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1. 发明授权

US5475157A Process for producing aromatic hydroxylic compound 失效
标题翻译：制备芳香族羟基化合物的方法
公开(公告)号：US5475157A
公开(公告)日：1995-12-12
申请号：US256245
申请日：1994-09-02
申请人： Shintaro Araki , Hiroshi Iwasaki , Hiroyasu Ohno , Isao Hashimoto , Teruaki Mukaiyama
发明人： Shintaro Araki , Hiroshi Iwasaki , Hiroyasu Ohno , Isao Hashimoto , Teruaki Mukaiyama
IPC分类号： C07C37/08 , C07C45/53
CPC分类号： C07C37/08 , Y02P20/52
摘要： There is disclosed a process for producing an aromatic hydroxylic compound by acid decomposition of a hydroperoxide having the general formula (I) ##STR1## wherein Ar represents an aromatic hydrocarbon group having a valence of n; and n represents an integer of 1 or 2, in the presence of an acid catalyst, thereby to provide an aromatic hydroxylic compound having the general formula (II)Ar--(OH)n (II)wherein Ar and n are the same as above defined, characterized in that tetrafluoroboric acid, hexafluorosilicic acid or hexafluorophosphoric acid is used as the acid catalyst. According to this process, the aromatic hydroxylic compound is obtained in a high yield while the by-production of hydroxyacetone is effectively suppressed. In paricular, a more effective suppression of by-production of hydroxyacetone and a higher yield of the target compound can be achieved by carrying out the acid decomposition reaction in two stages wherein the first stage of the reaction is carried out in the first reactor at a temperature of 50.degree.-95.degree. C., the resultant reaction mixture is sent to the second reactor, and the second stage of the reaction is then carried out in the second reactor at a temperature of 80.degree.-120.degree. C.
摘要翻译： PCT No.PCT / JP93 / 01586 Sec。 371日期：1994年9月2日 102（e）1994年9月2日PCT 1993年11月1日PCT公布。公开号WO94 / 10115 PCT 日本公报1994年5月11日。公开了通过酸分解具有通式（I）c的化合价n为n的烃基的氢过氧化物制备芳族羟基化合物的方法。并且n表示1或2的整数，在酸催化剂的存在下，由此提供具有通式（II）的Ar-（OH）n（II）的芳族羟基化合物，其中Ar和n与上述相同其特征在于使用四氟硼酸，六氟硅酸或六氟磷酸作为酸催化剂。根据该方法，以高产率获得芳族羟基化合物，同时有效抑制羟基丙酮的副产物。在这种情况下，可以通过在两个阶段中进行酸分解反应来实现对羟基丙酮的副产物的更有效抑制和目标化合物的较高产率，其中反应的第一阶段在第一反应器中以温度为50-95℃，将所得反应混合物送至第二反应器，然后在第二反应器中在80-120℃的温度下进行第二阶段反应。

2. 发明授权

US4808726A Process for preparation of guanidine derivative 失效
标题翻译：胍衍生物的制备方法
公开(公告)号：US4808726A
公开(公告)日：1989-02-28
申请号：US91849
申请日：1987-09-01
申请人： Isao Hashimoto , Ikuo Tomino , Houji Kato , Noriaki Kihara , Teruaki Mukaiyama
发明人： Isao Hashimoto , Ikuo Tomino , Houji Kato , Noriaki Kihara , Teruaki Mukaiyama
IPC分类号： C07D233/54 , C07D233/64
CPC分类号： C07D233/64
摘要： N-cyano-N'-methyl-N"-(2-(5-methyl-4-imidazolylmethylthio)ethyl)guanidine (Cimetidine), which is valuable as an agent for controlling secretion of gastric acid, is prepared in a high yield by reacting N-cyano-N'-methyl-N"-(2-(butane-2,3-dionyl)thioethyl)-guanidine as the starting compound with an ammonium salt of a carboxylic acid and formaldehyde.

3. 发明授权

US06706863B2 Organic pigment with high transparency and hydrophobicity 失效
标题翻译：有机颜料具有高透明度和疏水性
公开(公告)号：US06706863B2
公开(公告)日：2004-03-16
申请号：US10204012
申请日：2002-08-15
申请人： Isao Hashimoto , Noboru Tsuda , Hiroshi Ohsawa , Tomonori Okazaki , Manabu Shiga , Kohei Ohtsuki
发明人： Isao Hashimoto , Noboru Tsuda , Hiroshi Ohsawa , Tomonori Okazaki , Manabu Shiga , Kohei Ohtsuki
IPC分类号： C09B3522
CPC分类号： C08K5/3447 , C09B35/033 , C09B35/22 , C09B41/001 , G03G9/091
摘要： The present invention provides Pigment Yellow 180 having an excellent transparency produced by using a fine slurry of 5-acetoacetylamino-benzimidazolone as a coupling component when Pigment Yellow 180 is produced by coupling reaction of 5-acetoacetylamino-benzimidazolone and diazo component obtained by diazotization of 1,2-bis(2-aminophenoxy)ethane.
摘要翻译：本发明提供了通过使用5-乙酰乙酰氨基 - 苯并咪唑酮作为偶联成分的细浆而产生的颜料黄180，通过将5-乙酰乙酰氨基 - 苯并咪唑酮与通过重氮化得到的重氮组分的偶联反应1 ，2-双（2-氨基苯氧基）乙烷。

4. 发明授权

US5510511A Process for preparing N,O-dialkylhydroxylamine, its salts or intermediates in their synthesis 失效
标题翻译：在其合成中制备N，O-二烷基羟胺，其盐或中间体的方法
公开(公告)号：US5510511A
公开(公告)日：1996-04-23
申请号：US97225
申请日：1993-07-27
申请人： Satoshi Inoki , Mitsuyuki Takesue , Isao Hashimoto , Noriaki Kihara , Kiyoaki Sugi
发明人： Satoshi Inoki , Mitsuyuki Takesue , Isao Hashimoto , Noriaki Kihara , Kiyoaki Sugi
IPC分类号： C07C239/20 , C07C271/12 , C07C261/00
CPC分类号： C07C271/12 , C07C239/20
摘要： A process for preparing N,O-dialkylhydroxycarbamic acid ester which comprises reacting hydroxylamine or its salt with dihydrocarbyl carbonate in the presence of a basic compound to prepare hydroxycarbamic acid ester and subsequently alkylating this compound with an alkylating agent; a process for recovering N,O-dialkylhydroxycarbamic acid ester which comprises azeotropically distilling the ester with water from a solution containing the ester; a process for preparing N,O-dialkylhydroxylamine which comprises hydrolyzing N,O-dialkylhydroxycarbamic acid ester in an aqueous solution or a hydrous solvent in the presence of an alkali; a process for purifying N,O-dialkylhydroxylamine hydrochloride which comprises adding aldehyde or ketone to a solution of N,O-dialkylhydroxylamine hydrochloride containing O-alkylhydroxylamine hydrochloride as impurities to convert the O-alkylhydroxylamine hydrochloride into O-alkyl aldoxime or O-alkyl ketoxime and subsequently separating the N,O-dialkylhydroxylamine hydrochloride from the reaction system; and a process for separating N,O-dialkylhydroxylamine hydrochloride which comprises (i) adding benzene or alkylated benzene to an aqueous solution containing N,O-dialkylhydroxylamine hydrochloride, azeotropically removing water or a hydrochloride solution, and, subsequently (ii)adding alcohol thereto to obtain N,O-dialkylhydroxylamine hydrochloride in the form of crystal.
摘要翻译：一种制备N，O-二烷基羟基氨基甲酸酯的方法，其包括使羟胺或其盐与二烃基碳酸酯在碱性化合物的存在下反应以制备羟基氨基甲酸酯，随后用烷基化剂烷基化该化合物; 一种回收N，O-二烷基羟基氨基甲酸酯的方法，该方法包括从含有酯的溶液中用水共沸蒸馏该酯; 一种制备N，O-二烷基羟胺的方法，其包括在碱存在下水溶液或含水溶剂中N，O-二烷基羟基氨基甲酸酯水解; 一种纯化N，O-二烷基羟胺盐酸盐的方法，其包括将醛或酮加入到含有O-烷基羟胺盐酸盐的N，O-二烷基羟胺盐酸盐的溶液中作为杂质，以将O-烷基羟胺盐酸盐转化为O-烷基羟基肟或O-烷基酮肟随后从反应体系中分离出N，O-二烷基羟胺盐酸盐; 以及分离N，O-二烷基羟胺盐酸盐的方法，其包括（i）将苯或烷基化苯加入到含有N，O-二烷基羟胺盐酸盐的水溶液中，共沸除去水或盐酸盐溶液，随后（ii）向其中加入醇得到晶体形式的N，O-二烷基羟胺盐酸盐。

5. 发明授权

US5266146A Microwave-powered plasma-generating apparatus and method 失效
标题翻译：微波功率等离子体发生装置及方法
公开(公告)号：US5266146A
公开(公告)日：1993-11-30
申请号：US763206
申请日：1991-09-20
申请人： Yasunori Ohno , Takashi Iga , Noriyuki Sakudo , Kenichi Natsui , Isao Hashimoto
发明人： Yasunori Ohno , Takashi Iga , Noriyuki Sakudo , Kenichi Natsui , Isao Hashimoto
IPC分类号： H01J27/18 , H01J37/08 , H01J37/32 , H01L21/00
CPC分类号： H01J37/32623 , H01J37/32357 , H01J37/3266
摘要： A plasma-generating apparatus has a plasma discharge chamber having a plasma-generation region. Microwave energy is applied, while introducing plasma-forming gas, and a magnetic field is applied to the plasma-generation region by an electromagnetic coil extending around the chamber. To enhance the field in the plasma-generation region while reducing it outside said region, and a permanent magnet arrangement is at least partly located radially within the coil so as to provide a unidirectional magnetic field which extends through the whole of the plasma-generation region as seen in radial cross-section and is oriented in the axial direction of the coil.

6. 发明授权

US5221051A Crushing apparatus and crushing method 失效
标题翻译：破碎装置和破碎方法
公开(公告)号：US5221051A
公开(公告)日：1993-06-22
申请号：US879289
申请日：1992-05-07
申请人： Isao Hashimoto , Seisuke Sawamura , Hiroshi Ueda , Yuji Yamamoto , Kanzaburo Sutoh , Mitsunari Ichikawa , Tsuneichi Shitara
发明人： Isao Hashimoto , Seisuke Sawamura , Hiroshi Ueda , Yuji Yamamoto , Kanzaburo Sutoh , Mitsunari Ichikawa , Tsuneichi Shitara
IPC分类号： B02C15/04 , B02C21/00 , B02C25/00 , C04B7/52
CPC分类号： B02C25/00 , B02C15/04 , B02C21/002
摘要： Materials such as cement clinker are crushed by utilizing a crushing apparatus including a vertical roller mill provided with a rotatable table and a plurality of rollers and a distributing device for distributing materials preliminarily crushed by the vertical roller mill. The materials to be crushed is fed into the vertical roller mill, the materials are crushed between the table and the rollers by a pressing force applied to the rollers and substantially the whole amount of the crushed materials is then taken out from the vertical roller mill and conveyed to the distributing device. The crushed materials once conveyed to the distributing device is returned partially as they are to the vertical roller mill and again crushed together with the materials newly fed into the vertical roller mill. The materials are returned to the vertical roller mill by about 20% or more in weight ratio with respect to the newly fed materials when cement clinker is utilized as the materials to be crushed. The returning amount of the crushed materials are controlled in accordance with a power consumption of the rotatable table of the vertical roller mill, and the pressing force of the rollers is controlled in accordance with a power consumption of the rotatable table of the vertical roller mill. The crushed materials are fed to a tube mill installed downstream the vertical roller mill for carrying out a secondary crushing operation.

7. 发明授权

US5193997A Apparatus for preheating granular material 失效
标题翻译：预处理颗粒材料的装置
公开(公告)号：US5193997A
公开(公告)日：1993-03-16
申请号：US719627
申请日：1991-06-24
申请人： Mikio Aoyama , Isao Hashimoto , Jun Tatebayashi
发明人： Mikio Aoyama , Isao Hashimoto , Jun Tatebayashi
IPC分类号： B01J8/24 , C04B2/10 , C04B7/44 , F27B15/00 , F27D13/00
CPC分类号： F27B15/003 , C04B2/10
摘要： An apparatus for preheating a granular material having a suspension preheater including a plurality of stages of cyclones arranged above a calcination furnace such that the granular material is preheated by waste gas from the calcination furnace as the granular material passes through the suspension preheater. The apparatus has a precalciner of fluidized-bed type or spouted-bed type connected, in place of a duct used in conventional apparatus, between a collecting cyclone directly connected to be calcination furnace and a first cyclone constituting the most downstream stage.

8. 发明授权

US4968341A Substituted aryloxyureas, processes for production thereof and uses thereof 失效
标题翻译：取代的芳氧基脲，其制备方法及其用途
公开(公告)号：US4968341A
公开(公告)日：1990-11-06
申请号：US232634
申请日：1988-08-16
申请人： Isao Hashimoto , Tatsuyodihi Ishida , Kazutaka Tsuru , Yuji Yamada , Takeshige Miyazawa , Yasuo Nakamura , Susumu Katou , Katsuya Takahashi
发明人： Isao Hashimoto , Tatsuyodihi Ishida , Kazutaka Tsuru , Yuji Yamada , Takeshige Miyazawa , Yasuo Nakamura , Susumu Katou , Katsuya Takahashi
IPC分类号： A01N43/28 , A01N43/32 , A01N43/38 , A01N47/28 , A01N47/32 , A01N47/34 , A01N47/38 , C07C275/64 , C07D209/02 , C07D209/44 , C07D213/64 , C07D213/68 , C07D213/79 , C07D213/80 , C07D213/84 , C07D217/06 , C07D221/22 , C07D237/14 , C07D239/34 , C07D239/56 , C07D241/18 , C07D251/26 , C07D251/30 , C07D251/38 , C07D263/06 , C07D265/02 , C07D265/06 , C07D295/215 , C07D453/06 , C07D487/08 , C07D498/08
CPC分类号： C07D213/64 , A01N43/28 , A01N43/32 , A01N43/38 , A01N47/28 , A01N47/32 , A01N47/34 , A01N47/38 , C07C275/64 , C07D209/02 , C07D209/44 , C07D213/68 , C07D213/79 , C07D213/80 , C07D213/84 , C07D217/06 , C07D221/22 , C07D237/14 , C07D239/34 , C07D239/56 , C07D241/18 , C07D251/26 , C07D251/30 , C07D251/38 , C07D263/06 , C07D265/02 , C07D265/06 , C07D295/215 , C07D453/06 , C07D487/08
摘要： Novel substituted aryloxyureas, processes for their production, and herbicides comprising them as active ingredients are provided.The substituted aryloxyureas exhibit an excellent herbicidal efficacy against weeds when applied, for example, to the weeds in a wide range of period from a preemergence stage to a growth stage.The substituted aryloxyureas of the invention have the excellent advantage of maintaining high safety on crops or crop plants in spite of their herbicidal efficacy.
摘要翻译：提供新型取代的芳氧基脲，它们的生产方法和包含它们作为活性成分的除草剂。取代的芳氧基脲在例如从芽前期到生长阶段的广泛范围内施用于杂草时，对杂草具有优异的除草效力。本发明的取代的芳氧基脲具有优异的优点，即尽管它们具有除草效力，仍保持对作物或作物的高安全性。

9. 发明授权

US4679739A Vertical roller mill 失效
标题翻译：立式辊磨机
公开(公告)号：US4679739A
公开(公告)日：1987-07-14
申请号：US745287
申请日：1985-06-14
申请人： Isao Hashimoto , Tosuke Kinoshita , Masahiro Uchida , Susumu Uchiyama
发明人： Isao Hashimoto , Tosuke Kinoshita , Masahiro Uchida , Susumu Uchiyama
IPC分类号： B02C15/00 , B02C15/04
CPC分类号： B02C15/04 , B02C15/004
摘要： A roller mill according to this invention includes a base and a table supported on the base, the table being adapted to be rotated on a generally vertical axis. The table has an annular groove formed in its top surface, the groove having a semicircular cross section. At least one roller is supported by the base above the table, each roller being rotatable on an axis which intersects with the vertical axis of the table. Each roller has an arcuate peripheral portion which forms part of a circle of curvature in cross section. The roller and the table rotate on their respective axes, and they are adapted to compress and mill material in the groove betweem them, a clearance which receives the material being formed between the peripheral portion of the roller and the groove. The roller has a wider axial dimension on the side which is inward radially of the table from a radial plane of the roller, this plane passing through the center of the circle of the peripheral part of the roller, than the axial dimension on the outward side of the table.
摘要翻译：根据本发明的辊磨机包括底座和支撑在基座上的工作台，该工作台适于在大致垂直的轴线上旋转。该工作台具有形成在其顶表面上的环形槽，该槽具有半圆形横截面。至少一个辊子由桌子上方的基座支撑，每个辊子可在与桌子的垂直轴线相交的轴线上旋转。每个辊具有弓形周边部分，其形成横截面为曲率圆的一部分。辊子和工作台在其各自的轴线上旋转，并且它们适于压缩和磨碎它们之间的槽中的材料，该间隙容纳形成在辊的周边部分和槽之间的材料。滚子在从滚子的径向平面向内径向延伸的一侧具有较宽的轴向尺寸，该平面通过滚子周边部分圆的中心，而不是在外侧的轴向尺寸的表。

10. 发明授权

US4267387A Process for preparation of aromatic hydroperoxides 失效
标题翻译：芳香族氢过氧化物的制备方法
公开(公告)号：US4267387A
公开(公告)日：1981-05-12
申请号：US85587
申请日：1979-10-17
申请人： Ichiro Imai , Isao Hashimoto , Keiji Suzuki , Hiroaki Nakagawa
发明人： Ichiro Imai , Isao Hashimoto , Keiji Suzuki , Hiroaki Nakagawa
IPC分类号： C07C67/00 , C07C407/00 , C07C409/08 , C07C179/035
CPC分类号： C07C409/08 , C07C407/00
摘要： An improved process for the preparation of an aromatic hydroperoxide by oxidizing a hydroxyalkyl-substituted aromatic compound having at least one hydroxyalkyl group directly bonded to an aromatic ring carbon of the aromatic compound and being represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 each are a lower alkyl group, with hydrogen peroxide in the presence of an acid catalyst in a heterogeneous system of a water-immiscible inert aromatic hydrocarbon solvent at a reaction temperature of up to about 70.degree. C. while removing by-product water as an azeotrope with the aromatic hydrocarbon solvent in the oxidation system; characterized in that said oxidation is carried out while feeding a vapor of a water-immiscible inert aromatic hydrocarbon solvent having a temperature higher than the reaction temperature but not exceeding about 90.degree. C. into a liquid phase of the oxidation system.
摘要翻译：通过氧化具有至少一个羟基烷基的羟烷基取代的芳族化合物来制备芳香族氢过氧化物的改进方法，所述羟烷基取代的芳族化合物直接与芳香族化合物的芳香环碳键合，并且由式（I）表示，其中R 1和R 2各自为低级烷基与过氧化氢在酸性催化剂存在下在水不混溶惰性芳烃溶剂的异相体系中反应温度高达约70℃，同时除去副产物水作为共沸物，氧化体系中的芳烃溶剂; 其特征在于，在将温度高于反应温度但不超过约90℃的与水不混溶的惰性芳族烃溶剂的蒸气进料到氧化系统的液相中的同时进行所述氧化。

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