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1. 发明授权

US08940270B2 Catalyst for decomposition of sulfur trioxide and hydrogen production process 有权
标题翻译：三氧化硫分解催化剂和氢气生产工艺
公开(公告)号：US08940270B2
公开(公告)日：2015-01-27
申请号：US13997473
申请日：2011-12-27
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： B01J23/847 , B01J23/26 , C01B3/06 , B01J23/22
CPC分类号： B01J23/8472 , B01J23/22 , B01J23/26 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1061 , B01J35/109 , B01J37/0201 , B01J37/0205 , B01J37/0242 , C01B3/068 , Y02A50/2348 , Y02E60/36
摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.
摘要翻译：提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

2. 发明申请

US20130280159A1 CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS 有权
标题翻译：用于分解三氧化硫和氢生产过程的催化剂
公开(公告)号：US20130280159A1
公开(公告)日：2013-10-24
申请号：US13997473
申请日：2011-12-27
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： B01J23/847 , B01J23/26 , C01B3/06 , B01J23/22
CPC分类号： B01J23/8472 , B01J23/22 , B01J23/26 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1061 , B01J35/109 , B01J37/0201 , B01J37/0205 , B01J37/0242 , C01B3/068 , Y02A50/2348 , Y02E60/36
摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.
摘要翻译：提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

3. 发明授权

US08932555B2 Catalyst for decomposition of sulfur trioxide and hydrogen production process 有权
标题翻译：三氧化硫分解催化剂和氢气生产工艺
公开(公告)号：US08932555B2
公开(公告)日：2015-01-13
申请号：US14118386
申请日：2012-05-18
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： C01B3/00 , C01B17/50 , C01B3/06 , B01J23/00 , B01J23/30 , B01J35/10 , B01J37/02 , B01J37/08 , C01B3/04 , C01B13/02 , B01J23/888 , B01J37/00 , B01J37/03 , B01J21/08
CPC分类号： C01B3/068 , B01J21/08 , B01J23/002 , B01J23/30 , B01J23/888 , B01J35/1057 , B01J35/1061 , B01J35/109 , B01J37/0018 , B01J37/0201 , B01J37/0205 , B01J37/024 , B01J37/033 , B01J37/088 , B01J2523/00 , C01B3/042 , C01B13/0203 , C01B13/0207 , C01B17/502 , Y02E60/324 , Y02E60/364 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/67 , B01J2523/47 , B01J2523/48 , B01J2523/3706 , B01J2523/3712 , B01J2523/3725
摘要： A sulfur trioxide decomposition catalyst, in particular, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process is disclosed. A sulfur trioxide decomposition catalyst that includes a composite oxide of tungsten, vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process that includes decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process is provided.
摘要翻译：公开了一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程制备氢气所需温度的三氧化硫分解催化剂。提供了包含钨，钒和至少一种选自过渡金属和稀土元素的金属的复合氧化物的三氧化硫分解催化剂。另外，提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法，进行通过S-I循环工序将三氧化硫分解成二氧化硫和氧的反应的氢气制造方法。

4. 发明申请

US20140086823A1 CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS 有权
标题翻译：用于分解三氧化硫和氢生产过程的催化剂
公开(公告)号：US20140086823A1
公开(公告)日：2014-03-27
申请号：US14118386
申请日：2012-05-18
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： C01B3/06 , C01B17/50
CPC分类号： C01B3/068 , B01J21/08 , B01J23/002 , B01J23/30 , B01J23/888 , B01J35/1057 , B01J35/1061 , B01J35/109 , B01J37/0018 , B01J37/0201 , B01J37/0205 , B01J37/024 , B01J37/033 , B01J37/088 , B01J2523/00 , C01B3/042 , C01B13/0203 , C01B13/0207 , C01B17/502 , Y02E60/324 , Y02E60/364 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/67 , B01J2523/47 , B01J2523/48 , B01J2523/3706 , B01J2523/3712 , B01J2523/3725
摘要： A sulfur trioxide decomposition catalyst, in particular, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process is disclosed. A sulfur trioxide decomposition catalyst that includes a composite oxide of tungsten, vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process that includes decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process is provided.
摘要翻译：公开了一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程制备氢气所需温度的三氧化硫分解催化剂。提供了包含钨，钒和至少一种选自过渡金属和稀土元素的金属的复合氧化物的三氧化硫分解催化剂。另外，提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法，进行通过S-I循环工序将三氧化硫分解成二氧化硫和氧的反应的氢气制造方法。

5. 发明授权

US08961922B2 Hydrogen production process 有权
标题翻译：氢气生产过程
公开(公告)号：US08961922B2
公开(公告)日：2015-02-24
申请号：US13996147
申请日：2011-12-07
申请人： Shinichi Takeshima , Norihiko Nakamura
发明人： Shinichi Takeshima , Norihiko Nakamura
IPC分类号： C01B3/02 , C01B3/06 , C01B17/50
CPC分类号： C01B3/068 , C01B17/502 , C01B17/503 , Y02E60/36 , Y02P20/134
摘要： A method for producing hydrogen from water is provided. The hydrogen production process includes splitting water into hydrogen and oxygen, wherein the process includes decomposing sulfuric acid into water, sulfur dioxide and oxygen through a reaction of formula (X1) by using solar thermal energy, wherein at least a part of the elementary reaction of formula (X1-1) is performed using thermal solar energy, and at least a part of the elementary reaction of formula (X1-2) is performed using additional thermal energy other than solar thermal energy, and wherein the heating temperature by the additional thermal energy is higher by 10° C. or more than the heating temperature by the solar thermal energy, and at least a part of the additional thermal energy is generated in a reaction vessel: (X1) H2SO4→H2O+SO2+1/2O2, (X1-1) H2SO4→H2O+SO3, and (X1-2) SO3→SO2+1/2O2.
摘要翻译：提供了一种从水中生产氢的方法。氢气生产过程包括将水分解成氢气和氧气，其中该方法包括通过使用太阳能热能将式（X 1）的反应将硫酸分解成水，二氧化硫和氧，其中至少一部分基本反应为使用热太阳能进行式（X1-1），并且使用除了太阳能热能之外的附加热能进行式（X1-2）的至少一部分元素反应，并且其中通过附加热量的加热温度能量高于10℃或高于太阳热能的加热温度，并且在反应容器中产生至少一部分附加热能：（X1）H 2 SO 4→H 2 O + SO 2 + 1 / 2O 2，（X1-1）H2SO4→H2O + SO3，（X1-2）SO3→SO2 + 1 / 2O2。

6. 发明授权

US08951497B2 Method and apparatus for producing hydrogen 有权
标题翻译：生产氢气的方法和装置
公开(公告)号：US08951497B2
公开(公告)日：2015-02-10
申请号：US12855236
申请日：2010-08-12
申请人： Shinichi Takeshima
发明人： Shinichi Takeshima
IPC分类号： C01B3/08 , C01B3/04 , C01B13/02
CPC分类号： C01B3/042 , C01B13/0207 , C01B13/0251 , C01B2210/0046 , Y02E60/364 , Y02P20/134
摘要： In the present invention, a method and apparatus for producing hydrogen by thermochemical water splitting are provided. The method for producing hydrogen of the present invention includes a reduction step of heating a high oxidation state redox material in an inert atmosphere to remove oxygen from the high oxidation state redox material, and thereby obtain a low oxidation state redox material and oxygen; and a hydrogen generation step of bringing water into contact with a low oxidation state redox material to oxidize the low oxidation state redox material and reduce the water, and thereby obtain a high oxidation state redox material and hydrogen. In the method for producing hydrogen of the present invention, the reduction step and the hydrogen generation step are performed switchingly in a same reaction vessel. Further, the apparatus for producing hydrogen of the present invention is used for performing the method for producing hydrogen of the present invention.
摘要翻译：在本发明中，提供了一种通过热化学水分解产生氢的方法和装置。本发明的制造氢的方法包括在惰性气氛中加热高氧化态氧化还原材料以从高氧化态氧化还原材料中除去氧的还原步骤，从而获得低氧化态氧化还原材料和氧; 以及使水与低氧化态氧化还原材料接触以氧化低氧化态氧化还原材料并降低水的氢生成步骤，从而获得高氧化态氧化还原材料和氢。在本发明的制造氢气的方法中，还原步骤和氢气生成步骤在相同的反应容器中进行切换。此外，本发明的氢气制造装置用于实施本发明的氢气制造方法。

7. 发明授权

US08382905B2 Plant-fiber-material transformation method 有权
标题翻译：植物纤维材料转化方法
公开(公告)号：US08382905B2
公开(公告)日：2013-02-26
申请号：US12597176
申请日：2008-04-25
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： C13K1/02
CPC分类号： C13K1/02 , C13K1/04
摘要： Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues and the cluster acid.
摘要翻译：植物纤维材料中所含的纤维素通过使用假熔融簇酸作为水解催化剂水解，生成糖，其中大部分是葡萄糖。葡萄糖生成后，使用有机溶剂使糖类沉淀，在水解过程中包含固化的糖类的糖类和析出的糖类与残基和簇酸分离。

8. 发明授权

US08206671B2 Porous composite oxide and production method thereof 有权
标题翻译：多孔复合氧化物及其制备方法
公开(公告)号：US08206671B2
公开(公告)日：2012-06-26
申请号：US12457034
申请日：2009-05-29
申请人： Shinichi Takeshima , Kohei Yoshida , Akio Koyama
发明人： Shinichi Takeshima , Kohei Yoshida , Akio Koyama
IPC分类号： C01G25/02
CPC分类号： B01J21/066 , B01D53/9445 , B01J23/002 , B01J23/02 , B01J23/10 , B01J35/0013 , B01J35/023 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B13/328 , C01F17/0018 , C01G25/00 , C01G25/02 , C01P2004/50 , C01P2004/64 , C01P2006/13 , C01P2006/16 , Y02T10/22 , B01J2523/24 , B01J2523/48 , B01J2523/3712 , B01J2523/3706
摘要： The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
摘要翻译：本发明提供一种多孔复合氧化物，其包含以二次或多种类型的金属元素为主成分的复合氧化物的一次粒子的聚集体形式的二次粒子的聚集体，并且在二次粒子的孔径为2〜100nm的介孔粒子; 其中，直径为10nm以上的二次粒子之间的中孔的百分比在氧气氛中在600℃下焙烧5小时后的总中孔体积的10％以上。

9. 发明申请

US20120100062A1 COMBINED PLANT 审中-公开
标题翻译：组合植物
公开(公告)号：US20120100062A1
公开(公告)日：2012-04-26
申请号：US13318223
申请日：2010-04-28
申请人： Norihiko Nakamura , Shigeki Sugiura , Shusei Obata , Shinichi Takeshima , Haruyuki Nakanishi , Yosuke Iida , Akinori Sato
发明人： Norihiko Nakamura , Shigeki Sugiura , Shusei Obata , Shinichi Takeshima , Haruyuki Nakanishi , Yosuke Iida , Akinori Sato
IPC分类号： C01C1/04 , B01J19/12 , C01B3/06
CPC分类号： C01C1/0405 , C01B3/025 , C01B3/042 , C01B3/063 , C01B3/08 , C01B21/04 , C01B2203/068 , C01C1/0488 , Y02E60/364 , Y02P20/52
摘要： A combined plant is provided. The combined plant of continuously supplying hydrogen and nitrogen to an ammonia synthesis facility that continuously synthesizes ammonia from hydrogen and nitrogen, the combined plant including: a hydrogen production facility for acquiring solar energy and producing hydrogen by utilizing a part of the acquired solar energy; a nitrogen production facility for producing nitrogen from air and supplying the nitrogen to the ammonia synthesis facility; and a hydrogen storage facility for storing the hydrogen produced by the hydrogen production facility and supplying the produced hydrogen to the ammonia synthesis facility.
摘要翻译：提供联合工厂。连续向氢气和氮气合成氨的氨合成设备连续提供氢气和氮气的组合工厂，该组合设备包括：利用部分获得的太阳能获得太阳能并产生氢气的氢气生产设备; 用于从空气生产氮气并将氮气供应到氨合成设备的氮气生产设备; 以及氢存储设备，用于存储由氢气生产设备产生的氢气并将产生的氢气供应到氨合成设备。

10. 发明申请

US20120004094A1 NANOPARTICLE CARRYING METHOD 有权
标题翻译：纳米粒子的携带方法
公开(公告)号：US20120004094A1
公开(公告)日：2012-01-05
申请号：US12673021
申请日：2009-03-18
申请人： Shinichi Takeshima , Toru Sasatani
发明人： Shinichi Takeshima , Toru Sasatani
IPC分类号： B01J31/02 , B01J31/26 , B01J31/04 , B82Y40/00
CPC分类号： B01J23/10 , B01D53/9422 , B01D2255/2065 , B01D2255/20707 , B01D2255/20738 , B01D2255/2092 , B01D2255/91 , B01D2255/9202 , B01J21/04 , B01J23/745 , B01J35/0013 , B01J35/006 , B01J37/0207 , B01J37/0211 , B01J37/031
摘要： A nanoparticle carrying method making a carrier adsorb ammonium ions, making the nanoparticles adsorb an organic acid, and making the carrier and the nanoparticles contact each other in a basic solution to thereby cause the carrier to adsorb the nanoparticles. Nanoparticles can be carried in high dispersion irrespective of superhydrophilicity.
摘要翻译：使载体吸附铵离子的纳米颗粒携带方法，使得纳米颗粒吸附有机酸，并使载体和纳米颗粒在碱性溶液中相互接触，从而使载体吸附纳米颗粒。无论超亲水性如何，纳米颗粒都可以承载高分散体。

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