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1. 发明授权

US4789610A Solid-electrolyte secondary cell 失效
标题翻译：固体电解质二次电池
公开(公告)号：US4789610A
公开(公告)日：1988-12-06
申请号：US95146
申请日：1987-09-11
申请人： Shigeo Kondo , Tadashi Sotomura , Teruhisa Kanbara , Satoshi Sekido
发明人： Shigeo Kondo , Tadashi Sotomura , Teruhisa Kanbara , Satoshi Sekido
IPC分类号： H01M4/136 , H01M4/58 , H01M10/054 , H01M10/0562 , H01M6/18
CPC分类号： H01M10/0562 , H01M4/581
摘要： A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu.sub.x Mo.sub.6 S.sub.8), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm.sup.2, can stand high temperatures of up to 100.degree. C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K.sub.q Rb.sub.1-q Cu.sub.4 I.sub.2-p Cl.sub.3+3 (0.ltoreq.q.ltoreq.0.5, 0.25.ltoreq.p.ltoreq.1.0) for both positive and negative electrodes.
摘要翻译：提供了由铜螯合物（CuxMo6S8）和铜离子导电性固体电解质构成的正极和负极的固体电解质二次电池。该二次电池能够以高达约1mA / cm 2的电流充电，可以承受高达100℃的高温，并且即使在长时间充电和放电之后也保持其初始性能。通过使用铜螯合物和由KqRb1-qCu4I2-pCl3 + 3（0≤q≤0.5）表示的铜离子导电固体电解质的热处理混合物，也提供了在二次加注期间电压降小的电池，0.25

2. 发明授权

US5324599A Reversible electrode material 失效
标题翻译：可逆电极材料
公开(公告)号：US5324599A
公开(公告)日：1994-06-28
申请号：US826000
申请日：1992-01-27
申请人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
发明人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
IPC分类号： H01M4/60 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01M10/052 , H01M10/0565 , H01M4/60
摘要： The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.
摘要翻译：本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物，其中通过电解还原将二硫键的SS键切割，形成硫 - 金属离子键或硫质子键，硫金属离子键或硫质子键通过电解氧化而重新形成SS键。本发明还提供一种锂可再充电电池，其包含阴极，固体电解质和阳极，其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。

3. 发明授权

US5275750A Method of manufacturing a solid polymer electrolyte 失效
标题翻译：固体高分子电解质的制造方法
公开(公告)号：US5275750A
公开(公告)日：1994-01-04
申请号：US916963
申请日：1992-07-20
申请人： Yoshiko Sato , Hiroshi Uemachi , Teruhisa Kanbara , Tadashi Sotomura , Kenichi Takeyama
发明人： Yoshiko Sato , Hiroshi Uemachi , Teruhisa Kanbara , Tadashi Sotomura , Kenichi Takeyama
IPC分类号： C08F290/06 , G02F1/15 , H01B1/12 , H01G9/02 , H01G9/025 , H01M10/052 , H01M10/0565
CPC分类号： H01G9/025 , C08F290/062 , H01B1/122 , H01M10/052 , H01M10/0565 , G02F1/1525
摘要： A method of manufacturing a solid polymer electrolyte which comprises polymerizing an ester polymethoxyoxyalkylene, a diester polyoxyalkylene, an oxycompound having a double bond, and an inorganic salt, and the solid polymer electrolyte thus obtained. The electrolyte is suitable for application in electrochemical devices such as primary or secondary battery, condenser or electrochromic display.
摘要翻译：一种固体高分子电解质的制造方法，其特征在于，聚酯化聚甲氧基氧化烯，二酯聚氧化烯，具有双键的氧化合物和无机盐，以及由此得到的固体高分子电解质。电解质适用于电化学装置，如一次或二次电池，冷凝器或电致变色显示。

4. 发明授权

US5388026A Electrolytic capacitor and method for producing the same 失效
标题翻译：电解电容器及其制造方法
公开(公告)号：US5388026A
公开(公告)日：1995-02-07
申请号：US171766
申请日：1993-12-22
申请人： Teruhisa Kanbara , Yuichiro Tsubaki , Tadashi Sotomura , Kenichi Takeyama
发明人： Teruhisa Kanbara , Yuichiro Tsubaki , Tadashi Sotomura , Kenichi Takeyama
IPC分类号： H01G9/02 , H01G9/025
CPC分类号： H01G9/025
摘要： An electrolyte of electrolytic capacitor comprises at least one ammonium salt and at least one polyether polyol having a skeletal structure represented by the formula: ##STR1## where, each of Rs independently represents a hydrogen atom, an optionally substituted isocyanate residue or acrylic residue which may be the same as or different from one another; m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2 and n.sub.3 each represent a positive integer, and the ends of the isocyanate residues or the acrylic residues are 3-dimensionally linked.
摘要翻译：电解电容器的电解质包含至少一种铵盐和至少一种具有由下式表示的骨架结构的聚醚多元醇：其中，各自各自独立地表示氢原子，任选取代的异氰酸酯残基或丙烯酸残基，彼此相同或不同; m1，m2，m3，n1，n2和n3各自表示正整数，异氰酸酯残基或丙烯酸残基的末端是三维连接的。

5. 发明授权

US5344499A Electric device of hydrogenated amorphous silicon and method of manufacture 失效
标题翻译：氢化非晶硅电气装置及其制造方法
公开(公告)号：US5344499A
公开(公告)日：1994-09-06
申请号：US978175
申请日：1992-11-17
申请人： Teruhisa Kanbara , Shigeo Kondo
发明人： Teruhisa Kanbara , Shigeo Kondo
IPC分类号： H01L31/0224 , H01L31/105 , H01L31/20 , H01L31/0392 , H01L31/0376
CPC分类号： H01L31/022408 , H01L31/1055 , H01L31/202 , Y02E10/50 , Y02P70/521
摘要： The electro-migration of electrode metal takes place under an elevated temperature condition in amorphous silicon devices having conventional PI-type, NI-type, or PIN-type hydrogenated amorphous silicon layered structures, which substantially degrades the electrical characteristics of the devices. This problem is solved by forming a chemically inactive layer consisting mainly of amorphous silicon oxide on the surface of amorphous silicon layer by an aqueous washing and drying process, to establish electrical contacts through the chemically inactive layer between the hydrogenated amorphous silicon layer and either a collector electrode or a transparent electrode. This structure not only prevents such electromigration of electrode metal, but it also allows a greater freedom for choosing a material for the collector electrode.
摘要翻译：电极金属的电迁移在具有常规PI型，NI型或PIN型氢化非晶硅层状结构的非晶硅器件中在升高的温度条件下进行，这大大降低了器件的电特性。该问题通过在非晶硅层的表面上通过水洗和干燥工艺形成主要由非晶硅氧化物组成的化学惰性层来形成，以通过氢化非晶硅层和收集器之间的化学惰性层建立电接触电极或透明电极。该结构不仅防止电极金属的这种电迁移，而且还允许选择用于集电极的材料的更大的自由度。

6. 发明授权

US07414004B2 Gas diffusion layer, electrode and membrane electrode assembly for fuel cell, and production methods thereof 有权
标题翻译：用于燃料电池的气体扩散层，电极和膜电极组件及其制造方法
公开(公告)号：US07414004B2
公开(公告)日：2008-08-19
申请号：US11002574
申请日：2004-12-03
申请人： Akihiko Yoshida , Yoichiro Tsuji , Masaki Yamauchi , Yoshihiro Hori , Makoto Uchida , Hisaaki Gyoten , Teruhisa Kanbara
发明人： Akihiko Yoshida , Yoichiro Tsuji , Masaki Yamauchi , Yoshihiro Hori , Makoto Uchida , Hisaaki Gyoten , Teruhisa Kanbara
IPC分类号： H01M4/88
CPC分类号： H01M8/023 , H01M4/8605 , H01M8/0234 , H01M8/0243 , Y02P70/56
摘要： The present invention provides a gas diffusion layer for a fuel cell which has proper rigidity, is easy to handle and contributes to the improvement of the productivity of fuel cells. A method for producing a gas diffusion layer for a fuel cell including a first step of: impregnating a conductive porous substrate made of a conductive carbon fiber cloth or conductive carbon fiber felt with a first dispersion containing a first fluorocarbon resin having thermoplasticity; and baking the first conductive porous substrate at a first baking temperature of not less than the melting point of the first fluorocarbon resin and less than the decomposition temperature of the first fluorocarbon resin to enhance the rigidity of the conductive porous substrate.
摘要翻译：本发明提供一种燃料电池用气体扩散层，其具有适当的刚性，易于处理并有助于提高燃料电池的生产率。一种燃料电池用气体扩散层的制造方法，其特征在于，包括以下步骤：浸渍由导电性碳纤维布或导电性碳纤维毡制成的导电性多孔质基材，所述第一分散体含有具有热塑性的第一氟碳树脂; 在不低于第一氟碳树脂的熔点的第一烘烤温度和低于第一氟碳树脂的分解温度的条件下烘烤第一导电性多孔质基材，以提高导电性多孔质基材的刚性。

7. 发明授权

US07220514B2 Polymer electrolyte fuel cell 有权
标题翻译：聚合物电解质燃料电池
公开(公告)号：US07220514B2
公开(公告)日：2007-05-22
申请号：US10335958
申请日：2003-01-03
申请人： Eiichi Yasumoto , Akihiko Yoshida , Makoto Uchida , Hisaaki Gyoten , Kazuhito Hatoh , Yasushi Sugawara , Junji Morita , Teruhisa Kanbara , Yasuo Takebe , Masato Hosaka , Junji Niikura
发明人： Eiichi Yasumoto , Akihiko Yoshida , Makoto Uchida , Hisaaki Gyoten , Kazuhito Hatoh , Yasushi Sugawara , Junji Morita , Teruhisa Kanbara , Yasuo Takebe , Masato Hosaka , Junji Niikura
IPC分类号： H01M4/96 , H01M8/10 , H01M4/88
CPC分类号： H01M4/8605 , H01M4/861 , H01M4/8814 , H01M4/8821 , H01M4/8828 , H01M4/921 , H01M4/926 , H01M8/0234 , H01M2008/1095
摘要： In a polymer electrolyte fuel cell including a hydrogen ion conductive polymer electrolyte membrane; a pair of electrodes composed of catalyst layers sandwiching the hydrogen ion conductive polymer electrolyte membrane between them and gas diffusion layers in contact with the catalyst layers; a conductive separator plate having a gas flow channel for supplying a fuel gas to one of the electrodes; and a conductive separator plate having a gas flow channel for supplying an oxidant gas to the other electrode, in order to bring a hydrogen ion conductive polymer electrolyte and a catalyst metal of the catalyst layers containing the hydrogen ion conductive polymer electrolyte and conductive carbon particles carrying the catalyst metal sufficiently and uniformly into contact with each other, the polymer electrolyte is provided in pores of an agglomerate structure of the conductive carbon particles. Consequently, the reaction area inside the electrodes is increased, and higher performance is exhibited.
摘要翻译：在具有氢离子导电性高分子电解质膜的固体高分子型燃料电池中，由催化剂层构成的一对电极，夹在其间的氢离子导电性高分子电解质膜和与催化剂层接触的气体扩散层; 具有用于将燃料气体供给到所述电极之一的气体流路的导电性隔板; 以及具有用于向另一个电极供给氧化剂气体的气体流动通道的导电隔板，以便使氢离子导电聚合物电解质和含有氢离子导电聚合物电解质的催化剂层和催化剂层的催化剂金属携带催化剂金属彼此充分均匀地接触，聚合物电解质被提供在导电碳颗粒的附聚结构的孔中。因此，电极内的反应区域增加，表现出更高的性能。

8. 发明授权

US06881510B1 Method for resorting characteristics of polymer electrolyte fuel cell 有权
标题翻译：采用聚合物电解质燃料电池特性的方法
公开(公告)号：US06881510B1
公开(公告)日：2005-04-19
申请号：US10088111
申请日：2000-09-14
申请人： Hisaaki Gyoten , Teruhisa Kanbara , Makoto Uchida , Kazuhito Hatoh , Osamu Sakai
发明人： Hisaaki Gyoten , Teruhisa Kanbara , Makoto Uchida , Kazuhito Hatoh , Osamu Sakai
IPC分类号： H01M8/02 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/24 , H01M8/18
CPC分类号： H01M8/0662 , H01M8/0258 , H01M8/0267 , H01M8/0273 , H01M8/04104 , H01M8/04223 , H01M8/04679 , H01M8/0488 , H01M8/0491 , H01M8/04952 , H01M8/241 , H01M8/2483 , H01M2300/0082
摘要： The present invention restores the performance of a fuel cell by: operating the cell in a loaded current mode different from that of a normal operation for a predetermined time; supplying an oxidant gas and a fuel gas to an anode and a cathode respectively and outputting a current from a cell body with the polarity being inverted; supplying a pressurized gas to at least one of the cathode and anode in an amount not less than 1.5 times as much as that in the normal operation or supplying oxygen to the cathode; or injecting a cleaning solution into the cathode and anode through a gas flow path. Consequently, it is possible to effectively restore a degraded performance of a polymer electrolyte fuel cell caused by a long operation.
摘要翻译：本发明通过以下方式恢复燃料电池的性能：在与预定时间的正常运行不同的负载电流模式下操作电池; 分别向阳极和阴极供给氧化剂气体和燃料气体，并从极性反转的电池体输出电流; 向阴极和阳极中的至少一个供给加压气体，其量不小于正常操作的1.5倍或向阴极供应氧气; 或者通过气体流动路径将清洁溶液注入阴极和阳极。因此，可以有效地恢复由长时间操作引起的聚合物电解质燃料电池的劣化性能。

9. 发明授权

US06689504B1 Fuel cell stack with separator of a laminate structure 失效
标题翻译：具有层压结构隔板的燃料电池堆
公开(公告)号：US06689504B1
公开(公告)日：2004-02-10
申请号：US09786728
申请日：2001-03-08
申请人： Toshihiro Matsumoto , Kazuhito Hatoh , Hisaaki Gyoten , Hideo Ohara , Kazufumi Nishida , Teruhisa Kanbara
发明人： Toshihiro Matsumoto , Kazuhito Hatoh , Hisaaki Gyoten , Hideo Ohara , Kazufumi Nishida , Teruhisa Kanbara
IPC分类号： H01M802
CPC分类号： H01M8/0206 , H01M8/0228 , H01M8/0263 , H01M8/0271 , H01M8/1007 , H01M8/241 , H01M8/247 , H01M8/2483 , H01M2300/0082
摘要： The present invention provides a fuel cell stack including a plurality of unit cells laid one upon another. Each of the unit cells includes an electrolyte, a pair of electrodes that are arranged across the electrolyte and respectively have a catalytic reaction layer, and a separator having means for feeding a supply of gaseous fuel to one of the electrodes and a supply of oxidant gas to the other of the electrodes. The separator is a laminate including a gas-tight conductive plate A and another conductive plate B having at least one slit, which continuously meanders from one end to another end of the conductive plate B. The technique of the present invention gives a compact fuel cell stack assembled by a simple process.
摘要翻译：本发明提供一种燃料电池堆，其包括彼此叠置的多个单元电池。每个单元电池包括电解质，一对电极，其布置在电解质两侧并分别具有催化反应层，以及具有用于将气态燃料供给到电极之一的装置和用于提供氧化剂气体的装置的隔板到另一个电极。隔板是包括气密导电板A和具有至少一个狭缝的另一个导电板B的层压体，该导电板B从导电板B的一端连续地弯曲到另一端。本发明的技术给出了紧凑的燃料电池堆栈通过简单的过程组装。

10. 发明授权

US06329093B1 Polymer electrolyte fuel cell stack 有权
标题翻译：聚合物电解质燃料电池堆
公开(公告)号：US06329093B1
公开(公告)日：2001-12-11
申请号：US09377651
申请日：1999-08-19
申请人： Hideo Ohara , Hisaaki Gyoten , Kazuhito Hatoh , Kazufumi Nishida , Makoto Uchida , Eiichi Yasumoto , Yasushi Sugawara , Teruhisa Kanbara , Toshihiro Matsumoto
发明人： Hideo Ohara , Hisaaki Gyoten , Kazuhito Hatoh , Kazufumi Nishida , Makoto Uchida , Eiichi Yasumoto , Yasushi Sugawara , Teruhisa Kanbara , Toshihiro Matsumoto
IPC分类号： H01M804
CPC分类号： H01M8/0247 , H01M8/0263 , H01M8/0267 , H01M8/04029 , H01M8/241 , H01M8/2415 , H01M8/2457 , H01M8/2465 , H01M8/247 , H01M8/2485 , H01M8/249 , H01M2300/0082
摘要： The present invention provides a polymer electrolyte fuel cell stack that includes an inlet manifold that distributes supplies of the gaseous fuel, the oxidant gas, and cooling water in a sequence of lamination from a unit cell on one end of the cell laminate to a unit cell on the other end of the cell laminate and an outlet manifold that discharges exhausts of the gaseous fuel, the oxidant gas, and the cooling water in an inverted sequence of lamination from the unit cell on the other end of the cell laminate to the unit cell on the one end of the cell laminate. This configuration actualizes a small-sized, compact fuel cell stack.
摘要翻译：本发明提供了一种聚合物电解质燃料电池堆，其包括入口歧管，所述入口歧管以气体燃料，氧化剂气体和冷却水的顺序从电池层压板的一端上的单电池分配到单电池在电池层叠体的另一端和排出歧管，排出歧管以与电池层叠体的另一端的单位电池相反的顺序排列排放气体燃料，氧化剂气体和冷却水到单电池在电池层叠体的一端。该配置实现了小型紧凑的燃料电池堆。

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