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    • 6. 发明授权
    • System and method for purifying heptane
    • 纯化庚烷的方法和系统
    • US07326820B2
    • 2008-02-05
    • US10927908
    • 2004-08-27
    • Daniel M. HasenbergMitchell D. RefvikChristopher Raymond TullyMichael S. HankinsonClyde Stewart DentonDale Solaas
    • Daniel M. HasenbergMitchell D. RefvikChristopher Raymond TullyMichael S. HankinsonClyde Stewart DentonDale Solaas
    • C07C7/12C07C7/13C07C7/00C07C7/148C07C7/17
    • C07C7/17C07C7/171C07C9/15
    • Removing impurities from a heptane stream by contacting the heptane stream with an acidic catalyst, wherein the contacting reduces a concentration of one or more close boiling impurities, one or more olefins, or both. The impurities are isomerized via contact with the acidic catalyst into species that possess lower octane levels or that do not possess boiling points as near to the boiling point of n-heptane, which promotes separation of the impurities via distillation. Close boiling impurities may include such compounds as cis-1,2-dimethylcyclopentane and methylcyclohexane or may be compounds having boiling points at a standard pressure of 760 Torr in the range of about 96.5 to about 100.5 degrees Celsius including such compounds as cis-1,2-dimethylcyclopentane and methylcyclohexane. The concentration of cis-1,2-dimethylcyclopentane and methylcyclohexane may be reduced by at least about 25 and 10 percent by weight, respectively. The concentration of olefins, as measured by the Bromine Index, may be reduced by at least about 25 percent by weight.
    • 通过使庚烷料流与酸性催化剂接触,从庚烷物流中除去杂质,其中接触降低了一种或多种近沸点杂质,一种或多种烯烃或两者的浓度。 通过与酸性催化剂接触将杂质异构化为具有较低辛烷值或不具有接近正庚烷沸点的沸点的物质,这促进通过蒸馏分离杂质。 接近沸腾的杂质可以包括诸如顺式-1,2-二甲基环戊烷和甲基环己烷的化合物,或者可以是在约96.5至约100.5摄氏度的标准压力为760托的沸点的化合物,包括顺式-1, 2-二甲基环戊烷和甲基环己烷。 顺式-1,2-二甲基环戊烷和甲基环己烷的浓度可以分别降低至少约25重量%和10重量%。 通过溴指数测量的烯烃浓度可以降低至少约25重量%。
    • 10. 发明授权
    • Modeling and simulation of a reaction for hydrotreating hydrocarbon oil
    • 烃油加氢处理反应的建模与模拟
    • US5841678A
    • 1998-11-24
    • US785467
    • 1997-01-17
    • Daniel M. HasenbergJoseph F. Campagnolo, Jr.
    • Daniel M. HasenbergJoseph F. Campagnolo, Jr.
    • C10G45/72G06G7/58
    • C10G45/72
    • A computer implemented method for modeling and simulating a hydrotreating reactor is disclosed where a first step in the simulation utilizes a computer data base of reaction kinetic parameters for hydrotreating sulfur and metals contaminated residuum and gas oil fractions. The data base is extended to include parameters and physical properties for residuum and gas oil fractions that are obtained from several different source locations. A group of equations, which are functions of catalyst properties, reactor parameters and feedstock composition, models the reaction by predicting yields, hydrogen consumption, contaminant levels, and physical properties of the reactor product. The simulation adjusts the kinetic parameters for reaction conditions to be simulated, such as temperature, catalyst activity, hours on stream, space velocity etc., and solves the model equations for the desired results. The simulation is particularly useful for evaluating a slate of crude oils to aid in selecting an economical crude oil for future processing in a refinery.
    • 公开了一种用于建模和模拟加氢处理反应器的计算机实现方法,其中模拟的第一步骤利用用于加氢处理硫和金属污染的渣油和瓦斯油馏分的反应动力学参数的计算机数据库。 数据库扩展到包括从几个不同的源位置获得的残油和瓦斯油馏分的参数和物理性质。 作为催化剂性能,反应器参数和原料组成的函数的一组方程通过预测反应器产物的产率,氢消耗,污染物水平和物理性质来模拟反应。 模拟调整待模拟反应条件的动力学参数,如温度,催化剂活性,流通时间,空间速度等,并求出所需结果的模型方程。 该模拟对于评估原油石油有助于选择经济原油以供炼油厂未来加工特别有用。