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1. 发明授权

US5906730A Process for desulfurizing catalytically cracked gasoline 失效
标题翻译：催化裂化汽油脱硫工艺
公开(公告)号：US5906730A
公开(公告)日：1999-05-25
申请号：US686037
申请日：1996-07-25
申请人： Shigeto Hatanaka , Satoru Hikita , Osamu Sadakane , Tadao Miyama
发明人： Shigeto Hatanaka , Satoru Hikita , Osamu Sadakane , Tadao Miyama
IPC分类号： B01J23/24 , B01J23/75 , B01J23/755 , C07B61/00 , C10G45/06 , C10G45/08 , C10G65/04
CPC分类号： C10G65/04
摘要： A process for desulfurizing catalytically cracked gasoline containing sulfur compounds and olefin components, which comprises the steps of:1) first desulfurizing the catalytically cracked gasoline in the presence of a hydrodesulfurization catalyst at a desulfurization rate of 60 to 90%, a reaction temperature of 200 to 350.degree. C., a hydrogen partial pressure of 5 to 30 kg/cm.sup.2, a hydrogen/oil ratio of 500 to 3,000 scf/bbl, and a liquid hourly space velocity of 2 to 10 1/hr, said first desulfuriing step comprising supplying a feed having a hydrogen sulfide vapor concentration of not more than 0.1% by volume, and2) next desulfurizing the treated oil obtained in the first step in the presence of a hydrodesulfurization catalyst at a desulfurization rate of 60 to 90%, a reaction temperature of 200 to 300.degree. C., a hydrogen partial pressure of 5 to 15 kg/cm.sup.2, a hydrogen/oil ratio of 1,000 to 3,000 scf/bbl, and a liquid hourly space velocity of 2 to 10 1/hr, said second desulfurizing step comprising supplying a feed having a hydrogen sulfide vapor concentration of not more than 0.05% by volume. A reduction in octane number due to hydrogenation of olefin components is minimized while achieving a high desulfurization rate.
摘要翻译：一种脱硫含硫化合物和烯烃组分的催化裂化汽油的方法，包括以下步骤：1）在加氢脱硫催化剂存在下，以60〜90％的脱硫率，反应温度为200℃，先将催化裂化汽油脱硫至350℃，氢分压为5至30kg / cm2，氢/油比为500至3,000scf / bbl，液时空速为2至10l / hr，所述第一脱硫步骤包括供给硫化氢蒸汽浓度为0.1体积％以下的原料，以及2）在加氢脱硫催化剂的存在下，以60〜90％的脱硫率，对第一工序中得到的处理油进行下一步脱硫，反应温度为200〜300℃，氢分压为5〜15kg / cm2，氢/油比为1,000〜3,000scf / bbl，液时空速为2〜10l / hr，所述第二脱硫步骤供给硫化氢蒸汽浓度为0.05体积％以下的饲料。由于烯烃组分的氢化导致的辛烷值的降低最小化，同时达到高的脱硫速率。

2. 发明授权

US5853570A Process for desulfurizing catalytically cracked gasoline 失效
标题翻译：催化裂化汽油脱硫工艺
公开(公告)号：US5853570A
公开(公告)日：1998-12-29
申请号：US701957
申请日：1996-08-23
申请人： Shigeto Hatanaka , Osamu Sadakane , Satoru Hikita , Tadao Miyama
发明人： Shigeto Hatanaka , Osamu Sadakane , Satoru Hikita , Tadao Miyama
IPC分类号： C10G35/00 , B01J23/16 , B01J23/74 , C10G45/08 , C10G45/60
CPC分类号： C10G45/08 , C10G2400/02
摘要： A catalytically cracked gasoline feedstock is desulfurized under reaction conditions of a hydrogen feed rate measured at the reactor inlet of from 1 to 5 mols per mol of the feedstock oil and of from 5 to 50 mols per mol of the olefin components contained in the feedstock oil, a reaction temperature of from 200.degree. to 300.degree. C., a total pressure inside the reactor of from 10 to 20 kg/cm.sup.2 G, and a liquid hourly space velocity of from 2 to 8 l/hr, and using a catalyst which comprises a support mainly comprising alumina and having a surface area of 200 m.sup.2 /g or larger, wherein MoO.sub.3 in an amount of from 10 to 20 wt % and CoO in an amount of from 3 to 6 wt % in terms of inner content are fixed to the support, and the weight ratio of MoO.sub.3 to CoO is from 2.5 to 4.5.
摘要翻译：催化裂化汽油原料在反应器入口处测量的氢进料速率为每摩尔原料油1至5摩尔的反应条件和每摩尔原料油中所含的5至50摩尔烯烃组分的反应条件下脱硫反应温度为200-300℃，反应器内的总压为10至20kg / cm2G，液时空速为2-8升/小时，并使用包含主要包含氧化铝并且表面积为200m 2 / g或更大的载体，其中含量为10至20重量％的MoO 3和以内含量计为3至6重量％的CoO固定为载体，MoO 3与CoO的重量比为2.5〜4.5。

3. 发明授权

US6120679A Method of hydrodesulfurizing catalytic cracked gasoline 有权
标题翻译：加氢脱硫催化裂化汽油的方法
公开(公告)号：US6120679A
公开(公告)日：2000-09-19
申请号：US149294
申请日：1998-09-09
申请人： Shigeto Hatanaka , Osamu Sadakane
发明人： Shigeto Hatanaka , Osamu Sadakane
IPC分类号： B01J23/88 , B01J31/02 , B01J31/34 , C07B61/00 , C10G45/08 , C10G69/04 , C10L1/06 , C10L10/10 , C10G45/04
CPC分类号： C10G69/04 , B01J31/0237 , B01J31/0244 , B01J31/34 , C10G2400/02
摘要： A method of hydrodesulfurizing a catalytic cracked gasoline which comprises providing a presulfided catalyst modified with a basic organic nitrogen compound and contacting the catalytic cracked gasoline with the catalyst.
摘要翻译：一种加氢脱硫催化裂化汽油的方法，该方法包括提供用碱性有机氮化合物改性的预硫化催化剂并使催化裂化汽油与催化剂接触。

4. 发明授权

US06251263B1 Process and apparatus for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺及装置
公开(公告)号：US06251263B1
公开(公告)日：2001-06-26
申请号：US09377089
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6504
CPC分类号： B01J35/0006 , B01J8/04 , B01J23/88 , B01J23/888 , B01J2208/00371 , C10G2400/04
摘要： A hydrogenation region in a fixed bed reactor is defined with a first, a second and a third hydrogenation zones sequentially from the entrance of the reactor, and a sulfur-containing diesel gas oil feedstock is passed through the first, second and third hydrogenation zones sequentially under conditions of a temperature of 320 to 420° C., a pressure of 5 to 15 MPa, an LHSV of 0.5 to 3 h−1 and a hydrogen/oil ratio of 1000 to 5000 scfb, wherein (a) a catalyst consisting essentially of cobalt and molybdenum on a porous carrier containing alumina as a main ingredient is loaded in the first hydrogenation zone in an amount of 20 to 60 vol %, (b) a catalyst consisting essentially of nickel and tungsten on a porous carrier containing 85 to 99 wt % of alumina or amorphous silica-alumina and 1 to 15 wt % of zeolite is loaded in the second hydrogenation zone in an amount of 20 to 60 vol % and (c) a catalyst consisting essentially of cobalt and/or nickel and molybdenum on a porous carrier containing alumina as a main ingredient is loaded in the third hydrogenation zone in an amount of 10 to 30 vol %.
摘要翻译：固定床反应器中的氢化区域从反应器的入口顺序地由第一，第二和第三加氢区定义，并且含硫柴油原料按顺序通过第一，第二和第三加氢区在温度为320〜420℃，压力为5〜15MPa，LHSV为0.5〜3h -1，氢/油比为1000〜5000scfb的条件下，（a）基本上由在含有氧化铝作为主要成分的多孔载体上的钴和钼以20至60体积％的量装载在第一氢化区中，（b）主要由镍和钨组成的催化剂在含有85至99的多孔载体上氧化铝或无定形二氧化硅 - 氧化铝的重量％和1至15重量％的沸石以20至60体积％的量装载在第二氢化区中，和（c）基本上由钴和/或镍和钼组成的催化剂多孔载体包含以氧化铝为主要成分，以10〜30体积％的量负载在第3氢化区中。

5. 发明授权

US06217748B1 Process for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺
公开(公告)号：US06217748B1
公开(公告)日：2001-04-17
申请号：US09378001
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6502
CPC分类号： C10G65/00 , C10G2400/04
摘要： A process for hydrodesulfurization of a sulfur-containing petroleum hydrocarbon diesel gas oil comprising; hydrodesulfurizing a sulfur-containing petroleum hydrocarbon diesel gas oil feedstock, separating the hydrodesulfurized diesel gas oil feedstock into light and heavy fractions by distillation, hydrodesulfurizing further the separated heavy fraction, and mixing the further hydrodesulfurized heavy fraction and the separated light fraction into the hydrocarbon diesel gas oil.
摘要翻译：一种含硫石油烃柴油瓦斯油的加氢脱硫方法，包括：加氢脱硫含硫石油烃柴油瓦斯油原料，通过蒸馏将加氢脱硫柴油机原料分离成轻馏分，再加氢脱硫分离的重馏分，再将加氢脱硫重馏分与分离的轻馏分混合成烃柴油瓦斯油。

6. 发明授权

US06251262B1 Process for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺
公开(公告)号：US06251262B1
公开(公告)日：2001-06-26
申请号：US09377087
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6504
CPC分类号： C10G65/04 , C10G2400/04
摘要： Diesel gas oil feedstock with 1-3 wt % sulfur can be hydrodesulfurized to a diesel gas oil with 0.05 wt % or less sulfur and a Saybolt color of +20 or higher, by defining a hydrogenation region in a fixed bed reactor with a first hydrogenation zone for dibenzothiophene, 1-, 2- and 3-methyldibenzothiophenes, a second hydrogenation zone for 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene and a third hydrogenation zone for thiols, sulfides and other sulfur-containing substances.
摘要翻译：通过在具有第一氢化的固定床反应器中限定氢化区域，可以将具有1-3重量％硫的柴油瓦斯油原料加氢脱硫至具有0.05重量％或更少硫并且Saybolt颜色为+ 20以上的柴油瓦斯油二苯并噻吩，1-，2-和3-甲基二苯并噻吩的区域，4-甲基二苯并噻吩和4,6-二甲基二苯并噻吩的第二氢化区和用于硫醇，硫化物和其它含硫物质的第三氢化区。

7. 发明授权

US06884272B2 Fuel for fuel cell system 失效
标题翻译：燃料电池系统燃料
公开(公告)号：US06884272B2
公开(公告)日：2005-04-26
申请号：US10240748
申请日：2001-04-10
申请人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
发明人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
IPC分类号： C01B3/32 , C01B3/48 , C01B3/58 , C10L1/02 , H01M8/06 , H01M8/10 , C10L1/18
CPC分类号： H01M8/0612 , C01B3/323 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/085 , C01B2203/1064 , C01B2203/1211 , C01B2203/1288 , C01B2203/1652 , C10L1/02 , H01M8/0618 , H01M8/1007
摘要： The present invention relates to a fuel for a fuel cell system comprising 5 vol. % or more of hydrocarbons based on the whole fuel, and 0.5-20 mass % of oxygenates in terms of an oxygen content based on the whole fuel, wherein the content of hydrocarbon compounds having a carbon number of 4 is 15 vol. % or less, the content of hydrocarbon compounds having a carbon number of 5 is 5 vol. % or more, the content of hydrocarbon compounds having a carbon number of 6 is 10 vol. % or more, the content of hydrocarbon compounds having carbon numbers of 7 and 8 in total is 20 vol. % or more, and the content of hydrocarbon compounds having carbon numbers of 10 or more is 20 vol. % or less.
摘要翻译：本发明涉及一种用于燃料电池系统的燃料，包括5体积％基于全部燃料的烃的％以上，以及基于全部燃料的氧含量为0.5〜20质量％的含氧化合物，其中碳数为4的烃化合物的含量为15体积％。％以下，碳数为5的烃化合物的含量为5体积％。％以上，碳数为6的烃化合物的含量为10体积％。％以上，碳数为7〜8的碳氢化合物的总量为20体积％。％以上，碳数为10以上的烃化合物的含量为20体积％。％或更少。

8. 发明授权

US06958117B2 Fuel for use in a fuel cell system 失效
标题翻译：用于燃料电池系统的燃料
公开(公告)号：US06958117B2
公开(公告)日：2005-10-25
申请号：US10240742
申请日：2001-04-10
申请人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
发明人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
IPC分类号： C01B3/48 , C01B3/58 , C10L1/04 , H01M8/06 , H01M8/10
CPC分类号： C01B3/48 , C01B3/583 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/085 , C01B2203/1064 , C01B2203/1205 , C01B2203/1211 , C01B2203/1247 , C01B2203/1288 , C01B2203/1652 , C01B2203/80 , C10L1/04 , H01M8/04201 , H01M8/0612 , H01M8/0618 , H01M8/0668 , H01M8/1007 , H01M2250/00 , H01M2250/40 , Y02E60/56
摘要： A fuel for a fuel cell system comprising hydrocarbon compounds, which fuel has distillation properties of the initial boiling point (initial boiling point 0) in distillation of 24° C. or higher and 40° C. or lower, the 10 vol. % distillation temperature (T10) of 25° C. or higher and 50° C. or lower, the 90 vol. % distillation temperature (T90) of 45° C. or higher and 130° C. or lower, and the final boiling point in distillation of 55° C. or higher and 150° C. or lower. The fuel for a fuel cell system has a high power generation quantity per weight, a high power generation quantity per CO2 emission, a low fuel consumption, a small quantity of evaporative gas (evapo-emission), small deterioration of a fuel cell system comprising such as a reforming catalyst, a water gas shift reaction catalyst, a carbon monoxide removal catalyst, fuel cell stacks and the like to maintain the initial performances for a long duration, good handling properties in terms of storage stability and inflammability, and a low preheating energy.
摘要翻译：一种用于燃料电池系统的燃料，其包含烃化合物，该燃料在蒸馏中具有沸点为24℃或更高和40℃或更低的初沸点（初始沸点为0）的蒸馏性能。 25℃或更高和50℃或更低的％蒸馏温度（T 10 N），90体积％ 45℃或更高和130℃或更低的蒸馏温度（T 90℃），蒸馏的最终沸点为55℃或更高和150℃或更低。用于燃料电池系统的燃料具有每重量的高发电量，每CO 2排放的高发电量，低燃料消耗量，少量蒸发气体（蒸发发射），包括诸如重整催化剂，水煤气变换反应催化剂，一氧化碳去除催化剂，燃料电池堆等的燃料电池系统的小的劣化，以保持长时间的初始性能，在储存方面具有良好的处理性能稳定性和易燃性，以及低预热能量。

9. 发明授权

US06837909B2 Fuel for use in a fuel cell system 失效
标题翻译：用于燃料电池系统的燃料
公开(公告)号：US06837909B2
公开(公告)日：2005-01-04
申请号：US10240743
申请日：2001-04-10
申请人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
发明人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
IPC分类号： G11B7/254 , C10L1/04
CPC分类号： G11B7/254
摘要： A fuel for a fuel cell system comprising hydrocarbon compounds, wherein a content of saturates is 30 vol. % or more, a content of olefins is 35 vol. % or less and a content of aromatics is 50 vol. % or less. The fuel for a fuel cell system has a high power generation quantity per weight, a high power generation quantity per CO2 emission, a low fuel consumption, a small quantity of evaporative gas (evapo-emission), small deterioration of a fuel cell system comprising such as a reforming catalyst, a water gas shift reaction catalyst, a carbon monoxide removal catalyst, fuel cell stacks and the like to maintain the initial performances for a long duration, good handling properties in terms of storage stability and inflammability, and a low preheating energy.
摘要翻译：一种用于包含烃化合物的燃料电池系统的燃料，其中饱和物的含量为30体积％。％以上，烯烃的含量为35体积％。％以下，芳香剂含量为50体积％。％或更少。用于燃料电池系统的燃料具有每重量的高发电量，每CO 2排放的高发电量，低燃料消耗量，少量蒸发气体（蒸发发射），燃料电池系统的小的劣化，包括例如重整催化剂，水煤气变换反应催化剂，一氧化碳去除催化剂，燃料电池堆等，以保持长时间的初始性能，在储存稳定性和易燃性方面具有良好的操作性能，以及低预热能源。

10. 发明授权

US06824573B2 Fuel for use in fuel cell 失效
标题翻译：用于燃料电池的燃料
公开(公告)号：US06824573B2
公开(公告)日：2004-11-30
申请号：US10240746
申请日：2002-10-10
申请人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
发明人： Kenichirou Saitou , Iwao Anzai , Osamu Sadakane , Michiro Matsubara
IPC分类号： C10L0118
CPC分类号： C01B3/48 , C01B3/323 , C01B3/583 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/085 , C01B2203/1064 , C01B2203/1205 , C01B2203/1288 , C01B2203/1652 , C10L1/02 , H01M8/0612 , H01M8/0618 , H01M8/1007
摘要： A fuel for a fuel cell system comprising 0.5-40 mass % of oxygenates in terms of an oxygen content based on the whole fuel. The fuel for a fuel cell system has a high power generation quantity per weight, a high power generation quantity per CO2 emission, a low fuel consumption, a small evaporative gas (evapo-emission), small deterioration of a fuel cell system comprising such as a reforming catalyst, an aqueous gas shift reaction catalyst, a carbon monoxide removal catalyst, fuel cell stacks and the like to maintain the initial performances for a long duration, good handling properties in view of storage stability and inflammability and a low preheating heat quantity.
摘要翻译：一种用于燃料电池系统的燃料，其以基于整个燃料的氧含量计含有0.5-40质量％的含氧化合物。用于燃料电池系统的燃料具有每重量的高发电量，每二氧化碳排放的高发电量，低燃料消耗量，小蒸发气体（蒸发发射），燃料电池系统的劣化，包括例如重整催化剂，含水气体转换反应催化剂，一氧化碳去除催化剂，燃料电池堆等，以保持长时间的初始性能，考虑到储存稳定性和易燃性以及低预热热量的良好的操作性能。

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