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1. 发明申请

US20060134517A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20060134517A1
公开(公告)日：2006-06-22
申请号：US11300373
申请日：2005-12-15
申请人： Shouichirou Sawa , Atsushi Fukui , Takuya Sunagawa , Maruo Kamino
发明人： Shouichirou Sawa , Atsushi Fukui , Takuya Sunagawa , Maruo Kamino
IPC分类号： H01M4/58 , H01M4/48 , H01M10/40 , H01M4/62
CPC分类号： H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/364 , H01M4/386 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0567 , H01M2004/028
摘要： Charge-discharge cycle performance is improved in a lithium secondary battery utilizing a material containing silicon as a positive electrode active material. A lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a lithium-transition metal composite oxide, and a non-aqueous electrolyte. Lithium carbonate is added in the positive electrode (1), and carbon dioxide is dissolved in the non-aqueous electrolyte.
摘要翻译：使用含有硅作为正极活性物质的材料的锂二次电池，充放电循环性能提高。锂二次电池包括含有硅作为负极活性物质的负极（2），含有锂 - 过渡金属复合氧化物的正极（1）和非水电解质。在正极（1）中加入碳酸锂，二氧化碳溶解在非水电解液中。

2. 发明申请

US20060068290A1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US20060068290A1
公开(公告)日：2006-03-30
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/52 , H01M4/50 , H01M4/58
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCOzO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式为Li x Mn x Mn y CO的化学式表示的层状结构的锂 - 过渡金属复合氧化物其中a，x，y和z满足以下表达式：0 <= a <= 1.3，x + y + z = 1,0

3. 发明授权

US07682744B2 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US07682744B2
公开(公告)日：2010-03-23
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/00 , H01M4/58 , H01M4/50 , H01M6/04
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCozO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式LiaNixMnyCozO2表示的层状结构的锂 - 过渡金属复合氧化物，其中a，x，y和z满足以下表达式：0＆nlE; a＆nlE; 1.3，x + y + z = 1 ，0

4. 发明申请

US20060204846A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20060204846A1
公开(公告)日：2006-09-14
申请号：US11372219
申请日：2006-03-10
申请人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
发明人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
IPC分类号： H01M4/58 , H01M4/48
CPC分类号： H01M10/052 , H01M2/0257 , H01M2/0275 , H01M4/02 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M10/0567 , H01M10/0587 , H01M2004/021 , Y02T10/7011
摘要： A lithium secondary battery is provided capable of significantly improving charge-discharge cycle performance by preventing gas generation originating from decomposition of the non-aqueous electrolyte while preventing manufacturing cost from increasing. A lithium secondary battery is provided with: a power generating element accommodated in a flexible battery case (6), the power generating element including a negative electrode (2), a positive electrode (1), and a non-aqueous electrolyte. The negative electrode contains negative electrode active material particles composed of silicon and/or a silicon alloy. The positive electrode contains a positive electrode active material composed of a lithium-transition metal composite oxide. The non-aqueous electrolyte contains ions of at least one element selected from the group consisting of Co, Cu, Mg, Mn, Ni, Fe, and Zr.
摘要翻译：提供了一种锂二次电池，其能够通过防止来自非水电解质分解的气体产生而显着提高充放电循环性能，同时防止制造成本增加。锂二次电池设置有容纳在柔性电池壳体（6）中的发电元件，发电元件包括负极（2），正极（1）和非水电解质。负极含有由硅和/或硅合金构成的负极活性物质粒子。正极含有由锂过渡金属复合氧化物构成的正极活性物质。非水电解质含有选自Co，Cu，Mg，Mn，Ni，Fe和Zr中的至少一种元素的离子。

5. 发明授权

US08211569B2 Lithium secondary battery including a negative electrode which is a sintered layer of silicon particles and/or silicon alloy particles and a nonaqueous electrolyte containing carbon dioxide dissolved therein and method for producing same 有权
标题翻译：包括作为硅颗粒和/或硅合金颗粒的烧结层的负极和溶解有二氧化碳的非水电解质的锂二次电池及其制造方法
公开(公告)号：US08211569B2
公开(公告)日：2012-07-03
申请号：US10531047
申请日：2004-06-04
申请人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
IPC分类号： H01M6/14 , H01M4/134 , H01M4/1395
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要： A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译：一种可再充电锂电池，包括通过烧结制成的负极，作为集电体的导电金属箔的表面，含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层，正极和非水电解质，其特征在于，所述非水电解质含有溶解在其中的二氧化碳。

6. 发明申请

US20070202365A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20070202365A1
公开(公告)日：2007-08-30
申请号：US11709252
申请日：2007-02-22
申请人： Shouichirou Sawa , Kazuyuki Satou , Atsushi Fukui , Yasuyuki Kusumoto , Maruo Kamino
发明人： Shouichirou Sawa , Kazuyuki Satou , Atsushi Fukui , Yasuyuki Kusumoto , Maruo Kamino
IPC分类号： H01M14/00 , H01M4/58 , H01M4/62
CPC分类号： H01M4/134 , H01M4/622 , H01M4/661 , H01M2004/021 , H01M2010/4292
摘要： In a lithium secondary battery using negative electrode active material particles containing silicon, excellent charge-discharge characteristics are achieved and swelling of the negative electrode is minimized. A lithium secondary battery has a positive electrode containing a positive electrode active material, a negative electrode containing an active material layer and a current collector made of a conductive metal foil, and a non-aqueous electrolyte. The active material layer has a binder and active material particles containing silicon, and is formed by sintering the active material layer on a current collector surface in a non-oxidizing atmosphere. The active material particles have an average particle size of from 7.5-15 μm and a particle size distribution such that 60 volume % or more of the active material particles falls within the ±40% range of the average particle size, and the lithium secondary battery has a negative/positive electrode capacity ratio of 1.7 or greater.
摘要翻译：在使用含有硅的负极活性物质粒子的锂二次电池中，实现了优异的充放电特性，并使负极的膨胀最小化。锂二次电池具有包含正极活性物质的正极，含有活性物质层的负极和由导电性金属箔构成的集电体和非水电解质。活性物质层具有粘合剂和含有硅的活性物质颗粒，并且通过在非氧化性气氛中在集电体表面上烧结活性物质层而形成。活性物质粒子的平均粒径为7.5〜15μm，粒径分布为60体积％以上的活性物质粒子落入平均粒径的±40％范围内，锂二次电池负极/正极容量比为1.7以上。

7. 发明申请

US20060003226A1 Lithium secondary battery and method for producing same 有权
标题翻译：锂二次电池及其制造方法
公开(公告)号：US20060003226A1
公开(公告)日：2006-01-05
申请号：US10531047
申请日：2004-06-04
申请人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
IPC分类号： H01M4/58 , H01M10/40 , H01M4/66
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要： A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译：一种可再充电锂电池，包括通过烧结制成的负极，作为集电体的导电金属箔的表面，含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层，正极和非水电解质，其特征在于，所述非水电解质含有溶解在其中的二氧化碳。

8. 发明授权

US09413010B2 Lithium secondary battery and method for manufacturing the same 有权
标题翻译：锂二次电池及其制造方法
公开(公告)号：US09413010B2
公开(公告)日：2016-08-09
申请号：US13636811
申请日：2011-03-24
申请人： Atsushi Fukui , Taizo Sunano , Maruo Kamino
发明人： Atsushi Fukui , Taizo Sunano , Maruo Kamino
IPC分类号： H01M4/62 , H01M4/04 , H01M4/134 , H01M4/1395 , H01M10/052 , C08L79/08 , C08G73/10
CPC分类号： H01M4/622 , C08G73/1067 , C08G73/1082 , C08L79/08 , H01M4/04 , H01M4/0404 , H01M4/134 , H01M4/1395 , H01M10/052 , Y02E60/122 , Y02P70/54 , Y10T29/49115
摘要： Provided is a lithium secondary battery in which negative-electrode active material particles containing silicon and/or a silicon alloy are used and which prevents the occurrence of breakage of a binder itself and peel-off of the binder at the interfaces with the negative-electrode active material and the negative-electrode current collector and has a high energy density and an excellent cycle characteristic. The lithium secondary battery includes: a negative electrode in which a negative-electrode active material layer including negative-electrode active material particles containing silicon and/or a silicon alloy and a binder is formed on a surface of electrically conductive metal foil serving as a negative-electrode current collector; a positive electrode; and a nonaqueous electrolyte, wherein the binder contains a polyimide resin including a crosslinked structure formed by imidization of a hexavalent or higher-valent carboxylic acid or an anhydride thereof with a diamine.
摘要翻译：提供一种锂二次电池，其中使用含有硅和/或硅合金的负极活性物质颗粒，并且防止粘合剂本身的破裂发生和粘合剂在与负极的界面处的剥离活性物质和负极集电体，具有高能量密度和优异的循环特性。锂二次电池包括：在作为负极的导电性金属箔的表面上形成有负极活性物质层的负极，负极活性物质层包含含有硅和/或硅合金的负极活性物质粒子和粘合剂电极集电器; 正极; 和非水电解质，其中所述粘合剂含有通过将六价或更高价羧酸或其酸酐与二胺酰亚胺化而形成的交联结构的聚酰亚胺树脂。

9. 发明授权

US08349491B2 Lithium secondary battery and method of manufacturing the same 有权
公开(公告)号：US08349491B2
公开(公告)日：2013-01-08
申请号：US12385016
申请日：2009-03-27
申请人： Atsushi Fukui , Taizo Sunano , Maruo Kamino
发明人： Atsushi Fukui , Taizo Sunano , Maruo Kamino
IPC分类号： H01M4/62
CPC分类号： H01M10/052 , H01M4/134 , H01M4/621 , H01M4/622 , H01M4/661 , Y02T10/7011 , Y10T29/49115
摘要： A lithium secondary battery contains a negative electrode binder containing a polyimide resin having a structure represented by the following chemical formula (1), and the polyimide resin having a molecular weight distribution such that the weight ratio of a polyimide resin having a molecular weight of less than 100,000 and a polyimide resin having a molecular weight from 100,000 to less than 200,000 is from 50:50 to 90:10: where n is an integer equal to or greater than 1, and R is a functional group represented by the following chemical formula (2) or (3):

10. 发明申请

US20090087731A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20090087731A1
公开(公告)日：2009-04-02
申请号：US12232917
申请日：2008-09-25
申请人： Atsushi Fukui , Maruo Kamino
发明人： Atsushi Fukui , Maruo Kamino
IPC分类号： H01M2/02
CPC分类号： H01M10/0525 , H01M2/0217 , H01M4/131 , H01M4/134 , H01M4/624 , H01M10/0569 , H01M10/0587 , H01M2004/021
摘要： A lithium secondary battery includes: a positive electrode having a positive electrode active material layer disposed on a positive electrode current collector, the positive electrode active material layer containing a positive electrode binder and a positive electrode active material containing a layered lithium-transition metal composite oxide; a negative electrode having a negative electrode current collector and a negative electrode active material layer disposed on the negative electrode current collector, the negative electrode active material layer containing a negative electrode binder and a negative electrode active material containing particles of silicon and/or a silicon alloy; and a non-aqueous electrolyte. Al2O3 particles are firmly adhered to a surface of the lithium-transition metal composite oxide so that a BET specific surface area of the positive electrode active material after the adherence of the Al2O3 particles is from 1.5 times to 8 times greater than that before the adherence of the Al2O3 particles
摘要翻译：锂二次电池包括：具有设置在正极集电体上的正极活性物质层的正极，包含正极粘合剂的正极活性物质层和含有层状锂过渡金属复合氧化物的正极活性物质 ; 具有负极集电体和设置在负极集电体上的负极活性物质层的负极，含有负极活性物质的负极活性物质层和含有硅和/或硅的粒子的负极活性物质合金; 和非水电解质。 Al 2 O 3颗粒牢固地粘附到锂 - 过渡金属复合氧化物的表面上，使得在Al 2 O 3颗粒粘附之后的正极活性材料的BET比表面积比粘附前的比例大1.5倍至8倍 Al2O3颗粒

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