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1. 发明申请

WO2016200719A1 PALLADIUM COATED METALS AS HYDROGEN ACCEPTORS FOR THE AROMATIZATION OF A METHANE CONTAINING GAS STREAM 审中-公开
标题翻译：作为含氢气体甲烷的氢化吸收剂的金属涂层金属
公开(公告)号：WO2016200719A1
公开(公告)日：2016-12-15
申请号：PCT/US2016/035968
申请日：2016-06-06
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： GEERLINGS, Jacobus Johannes Cornelis , MESTERS, Carolus Matthias Anna Maria
IPC分类号： B01D53/04 , C01B3/38
CPC分类号： C01B3/26 , C01B3/0026 , C01B2203/041 , C07C2/84 , C07C2529/40 , Y02E60/327 , C07C15/04
摘要： Implementations of the disclosed subject matter provide a process for the aromatization of a methane-containing gas stream including contacting the methane-containing gas stream in a reaction zone of an aromatization reactor comprising an aromatization catalyst and a hydrogen acceptor under methane-containing gas aromatization conditions to produce reaction products comprising aromatics and gaseous hydrogen. At least a portion of the gaseous hydrogen produced is bound by the hydrogen acceptor in the reaction zone and removed from the reaction products and the reaction zone. The hydrogen acceptor includes a palladium barrier layer surrounding at least a portion of the outer surface of the hydrogen acceptor.
摘要翻译：所公开的主题的实施方案提供了一种含甲烷气流的芳构化方法，该方法包括在包含芳构化催化剂和氢受体的芳构化反应器的含甲烷气体芳构化条件下使含甲烷的气流接触以产生包含芳族化合物和气态氢的反应产物。产生的气态氢的至少一部分被反应区中的氢受体结合，并从反应产物和反应区中除去。氢受体包括围绕氢受体的外表面的至少一部分的钯阻挡层。

2. 发明申请

WO2007060149A1 A PROCESS FOR SEQUESTRATION OF CARBON DIOXIDE BY MINERAL CARBONATION 审中-公开
标题翻译：通过矿物碳酸化处理二氧化碳的方法
公开(公告)号：WO2007060149A1
公开(公告)日：2007-05-31
申请号：PCT/EP2006/068691
申请日：2006-11-21
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GEERLINGS, Jacobus Johannes Cornelis , WESKER, Evert
发明人： GEERLINGS, Jacobus Johannes Cornelis , WESKER, Evert
IPC分类号： B01J20/10
CPC分类号： C01F5/24 , B01D53/62 , B01J20/10 , C01B33/22 , C01B33/24 , C01F11/18 , C10J3/463 , C10J2300/0983 , Y02C10/04 , Y02C10/08 , Y02P20/152
摘要： The invention provides a process for sequestration of carbon dioxide by mineral carbonation comprising the following steps: (a) converting a magnesium or calcium sheet silicate hydroxide into a magnesium or calcium ortho- or chain silicate by bringing the silicate hydroxide in direct or indirect heat-exchange contact with hot synthesis gas to obtain the silicate, silica, water and cooled synthesis gas; (b) contacting the silicate obtained in step (a) with carbon dioxide to convert the silicate into magnesium or calcium carbonate and silica.
摘要翻译：本发明提供了一种通过矿物碳酸化进行二氧化碳螯合的方法，包括以下步骤：（a）通过将硅酸氢氧化物直接或间接加热，将镁或钙硅酸镁硅酸盐转化成邻 - 或链式硅酸镁或钙，与热合成气交换接触，得到硅酸盐，二氧化硅，水和冷却的合成气; （b）使步骤（a）中获得的硅酸盐与二氧化碳接触，将硅酸盐转化为碳酸镁或碳酸钙和二氧化硅。

3. 发明申请

WO2007071633A1 PROCESS FOR SEQUESTRATION OF CARBON DIOXIDE 审中-公开
标题翻译：二氧化碳排序方法
公开(公告)号：WO2007071633A1
公开(公告)日：2007-06-28
申请号：PCT/EP2006/069796
申请日：2006-12-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GEERLINGS, Jacobus Johannes Cornelis , VAN MOSSEL, Gerardus Antonius Franciscus , IN 'T VEEN, Bernardus Cornelis Maria
发明人： GEERLINGS, Jacobus Johannes Cornelis , VAN MOSSEL, Gerardus Antonius Franciscus , IN 'T VEEN, Bernardus Cornelis Maria
IPC分类号： C01F11/18 , C01F11/02 , C01B31/24 , B01D53/62
CPC分类号： B01D53/62 , B01D2251/404 , C01F11/18 , Y02C10/04 , Y02P20/152
摘要： A process for sequestration of carbon dioxide comprising the following steps: (a) dispersing solid waste material comprising calcium oxide and a calcium-comprising mixed oxide in water to dissolve at least part of the calcium oxide and to form calcium oxide-depleted solid waste material in a calcium hydroxide solution; (b) separating the calcium hydroxide solution from the calcium oxide-depleted solid waste material; (c) converting the calcium hydroxide in the separated calcium hydroxide solution in precipitated calcium carbonate; and (d) contacting an aqueous slurry of the calcium oxide- depleted solid waste material with carbon dioxide for mineral carbonation of the carbon dioxide to form carbonated solid waste material.
摘要翻译：一种封存二氧化碳的方法，包括以下步骤：（a）将包含氧化钙和钙的混合氧化物的固体废料分散在水中以溶解至少部分氧化钙并形成贫氧的氧化钙废物在氢氧化钙溶液中; （b）从氧化钙贫化固体废物中分离氢氧化钙溶液; （c）将分离的氢氧化钙溶液中的氢氧化钙转化成沉淀碳酸钙; 和（d）使氧化钙贫乏的固体废弃物材料的含水浆料与用于二氧化碳的矿物碳酸化的二氧化碳接触以形成碳酸化的固体废料。

4. 发明申请

WO2008138954A1 PROCESS FOR PREPARING TI-DOPED HYDRIDES 审中-公开
标题翻译：制备TI-DOPED HYDRIDES的方法
公开(公告)号：WO2008138954A1
公开(公告)日：2008-11-20
申请号：PCT/EP2008/055925
申请日：2008-05-14
申请人： Shell Internationale Research Maatschappij B.V. , GEERLINGS, Jacobus Johannes Cornelis , PAULUS, Peter Marie , STIL, Hans Arie
发明人： GEERLINGS, Jacobus Johannes Cornelis , PAULUS, Peter Marie , STIL, Hans Arie
IPC分类号： C01B3/00 , C01B6/24
CPC分类号： C01B3/0031 , C01B6/24 , Y02E60/327 , Y02E60/364
摘要： The present invention provides a process for the preparation of Ti-doped alkali metal and/or alkaline- earth metal aluminium hydride, comprising intimately mixing: an alkali metal and/or alkaline-earth metal aluminium hydride, or at least one alkali metal hydride and/or alkaline- earth metal hydride, metallic aluminium and H 2 , with in the range of from 0.5 to 20 mol% of Ti (OCH 3 ) 4 , based on the moles of A1 in the prepared Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride. The invention further relates to a Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride, obtainable by a process according to the invention, a hydrogen storage material comprising a Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride according the invention, a process for reversibly desorbing and/or absorbing hydrogen, the use of a Ti- doped alkali metal and/or alkaline-earth metal aluminium hydride according to invention to store hydrogen and the use of Ti (OCH 3 ) 4 as Ti-dopant for an alkali metal and/or alkaline-earth metal aluminium hydride.
摘要翻译：本发明提供了一种制备掺杂Ti的碱金属和/或碱土金属氢化铝的方法，包括：将碱金属和/或碱土金属氢化铝，或至少一种碱金属氢化物和 /或碱土金属氢化物，金属铝和H 2 O 2，其量为0.5至20摩尔％的Ti（OCH 3 3）4 基于制备的Ti掺杂的碱金属和/或碱土金属氢化铝中的Al的摩尔数。本发明还涉及通过本发明的方法获得的掺杂Ti的碱金属和/或碱土金属氢化铝，包含掺Ti的碱金属和/或碱土金属氢化铝的氢存储材料根据本发明，可逆地解吸和/或吸收氢的方法，使用根据本发明的Ti-掺杂的碱金属和/或碱土金属氢化铝来储存氢气和使用Ti（OCH 3）作为碱金属和/或碱土金属氢化铝的Ti掺杂剂。

5. 发明申请

WO2006008242A1 PROCESS FOR PRODUCING CACO3 OR MGCO3 审中-公开
标题翻译：生产CACO3或MGCO3的方法
公开(公告)号：WO2006008242A1
公开(公告)日：2006-01-26
申请号：PCT/EP2005/053258
申请日：2005-07-07
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GEERLINGS, Jacobus Johannes Cornelis , VAN MOSSEL, Gerardus Antonius Franciscus , IN 'T VEEN, Bernardus Cornelis Maria
发明人： GEERLINGS, Jacobus Johannes Cornelis , VAN MOSSEL, Gerardus Antonius Franciscus , IN 'T VEEN, Bernardus Cornelis Maria
IPC分类号： C01F5/24
CPC分类号： C01F11/181 , C01F5/24 , C01P2006/60
摘要： The present invention relates to a process for producing CaC03 or MgC03 from a feedstock comprising a Ca- or Mg-comprising mixed metal oxide, wherein: (a) an aqueous slurry of the feedstock is contacted with a C02 containing gas to form an aqueous solution of Ca(HC03)2 or Mg(HC03)2 and a solid Ca- or Mg-depleted feedstock; (b) part or all of the aqueous solution of Ca(HC03)2 or Mg(HC03)2 is separated from the solid Ca- or Mg-depleted feedstock; (c) CaC03 or MgC03 is precipitated from the separated aqueous solution of Ca(HC03)2 or Mg(HC03)2; and (d) the precipitated CaC03 or MgC03 is recovered as product. The invention further relates to a process for the production of an aqueous solution of Ca(HC03)2 or Mg(HC03)2.
摘要翻译：本发明涉及一种由包含含Ca或Mg的混合金属氧化物的原料生产CaCO 3或MgCO 3的方法，其中：（a）原料的含水浆料与含CO 2的气体接触以形成水溶液的Ca（HCO 3）2或Mg（HCO 3）2和固体Ca或Mg贫化的原料; （b）部分或全部Ca（HCO 3）2或Mg（HCO 3）2的水溶液与固体Ca或Mg贫化的原料分离; （c）从分离的Ca（HCO 3）2或Mg（HCO 3）2水溶液中沉淀出CaCO 3或MgCO 3; 和（d）沉淀的CaCO 3或MgCO 3作为产物回收。本发明还涉及一种生产Ca（HCO 3）2或Mg（HCO 3）2的水溶液的方法。

6. 发明申请

WO2010097444A1 A PROCESS FOR CARBON DIOXIDE SEQUESTRATION 审中-公开
标题翻译：二氧化碳序列的方法
公开(公告)号：WO2010097444A1
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052430
申请日：2010-02-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BOERRIGTER, Harold , GEERLINGS, Jacobus Johannes Cornelis , IN 'T VEEN, Bernardus Cornelis Maria
发明人： BOERRIGTER, Harold , GEERLINGS, Jacobus Johannes Cornelis , IN 'T VEEN, Bernardus Cornelis Maria
IPC分类号： B01D53/62 , B01J20/10
CPC分类号： B01D53/62 , B01D2251/402 , B01D2251/602 , B01D2253/304 , B01D2257/504 , B01D2259/80 , B01J20/041 , B01J20/10 , B01J20/28004 , B01J20/3085 , B01J2220/56 , Y02A50/2342 , Y02C10/04 , Y02C10/08
摘要： The present invention provides a process for sequestration of carbon dioxide by mineral carbonation comprising: (i) providing a serpentine magnesium sheet silicate hydroxide mineral and activating the serpentine magnesium sheet silicate hydroxide mineral at an elevated temperature T for an activation time period τ to obtain an activated mineral, wherein τ is, a function of T and: formula (2) wherein 630
摘要翻译：本发明提供一种通过矿物碳酸化进行二氧化碳螯合的方法，包括：（i）提供蛇形镁硅酸镁硅酸盐矿物质，并在升高的温度T下活化蛇形镁硅酸镁硅酸盐矿物，以使活化时间t得到活化的矿物，其中t是T的函数;和式（2）其中630

7. 发明申请

WO2009043895A2 CATALYST AND METHOD 审中-公开
标题翻译：催化剂和方法
公开(公告)号：WO2009043895A2
公开(公告)日：2009-04-09
申请号：PCT/EP2008/063194
申请日：2008-10-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GEERLINGS, Jacobus Johannes Cornelis , REYNHOUT, Marinus Johannes , SCHOLTEN, Wilhelmus Johannes Franciscus , VERBIST, Guy Lode Magda Maria
发明人： GEERLINGS, Jacobus Johannes Cornelis , REYNHOUT, Marinus Johannes , SCHOLTEN, Wilhelmus Johannes Franciscus , VERBIST, Guy Lode Magda Maria
IPC分类号： C10G2/00 , B01J21/06 , B01J35/10 , B01J35/02
CPC分类号： B01J21/063 , B01J23/8892 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J37/0009 , C10G2/33 , C10G2/332 , Y10T428/2982
摘要： A titania catalyst support having a particle size distribution with a first peak at a first particle size and a second peak at a second particle size, wherein the second particle size is at least 50% larger than the first particle size. A method of manufacture is also disclosed. The support and resulting catalyst can be used for catalysing a Fischer-Tropsch reaction.
摘要翻译：二氧化钛催化剂载体，其具有在第一粒度下具有第一峰值和在第二粒径下具有第二峰值的粒度分布，其中第二粒径比第一粒径大至少50％粒度。还公开了一种制造方法。载体和得到的催化剂可用于催化费 - 托反应。

8. 发明申请

WO2008142017A2 A PROCESS FOR SEQUESTRATION OF CARBON DIOXIDE BY MINERAL CARBONATION 审中-公开
标题翻译：通过矿物碳酸化处理二氧化碳的方法
公开(公告)号：WO2008142017A2
公开(公告)日：2008-11-27
申请号：PCT/EP2008/056027
申请日：2008-05-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , GEERLINGS, Jacobus Johannes Cornelis , WESKER, Evert
发明人： GEERLINGS, Jacobus Johannes Cornelis , WESKER, Evert
IPC分类号： C01F5/24 , C01F11/18 , B01D53/62 , C01B33/12 , C01B33/18
CPC分类号： C01F11/18 , B01D53/62 , B01D2251/402 , B01D2251/404 , B01D2257/504 , C01B32/50 , C01B33/126 , C01F5/24 , Y02C10/04 , Y02P20/152
摘要： The invention provides a process for sequestration of carbon dioxide by mineral carbonation comprising the following steps: (a) converting a magnesium or calcium sheet silicate hydroxide into a magnesium or calcium ortho- or chain silicate by bringing the silicate hydroxide in direct or indirect heat-exchange contact with hot flue gas to obtain the silicate, silica, water and cooled flue gas; (b) contacting the silicate obtained in step (a) with carbon dioxide to convert the silicate into magnesium or calcium carbonate and silica.
摘要翻译：本发明提供了一种通过矿物碳酸化进行二氧化碳螯合的方法，包括以下步骤：（a）通过将硅酸氢氧化物直接或间接加热，将镁或钙硅酸镁硅酸盐转化成邻 - 或链式硅酸镁或钙，与热烟气交换接触，获得硅酸盐，二氧化硅，水和冷却烟气; （b）使步骤（a）中获得的硅酸盐与二氧化碳接触，将硅酸盐转化为碳酸镁或碳酸钙和二氧化硅。

9. 发明公开

EP2160351A1 PROCESS FOR PREPARING TI-DOPED HYDRIDES 有权
标题翻译：于制备TI掺杂氢化物
公开(公告)号：EP2160351A1
公开(公告)日：2010-03-10
申请号：EP08759603.7
申请日：2008-05-14
申请人： Shell Internationale Research Maatschappij B.V.
发明人： GEERLINGS, Jacobus Johannes Cornelis , PAULUS, Peter Marie , STIL, Hans Arie
IPC分类号： C01B3/00 , C01B6/24
CPC分类号： C01B3/0031 , C01B6/24 , Y02E60/327 , Y02E60/364
摘要： The present invention provides a process for the preparation of Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride, comprising intimately mixing: an alkali metal and/or alkaline-earth metal aluminium hydride, or at least one alkali metal hydride and/or alkaline-earth metal hydride, metallic aluminium and H2, with in the range of from 0.5 to 20 mol % of Ti(OCH3)4, based on the moles of Al in the prepared Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride. The invention further relates to a Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride, obtainable by a process according to the invention, a hydrogen storage material comprising a Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride according the invention, a process for reversibly desorbing and/or absorbing hydrogen, the use of a Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride according to invention to store hydrogen and the use of Ti(OCH3)4 as Ti-dopant for an alkali metal and/or alkaline-earth metal aluminium hydride.

10. 发明授权

EP0966415B1 PROCESS FOR THE PREPARATION OF HYDROCARBONS 失效
标题翻译：用于制备烃类
公开(公告)号：EP0966415B1
公开(公告)日：2002-04-03
申请号：EP97954429.3
申请日：1997-12-11
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： GEERLINGS, Jacobus Johannes Cornelis , HOEK, Arend , HUISMAN, Hans Michiel , LEDNOR, Peter William
IPC分类号： C07C1/04
CPC分类号： C10G2/332 , B01J23/8892 , C07C1/0435 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/34 , C07C2523/75 , C07C2523/889
摘要： The present invention relates to a process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen in which reaction a feed comprising hydrogen and carbon monoxide is contacted at elevated temperature and pressure with a catalyst comprising cobalt and manganese in which catalyst the cobalt/manganese molar ratio is between 14:1 and 7:1 and the GHSV is at least 1600 N1/1/h. Preferably the cobalt/manganese molar ratio is between 13:1 and 9:1 and the GHSV is between 2700 and 25,000 N1/1/h. The reaction is especially carried out in a slurry phase regime.

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