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1. 发明授权

US6103816A Aqueous aminoplast curable film-forming compositions providing films having resistance to acid etching 失效
标题翻译：提供具有耐酸腐蚀性的膜的水性氨基塑料固化成膜组合物
公开(公告)号：US6103816A
公开(公告)日：2000-08-15
申请号：US968807
申请日：1992-10-30
申请人： Shanti Swarup , Debra L. Singer , Gregory J. McCollum , Kurt G. Olson , S. Tonya Stefko , Richard J. Sadvary , Robyn E. McMillan , Michael A. Mayo
发明人： Shanti Swarup , Debra L. Singer , Gregory J. McCollum , Kurt G. Olson , S. Tonya Stefko , Richard J. Sadvary , Robyn E. McMillan , Michael A. Mayo
IPC分类号： C08G73/00 , C08F8/30 , C08L61/20 , C09D133/06 , C09D161/20 , C09D161/28 , C09D167/00 , C09D179/00 , C09D201/02 , C09D201/06 , G08L67/04 , G08L75/04
CPC分类号： C09D167/00 , C08F8/30 , C08F8/32 , C09D133/062 , C09D201/06 , C08L61/20
摘要： An aqueous aminoplast-curable film-forming composition is disclosed. The aqueous film-forming composition is a crosslinkable composition comprising (1) a material containing a plurality of carbamate and/or urea functional groups and (2) an aminoplast crosslinking agent. The aqueous composition provides a coating with improved acid etch resistance, making the compositions particularly useful as automotive clear coats.
摘要翻译：公开了一种含氨基塑料可固化成膜组合物。含水成膜组合物是可交联组合物，其包含（1）含有多个氨基甲酸酯和/或脲官能团的材料和（2）氨基塑料交联剂。水性组合物提供具有改善的耐酸蚀性的涂层，使得该组合物特别用作汽车透明涂层。

2. 发明申请

US20080138627A1 COLOR-PLUS-CLEAR COMPOSITE COATINGS 审中-公开
标题翻译：彩色高分子复合涂料
公开(公告)号：US20080138627A1
公开(公告)日：2008-06-12
申请号：US11608423
申请日：2006-12-08
申请人： Shanti Swarup , Richard J. Sadvary , Dennis A. Simpson
发明人： Shanti Swarup , Richard J. Sadvary , Dennis A. Simpson
IPC分类号： B32B27/38
CPC分类号： C09D133/10 , B05D7/53 , B05D2451/00 , C08L33/068 , C09D133/068 , C09D167/00 , Y10T428/31511 , C08L2666/04 , B05D2401/20 , B05D2401/10
摘要： A multi-component composite coating composition comprising an aqueous-based film-forming composition serving as a color coat or a basecoat and a polyepoxide-polyacid clearcoat is disclosed. The polyacid is made from ring opening a polybasic anhydride with a polyester polyol formed from reacting a polyol with a polycarboxylic acid having at least 20 contiguous carbon atoms between the carboxylic acid groups.
摘要翻译：公开了一种多组分复合涂层组合物，其包含用作彩色涂层或底涂层的水性成膜组合物和聚环氧化物 - 多酸透明涂层。多酸由多元酸酐与由多元醇与羧酸基团之间具有至少20个连续碳原子的多元羧酸反应形成的聚酯多元醇开环制成。

3. 发明授权

US5703155A Waterborne coating composition having improved rheology control and appearance 失效
标题翻译：水性涂料组合物具有改进的流变控制和外观
公开(公告)号：US5703155A
公开(公告)日：1997-12-30
申请号：US627527
申请日：1996-04-04
申请人： Shanti Swarup , Richard J. Sadvary
发明人： Shanti Swarup , Richard J. Sadvary
IPC分类号： B05D5/06 , C08F20/10 , C08F220/10 , C09D4/06 , C09D155/00 , C09D163/00 , C09D175/04 , C09K3/00 , C08L31/00
CPC分类号： C09D155/005 , C08F20/10 , C09D175/04
摘要： Waterborne coating compositions are provided comprising a polymeric film-forming resin, a non-gelled copolymer and up to about 2.1 percent by weight silica, based on the total weight of resin solids in the coating compositions. The non-gelled copolymer is prepared from about 75 to about 95 percent by weight of an ethylenically unsaturated monomer such as methyl methacrylate, butyl acrylate, butyl methacrylate, styrene, and mixtures thereof; about 2 to about 12 percent by weight of an ethylenically unsaturated monomer having one acid functional group; and about 2 to about 20 percent by weight of an ethylenically unsaturated oligomeric monomer hating a number average molecular weight of about 1500 to about 4000 and which is derived from a hydroxyl functional acid having a predominantly hydrocarbon chain of from about 10 to 19 carbon atoms. Note that the percentages by weight are based upon the total solid weight of reactants used to prepare the copolymer. The coating compositions may be applied to a substrate alone or as a clear film-forming composition in a color-plus-clear composite coating.
摘要翻译：基于涂料组合物中树脂固体的总重量，提供水性涂料组合物，其包含聚合物成膜树脂，非胶凝共聚物和高达约2.1重量％的二氧化硅。非胶凝共聚物由约75至约95重量％的烯属不饱和单体如甲基丙烯酸甲酯，丙烯酸丁酯，甲基丙烯酸丁酯，苯乙烯及其混合物制备; 约2至约12重量％的具有一个酸官能团的烯属不饱和单体; 和约2至约20重量％的烯键式不饱和低聚单体，其数均分子量为约1500至约4000，并且衍生自主要具有约10至19个碳原子的烃链的羟基官能酸。注意，重量百分数是基于用于制备共聚物的反应物的总固体重量。涂料组合物可以单独使用或者作为透明的成膜组合物涂覆在彩色 - 透明的复合涂层中。

4. 发明申请

US20100119834A1 COLOR-PLUS-CLEAR COMPOSITE COATINGS 审中-公开
标题翻译：彩色高分子复合涂料
公开(公告)号：US20100119834A1
公开(公告)日：2010-05-13
申请号：US12688937
申请日：2010-01-18
申请人： Shanti Swarup , Richard J. Sadvary , Dennis A. Simpson
发明人： Shanti Swarup , Richard J. Sadvary , Dennis A. Simpson
IPC分类号： B32B27/38 , C08F224/00 , C08F226/06 , B32B27/08
CPC分类号： C09D133/10 , B05D7/53 , B05D2451/00 , C08L33/068 , C09D133/068 , C09D167/00 , Y10T428/31511 , C08L2666/04 , B05D2401/20 , B05D2401/10
摘要： A multi-component composite coating composition comprising an aqueous-based film-forming composition serving as a color coat or a basecoat and a polyepoxide-polyacid clearcoat is disclosed. The polyacid is made from ring opening a polybasic anhydride with a polyester polyol formed from reacting a polyol with a polycarboxylic acid having at least 20 contiguous carbon atoms between the carboxylic acid groups.
摘要翻译：公开了一种多组分复合涂层组合物，其包含用作彩色涂层或底涂层的水性成膜组合物和聚环氧化物 - 多酸透明涂层。多酸由多元酸酐与由多元醇与羧酸基团之间具有至少20个连续碳原子的多元羧酸反应形成的聚酯多元醇开环制成。

5. 发明授权

US06270905B1 Multi-component composite coating composition and coated substrate 失效
标题翻译：多组分复合涂料组合物和涂层基材
公开(公告)号：US06270905B1
公开(公告)日：2001-08-07
申请号：US09329408
申请日：1999-06-10
申请人： Shanti Swarup , Walter Metzger , Giancarlo Cirani , Debra L. Singer , Richard J. Sadvary , Robyn E. McMillan , James E. Reddy , Dieter Eiss
发明人： Shanti Swarup , Walter Metzger , Giancarlo Cirani , Debra L. Singer , Richard J. Sadvary , Robyn E. McMillan , James E. Reddy , Dieter Eiss
IPC分类号： B32B1508
CPC分类号： C09D4/06 , C08F290/062 , C08G18/6229 , C09D4/00 , C09D175/04 , Y10T428/31692 , Y10T428/31699 , Y10T428/31928 , Y10T428/31935 , C08F220/18 , C08F220/28 , C08L2666/16
摘要： A coated substrate is provided which includes an outer coating formed from a film-forming composition which includes a crosslinkable, non-gelled acrylic polymer and a crosslinking material capable of reacting with the acrylic polymer to form a crosslinked outer coating. The acrylic polymer is the reaction product of a polyoxyalkylene acrylate monomer comprising a terminal alkoxy group containing about 1 to about 6 carbon atoms and a copolymerizable ethylenically unsaturated monomer different from the polyoxyalkylene acrylate monomer. A multi-component composite coating composition is also provided.
摘要翻译：提供了一种涂覆的基材，其包括由成膜组合物形成的外涂层，其包含可交联的非胶凝的丙烯酸聚合物和能够与丙烯酸类聚合物反应以形成交联的外涂层的交联材料。丙烯酸类聚合物是包含含有约1至约6个碳原子的末端烷氧基的聚氧化烯丙烯酸酯单体和不同于聚氧化烯丙烯酸酯单体的可共聚烯属不饱和单体的反应产物。还提供了多组分复合涂料组合物。

6. 发明授权

US07959981B2 Process for depositing multiple coatings layers on a substrate 有权
标题翻译：在衬底上沉积多个涂层的方法
公开(公告)号：US07959981B2
公开(公告)日：2011-06-14
申请号：US11845324
申请日：2007-08-27
申请人： Richard J. Sadvary , Dennis A. Simpson
发明人： Richard J. Sadvary , Dennis A. Simpson
IPC分类号： B05D7/16
CPC分类号： B05D7/14 , B05D5/066 , B05D7/572 , B05D2202/10 , B05D2601/00
摘要： A process for coating a substrate comprising (a) applying a solventborne primer coating composition onto at least a portion of the substrate; (b) applying a solventborne color containing coating composition onto at least a portion of the solventborne primer coating composition, wherein the solventborne color containing coating composition comprises a colorant and an insoluble microparticle; and (c) curing at least a portion of the solventborne primer coating composition and the solventborne color containing coating composition.
摘要翻译：一种用于涂覆基材的方法，包括（a）将溶剂型底漆涂料组合物施加到所述基材的至少一部分上; （b）将溶剂型含颜料的涂料组合物涂覆在至少一部分溶剂型底漆涂料组合物上，其中含溶剂型的涂料组合物包含着色剂和不溶性微粒; 和（c）固化至少一部分溶剂型底漆涂料组合物和含溶剂型涂料组合物。

7. 发明授权

US07268176B2 Additives for imparting mar and scratch resistance and compositions comprising the same 失效
标题翻译：赋予耐磨性和耐划伤性的添加剂和包含它们的组合物
公开(公告)号：US07268176B2
公开(公告)日：2007-09-11
申请号：US10317971
申请日：2002-12-12
申请人： Ronald R. Ambrose , Shengkui Hu , William H. Retsch, Jr. , Kristin M. Bartlett , Richard J. Sadvary , Masayuki Nakajima
发明人： Ronald R. Ambrose , Shengkui Hu , William H. Retsch, Jr. , Kristin M. Bartlett , Richard J. Sadvary , Masayuki Nakajima
IPC分类号： C08K5/5419
CPC分类号： B82Y30/00 , C08K3/36 , C08K2201/011
摘要： Additives comprising dispersed silica nanoparticles are disclosed. The silica nanoparticles are dispersed in an aminoplast, such as a modified aminoplast formed from the reaction between an aminoplast, a modifying component, and optionally a siloxane. The resulting additives can be added to coating compositions to provide improved mar and/or scratch resistance.
摘要翻译：公开了包含分散的二氧化硅纳米颗粒的添加剂。将二氧化硅纳米颗粒分散在氨基塑料中，例如由氨基塑料，改性组分和任选的硅氧烷之间的反应形成的改性氨基塑料。可以将所得添加剂加入到涂料组合物中以提供改善的耐磨损性和/或耐刮擦性。

8. 发明授权

US07053149B2 Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权
标题翻译：涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法
公开(公告)号：US07053149B2
公开(公告)日：2006-05-30
申请号：US10795216
申请日：2004-03-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L83/04 , C08L83/06 , C08L83/08
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译：提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。还提供了制备涂料组合物的方法。本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

9. 发明授权

US06592999B1 Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto 有权
公开(公告)号：US06592999B1
公开(公告)日：2003-07-15
申请号：US09919200
申请日：2001-07-31
申请人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
发明人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
IPC分类号： B32B904
CPC分类号： B05D7/57 , B05D7/574 , C08J5/12 , C08K3/38 , C08K5/55 , C09D7/60 , Y10T428/31511 , Y10T428/31663 , Y10T428/31725 , Y10T428/31786 , Y10T428/31935
摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

10. 发明授权

US07872078B2 Curable film-forming compositions demonstrating self-healing properties 有权
标题翻译：证明自愈性的可固化成膜组合物
公开(公告)号：US07872078B2
公开(公告)日：2011-01-18
申请号：US11846070
申请日：2007-08-28
申请人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
发明人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
IPC分类号： C08G18/00
CPC分类号： C08G18/637 , B05D5/005 , C08G18/4063 , C08G18/423 , C08G18/6254 , C08G18/792 , C08K3/36 , C08L33/08 , C08L67/00 , C09D133/08 , C09D175/16 , C08L2666/18
摘要： The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.
摘要翻译：本发明涉及可固化成膜组合物，其包含：（a）包含具有羟基官能团的聚酯的聚合物粘合剂; 和（b）包含具有至少三个异氰酸酯官能团的多异氰酸酯的固化剂。在某些实施方案中，作为涂层施用于基材并且在固化后，组合物在15至25℃的环境温度和大于或等于35℃的软化点下显示出至少120的Fisher显微硬度。另外在某些实施方案中，在作为涂层施加到基材上并且在固化之后，当进行干磨试验方法时，组合物显示出至少75％的20°光泽恢复。

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