binder, and an electrode active material selected from the group consisting of LiCoO2, LiNiO2 and LiMn2O4. A negative electrode has a conductive material, a binder and an electrode active material selected from the group consisting of a titanium oxide having an anatase structure, lithium titanate having a spinel structure and a molybdenum oxide. An electrolyte has a supporting salt and a non-aqueous solvent having a boiling point greater than 200° C. A gasket is comprised of a material having a heat deformation temperature greater than 230° C. A separator is disposed between the positive electrode and the negative electrode and is comprised of a material having a heat deformation temperature greater than 230° C. At least one of the positive electrode and the negative electrode comprises an electrode heat-treated to a temperature of 250° C. to 450° C. for deactivating a thermally active portion of each of the conductive material, the binder and the electrode active material thereof.
摘要翻译：能够承受回流温度的非水电解质二次电池具有选自LiCoO 2，LiNiO 2和LiMn 2 O 4的导电材料，粘合剂和电极活性物质的正极。负极具有导电材料，粘合剂和选自具有锐钛矿结构的氧化钛，具有尖晶石结构的钛酸锂和氧化钼的电极活性材料。电解质具有支撑盐和沸点大于200℃的非水溶剂。垫片由热变形温度大于230℃的材料构成。隔板设置在正极和负极，并且由热变形温度大于230℃的材料构成。正极和负极中的至少一个包括热处理至250℃至450℃的电极，用于使导电材料，粘合剂及其电极活性物质的热活性部分失活。

7. 发明授权

US06459564B1 Electrical double layer capacitor and portable electronic apparatus equipped with electrical double layer capacitor 失效
标题翻译：电双层电容器和配备双电层电容器的便携式电子设备
公开(公告)号：US06459564B1
公开(公告)日：2002-10-01
申请号：US09490833
申请日：2000-01-25
申请人： Shunji Watanabe , Hideharu Onodera , Tsugio Sakai , Toyoo Harada , Yoshimi Kanno , Shinichi Takasugi , Tsuneaki Tamachi
发明人： Shunji Watanabe , Hideharu Onodera , Tsugio Sakai , Toyoo Harada , Yoshimi Kanno , Shinichi Takasugi , Tsuneaki Tamachi
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G11/04 , Y02E60/13 , Y02T10/7022 , Y10T29/417
摘要： An electrical double layer capacitor has an electrolyte comprised of a non-aqueous solvent and a supporting salt dissolved in the non-aqueous solvent. A pair of polarizing electrodes are disposed in confronting relation with one another. A separator is disposed between the polarizing electrodes. The supporting salt contained in the electrolyte exists only in regions proximate a surface of the polarizing electrodes when the electrical double layer capacitor is fully charged. The non-aqueous solvent contains a preselected amount of dissolved supporting salt calculated from a surface area of the polarizing electrodes and a size of a molecule of the supporting salt in an ionized state.
摘要翻译：电双层电容器具有由非水溶剂和溶解在非水溶剂中的支持盐构成的电解质。一对偏振电极彼此面对地设置。在极化电极之间设置隔板。包含在电解质中的支撑盐仅在双电层电容器充满电时仅存在于极化电极的表面附近的区域中。非水溶剂含有从极化电极的表面积计算的预选量的溶解的支持盐和离子化状态的支持盐的分子的大小。

8. 发明授权

US07169506B2 Electrochemical cell 有权
标题翻译：电化学电池
公开(公告)号：US07169506B2
公开(公告)日：2007-01-30
申请号：US10822993
申请日：2004-04-13
申请人： Shunji Watanabe , Yoshimi Kanno , Tsugio Sakai
发明人： Shunji Watanabe , Yoshimi Kanno , Tsugio Sakai
IPC分类号： H01M6/08 , H01M2/02
CPC分类号： H01M10/425 , B23K1/0008 , B23K2101/38 , H01M2/30
摘要： An electrochemical cell capable of reflow soldering has a terminal for connection to a circuit board. The terminal is fixed to either the positive pole can or the negative pole can, and the bottom surface of the other pole can which is not fixed to the terminal is provided with a layer consisting of at least one of Au, Sn, Sn-alloy and Ni.
摘要翻译：能够回流焊接的电化学电池具有用于连接到电路板的端子。端子固定在正极罐或负极罐上，另一个极的未固定在端子上的底面设有由Au，Sn，Sn合金中的至少一种构成的层和镍。

9. 发明申请

US20060127758A1 Negative electrode can, alkaline cell and production method for same 审中-公开
标题翻译：负电极罐，碱性电池及其制作方法相同
公开(公告)号：US20060127758A1
公开(公告)日：2006-06-15
申请号：US11288740
申请日：2005-11-29
申请人： Takeshi Shishido , Iwazou Takahashi , Shunji Watanabe , Tsugio Sakai
发明人： Takeshi Shishido , Iwazou Takahashi , Shunji Watanabe , Tsugio Sakai
IPC分类号： H01M2/02 , H01M4/42 , H01M4/54 , H01M4/50 , H01M2/08 , H01M10/04 , H01M4/66
CPC分类号： H01M2/0272 , H01M2/0222 , H01M2/0275 , H01M2/0287 , H01M2/0292 , H01M6/08 , H01M6/12 , Y10T29/49115
摘要： The invention provides a mercury-free alkaline cell which does not generate a hydrogen gas. The alkaline cell according to the invention contains a positive electrode, a negative electrode comprising zinc alloy powder, a separator which separates the positive electrode from the negative electrode, an alkaline electrolyte, a positive electrode can imparted with the positive electrode, a negative electrode can imparted with the negative electrode which has a tin-coated layer formed after subjected to a surface treatment with an electrically conductive polymer and comes in contact with the negative electrode via the tin-coated layer and a gasket interposed between the positive electrode can and the negative electrode can.
摘要翻译：本发明提供一种不产生氢气的无汞碱性电池。本发明的碱性电池含有正极，含有锌合金粉末的负极，将正极与负极分离的隔板，碱性电解质，能够赋予正极的正极，负极罐赋予负极，其具有在用导电聚合物进行表面处理之后形成的锡涂层，并且经由锡涂层与负极接触，并且插入在正极罐和负极之间的垫圈电极罐。

10. 发明授权

US06625008B2 Electrical double layer capacitor and portable electronic apparatus equipped with electrical double layer capacitor 失效
标题翻译：电双层电容器和配备双电层电容器的便携式电子设备
公开(公告)号：US06625008B2
公开(公告)日：2003-09-23
申请号：US10213258
申请日：2002-08-06
申请人： Shunji Watanabe , Hideharu Onodera , Tsugio Sakai , Toyoo Harada , Yoshimi Kanno , Shinichi Takasugi , Tsuneaki Tamachi
发明人： Shunji Watanabe , Hideharu Onodera , Tsugio Sakai , Toyoo Harada , Yoshimi Kanno , Shinichi Takasugi , Tsuneaki Tamachi
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G11/04 , Y02E60/13
摘要： An electrical double layer capacitor has an electrolyte included of a non-aqueous solvent and a supporting salt dissolved in the non-aqueous solvent. A pair of polarizing electrodes are disposed in confronting relation with one another. A separator is disposed between the polarizing electrodes. The supporting salt contained in the electrolyte exists only in regions proximate a surface of the polarizing electrodes when the electrical double layer capacitor is fully charged. When the electrical double layer capacitor is charged at 3.3 V for 24 hours, a charged current after 24 hours is in the range of from about 5 &mgr;A/cm2 to about 22 &mgr;A/cm2 per unit area of the polarizing electrodes.
摘要翻译：电双层电容器具有包含非水溶剂的电解质和溶解在非水溶剂中的支撑盐。一对偏振电极彼此面对地设置。在极化电极之间设置隔板。包含在电解质中的支撑盐仅在双电层电容器充满电时仅存在于极化电极的表面附近的区域中。当双电层电容器在3.3V充电24小时时，24小时后的充电电流在每单位面积偏振光的约5μA/ cm 2至约22μA/ cm 2的范围内电极。

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