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1. 发明授权

US06429339B1 Method for producing cyclopentanone 失效
标题翻译：环戊酮生产方法
公开(公告)号：US06429339B1
公开(公告)日：2002-08-06
申请号：US09700365
申请日：2000-11-15
申请人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
发明人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
IPC分类号： C07C4500
CPC分类号： B01J23/10 , C07C45/48 , C07C49/395
摘要： A process for preparing cyclopentanone by reacting adipic esters of the formula R1OOC—(CH2)4—COOR2 I where R1 and R2 are each alkyl having from 1 to 12 carbon atoms, cycloalkyl having 5 or 6 carbon atoms, aralkyl or aryl and R2 may additionally be hydrogen, in the presence of oxidic catalysts comprises reacting adipic esters of the formula I having less than 5% by weight of by-products other than adipic esters in the gas phase in the presence of water, a carrier gas and a) from 0.01 to 10% by weight of at least one metal oxide selected from the first or second main group of the periodic table or from the group of the rare earth metals on titanium dioxide or zirconium dioxide as catalyst support, or b) from 0.01 to 50% by weight of at least one metal oxide selected from the second main group of the periodic table on zink oxide as catalyst support.
摘要翻译：通过使式R 1和R 2的己二酸酯反应制备环戊酮的方法各自是在氧化催化剂存在的情况下，可以另外为氢，其中R 1和R 2各自为具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基或芳基，包括使式I的己二酸酯在水，载气的存在下，在气相中具有小于5重量％的除己二酸酯之外的副产物，和（ii）0.01至10重量％的至少一种金属氧化物，其选自周期表的第一或第二主族，或者来自稀土金属的二氧化钛或二氧化锆的组，作为催化剂载体，orb）为0.01至50重量％的至少一种选自氧化锌作为催化剂载体的周期表第二主要组。

2. 发明授权

US06316659B1 Method for producing cyclopentanone and cyclopentene-1-carboxylic acid and their esters 失效
标题翻译：环戊酮和环戊烯-1-羧酸及其酯的制备方法
公开(公告)号：US06316659B1
公开(公告)日：2001-11-13
申请号：US09508008
申请日：2000-03-07
申请人： Rolf Fischer , Shelue Liang , Rolf Pinkos , Frank Stein
发明人： Rolf Fischer , Shelue Liang , Rolf Pinkos , Frank Stein
IPC分类号： C07C6974
CPC分类号： C07C51/377 , C07C45/54 , C07C67/333 , C07C49/395 , C07C61/20 , C07C69/74
摘要： A process for preparing cyclopentanone and cyclopentene-1-carboxylic acid or an ester thereof of the formula I where R is hydrogen or an aliphatic radical having 1-6 carbon atoms or a cycloaliphatic, araliphatic or aromatic radical having 6-12 carbon atoms comprises heating a compound of the formula II X—(CH2)4—COOR II where X is formyl or hydroxymethyl and R is defined as above, and/or a compound which is converted into a compound of the formula II by reaction with water or alcohols ROH under the reaction conditions to from 200 to 450° C. in the gas or liquid phase in the presence of a heterogeneous oxidic catalyst.
摘要翻译：制备式I的环戊酮和环戊烯-1-羧酸或其酯的方法，其中R是氢或具有1-6个碳原子的脂族基团或具有6-12个碳原子的脂环族，芳脂族或芳族基团包括加热式II的化合物，其中X是甲酰基或羟甲基，R如上定义，和/或在反应条件下与水或醇ROH反应转化为式II化合物的化合物为200-450℃ 在气相或液相中存在非均相氧化催化剂。

3. 发明授权

US07172989B2 Catalytic hydrogenation over rhenium-containing catalysts supported on activated carbon 失效
标题翻译：通过负载在活性炭上的含铼催化剂进行催化氢化
公开(公告)号：US07172989B2
公开(公告)日：2007-02-06
申请号：US11104408
申请日：2005-04-13
申请人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
IPC分类号： B01J23/42 , B01J21/18 , B01J23/36
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated. It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭已经被非氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

4. 发明授权

US06906228B2 Method for catalytic hydrogenation on rhenium-containing active carbon carrier catalysts 失效
标题翻译：用于含铼活性炭载体催化剂的催化氢化方法
公开(公告)号：US06906228B2
公开(公告)日：2005-06-14
申请号：US10220566
申请日：2001-03-01
申请人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
IPC分类号： B01J21/18 , B01J23/656 , B01J23/89 , C07C29/17 , C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/145 , C07C29/147 , C07C29/149 , C07C29/146 , C07C29/148
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭未经氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

5. 发明授权

US06407294B1 Method for producing 1,6-hexanediol 有权
标题翻译： 1,6-己二醇的制备方法
公开(公告)号：US06407294B1
公开(公告)日：2002-06-18
申请号：US09529789
申请日：2000-04-20
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C2601/08 , C07C35/06 , C07C31/135 , C07C31/20
摘要： A process for producing 1,6-hexanediol by hydrogenation of adipic esters and/or 6-hydroxycaproic esters in the gas phase at elevated temperature and elevated pressure in the presence of chromium-free catalysts comprises hydrogenating a) over a catalyst comprising copper, manganese and aluminum as essential constituents or over Raney copper, b) at a temperature of from 150 to 230° C. and a pressure of from 10 to 70 bar, c) at a molar ratio of hydrogen to ester to be hydrogenated within the range from 150:1 to 300:1, and d) at a catalyst space velocity of from 0.01 to 0.3 kg of C6 ester per liter of catalyst per hour.
摘要翻译：在无铬催化剂存在下，在升高的温度和升高的压力下，气相中己二酸酯和/或6-羟基己酸酯的氢化制备1,6-己二醇的方法包括在包含铜，锰和铝作为必需组分或在阮内铜上，b）在150-230℃的温度和10至70巴的压力下，c）以氢化至酯的摩尔比在150℃的范围内：1至300:1，和d），催化剂空速为每升催化剂每小时0.01至0.3kg的C6酯。

6. 发明授权

US06359108B1 Method for polymerizing cyclic ether 失效
标题翻译：聚合环醚的方法
公开(公告)号：US06359108B1
公开(公告)日：2002-03-19
申请号：US09423459
申请日：1999-11-09
申请人： Karsten Eller , Frank Stein , Christoph Sigwart , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Ulrich Müller
发明人： Karsten Eller , Frank Stein , Christoph Sigwart , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Ulrich Müller
IPC分类号： C08G5968
CPC分类号： B01J29/049 , C08G65/2657
摘要： A process for polymerizing cyclic ethers over a heterogeneous catalyst comprises using a heterogeneous catalyst comprising one or more pillared interlayered clays (PILCs).
摘要翻译：在非均相催化剂上聚合环醚的方法包括使用包含一个或多个柱状中间层粘土（PILC）的多相催化剂。

7. 发明授权

US06211401B1 Process for preparing polytetrahydrofuran 失效
标题翻译：制备聚四氢呋喃的方法
公开(公告)号：US06211401B1
公开(公告)日：2001-04-03
申请号：US09308320
申请日：1999-05-19
申请人： Karsten Eller , Christoph Sigwart , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Müller , Michael Hesse
发明人： Karsten Eller , Christoph Sigwart , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Müller , Michael Hesse
IPC分类号： C07C6724
CPC分类号： C08G65/2693 , B01J23/24 , C08G65/20
摘要： Polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers are prepared by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer on a heterogeneous carrier catalyst which contains on an oxidic carrier material as active mass a catalytically active amount of at least one oxygenous molybdenum and/or tungsten compound and, when the precursor compounds of the active mass have been applied to the carrier material precursor, has been calcined at temperatures of between 500° C. and 1000° C. The catalyst used contains a promotor which comprises at least one element or a compound of an element of the 2nd, 3rd including the lanthanides, 5th, 6th, 7th, 8th or 14th group of the periodic system of elements.
摘要翻译：这些聚合物的四氢呋喃共聚物，二酯或单酯通过在至少一种前体和/或共聚单体存在下在非均相载体催化剂的存在下聚合四氢呋喃来制备，所述非均相载体催化剂在氧化载体材料上作为活性物质至少具有催化活性量一种氧钼和/或钨化合物，并且当将活性物质的前体化合物已经施加到载体材料前体时，已经在500℃和1000℃之间的温度下煅烧。所使用的催化剂包含一种促进剂，包括至少一种元素或元素的化合物，其包括元素周期性系统的镧系元素，第5，第6，第7，第8或第14组的第2,3族元素。

8. 发明授权

US6111147A Process for preparing polytetrahydrofuran and derivatives thereof 失效
标题翻译：制备聚四氢呋喃及其衍生物的方法
公开(公告)号：US6111147A
公开(公告)日：2000-08-29
申请号：US269210
申请日：1999-04-01
申请人： Christoph Sigwart , Karsten Eller , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Mueller , Michael Hesse
发明人： Christoph Sigwart , Karsten Eller , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Mueller , Michael Hesse
IPC分类号： C08G65/10 , C08G18/48 , C08G65/20 , C08G65/28 , C07C43/10 , C07C43/11 , C07C67/24 , C07C69/76
CPC分类号： C08G65/20 , C08G18/4854
摘要： Polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butyne-1,4-diol, diesters of these polymers with C.sub.2 -C.sub.20 -monocarboxylic acids or monoesters of these polymers with C.sub.1 -C.sub.10 -monocarboxylic acids are prepared by polymerization of tetrahydrofuran in the presence of one of the telogens water, 1,4-butanediol, 2-butyne-1,4-diol, polytetrahydrofuran having a molecular weight of from 200 to 700 Dalton, a C.sub.1 -C.sub.10 -monocarboxylic acid or an anhydride of a C.sub.2 -C.sub.20 -monocarboxylic acid or a mixture of these telogens over a heterogeneous supported catalyst which comprises a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound on an oxidic support material and which has been calcined at from 5OO.degree. C. to 1OOO.degree. C. after application of the precursor compounds of the oxygen-containing molybdenum and/or tungsten compounds onto the support material precursor, wherein the catalyst is activated by treatment with a reducing agent before it is used as a polymerization catalyst.
摘要翻译： PCT No.PCT / EP97 / 05204 Sec。 371日期1999年4月1日 102（e）1999年4月1日PCT PCT 1997年9月23日PCT公布。第WO98 / 15589号公报日期：1998年4月16日四氢呋喃，四氢呋喃和2-丁炔-1,4-二醇的共聚物，这些聚合物与C2-C20-一元羧酸的二酯或这些聚合物与C1-C10-一元羧酸的单酯通过四氢呋喃在其中一种使用水，1,4-丁二醇，2-丁炔-1,4-二醇，分子量为200-700道尔顿的聚四氢呋喃，C1-C10-一元羧酸或 C2-C20-一元羧酸或这些方法的混合物在非均相载体催化剂上的混合物，其包含在氧化载体材料上的催化活性量的含氧钼和/或钨化合物，并且已经在500℃煅烧将含氧钼和/或钨化合物的前体化合物施加到载体材料前体上之后，至1000℃，其中催化剂在用作还原剂之前通过用还原剂进行活化聚合催化剂。

9. 发明授权

US5981769A Process for preparing 1,6- hexanediol and caprolactone 有权
标题翻译：制备1,6-己二醇和己内酯的方法
公开(公告)号：US5981769A
公开(公告)日：1999-11-09
申请号：US125974
申请日：1998-08-28
申请人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Boris Breitscheidel , Harald Rust
发明人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Boris Breitscheidel , Harald Rust
IPC分类号： C07D313/04 , C07C27/12 , C07C29/149 , C07C29/80 , C07C29/88 , C07C31/20 , C07C31/27 , C07C51/31 , C07D315/00 , C07D313/00
CPC分类号： C07D315/00 , C07C29/149 , C07C29/80 , C07C29/88 , C07C51/313 , C07C2101/14
摘要： 1,6-hexanediol and .epsilon.-caprolactone are prepared from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol using oxygen or oxygen-containing gases by water extraction of the reaction mixture, by esterifying and hydrogenating a substream to give hexanediol and cyclizing 6-hydroxycaproic esters to give caprolactone.
摘要翻译： PCT No.PCT / EP97 / 00990 371日期1998年8月28日 102（e）1998年8月28日PCT PCT 1997年2月28日PCT公布。公开号WO97 / 31883 日期1991年9月4日，1991年6月 - 己二醇和ε-己内酯由包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备，其作为副产物在氧化使用氧或含氧气体通过水提取反应混合物，通过酯化和氢化子流，得到己二醇并环化6-羟基己酸酯，得到己内酯，得到环己烷至环己酮/环己醇。

10. 发明授权

US6008418A Process for preparing 1,6 hexanediol with a level of purity over 99% 有权
标题翻译：制备纯度超过99％的1,6己二醇的方法
公开(公告)号：US6008418A
公开(公告)日：1999-12-28
申请号：US125976
申请日：1998-08-28
申请人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Harald Rust , Boris Breitscheidel
发明人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Harald Rust , Boris Breitscheidel
IPC分类号： B01J23/80 , B01J23/889 , C07B61/00 , C07C29/149 , C07C31/20
CPC分类号： C07C29/149
摘要： 1,6-Hexanediol is prepared from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol by water extraction of the reaction mixture, by esterification of the acids and hydrogenation whereina) the monocarboxylic and dicarboxylic acids present in the aqueous dicarboxylic acid mixture are reacted with a low molecular weight alcohol to give the corresponding carboxylic esters,b) the resulting esterification mixture is freed of excess alcohol and low boilers in a first distillation stage,c) the bottoms are fractionated in a second distillation stage to give an ester fraction essentially free of 1,4-cyclohexanediols and a fraction comprising at least the major part of the 1,4-cyclohexanediols,d) the ester fraction essentially free of 1,4-cyclohexanediols is catalytically hydrogenated ande) in a pure distillation stage, 1,6-hexanediol is isolated from the hydrogenation product in a manner known per se.
摘要翻译： PCT No.PCT / EP97 / 00980 Sec。 371日期1998年8月28日 102（e）1998年8月28日PCT PCT 1997年2月28日PCT公布。公开号WO97 / 31882 日期1991年9月4日6,6-己二醇由包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备，其作为副产物在环己烷氧化成环己酮/ 环己醇通过水提取反应混合物，通过酸的酯化和氢化，其中存在于二羧酸水溶液混合物中的单羧酸和二羧酸与低分子量醇反应得到相应的羧酸酯，b）得到的酯化混合物在第一蒸馏阶段中不含过量的醇和低沸点，c）在第二蒸馏阶段对塔底物进行分馏，得到基本上不含1,4-环己烷二醇的酯馏分和至少包含至少大部分 1,4-环己烷二醇，d）基本上不含1,4-环己烷二醇的酯馏分是催化氢化的，e）在纯蒸馏阶段，以本身已知的方式从加氢产物中分离出1,6-己二醇。

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