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    • 7. 发明授权
    • Ultraviolet absorbing poly (organic oxidized silicon) particles having improved ultraviolet stability, and method for preparing same
    • 具有改善的紫外线稳定性的紫外线吸收性聚(有机氧化硅)颗粒及其制备方法
    • US08921505B2
    • 2014-12-30
    • US13810177
    • 2011-07-15
    • Young Baek KimGoo Jin JeongIn Whan Kim
    • Young Baek KimGoo Jin JeongIn Whan Kim
    • C08G77/26A61K8/893A61K8/02A61K8/81A61K8/898A61Q17/04C08G77/00
    • A61K8/898A61K8/025A61K8/8158A61K8/893A61K2800/612A61Q17/04C08G77/26C08G77/80
    • The present invention relates to a method for preparing poly(organic oxidized silicon) particles having UV-absorbing groups, including reacting an organoalkoxysilane precursor having a UV-absorbing group selected from a group consisting of organotrialkoxysilane, diorganoalkoxysilane and a mixture thereof, in the presence of a base, with a silane compound selected from a group consisting of tetraalkoxysilane, alkyltrialkoxysilane, tetraalkoxysilane, aryltrialkoxysilane, dialkyldialkoxysilane, diaryldialkoxysilane, arylalkyldialkoxysilane and a mixture thereof, serving as a crosslinking regulator and UV stability enhancer, so as to prepare poly(organic oxidized silicon) particles selected from a group consisting of polysilsesquioxane, silsesquioxane-siloxane copolymer, silsesquioxane-silica copolymer, silsesquioxane-siloxane-silica copolymer and silsesquioxane-siloxane copolymer, having UV-absorbing groups. The poly(organic oxidized silicon) particles significantly solves the problem of poor UV stability, while maintaining UV absorption by the UV-absorbing group contained in the particles. Since the poly(organic oxidized silicon) particles having UV-absorbing groups do not exhibit white turbidity, they can be effectively used in cosmetics. In accordance with the present invention, the poly(organic oxidized silicon) particles having UV-absorbing groups can be prepared economically as compared to the existing methods.
    • 本发明涉及一种制备具有UV吸收基团的聚(有机氧化硅)颗粒的方法,包括使有机烷氧基硅烷前体具有选自有机三烷氧基硅烷,二有机基烷氧基硅烷及其混合物的UV吸收基团的有机烷氧基硅烷前体, 的基团,其具有选自四烷氧基硅烷,烷基三烷氧基硅烷,四烷氧基硅烷,芳基三烷氧基硅烷,二烷基二烷氧基硅烷,二芳基二烷氧基硅烷,芳基烷基二烷氧基硅烷及其混合物的硅烷化合物,用作交联调节剂和UV稳定性增强剂,以制备聚(有机氧化 选自聚倍半硅氧烷,倍半硅氧烷 - 硅氧烷共聚物,倍半硅氧烷 - 二氧化硅共聚物,倍半硅氧烷 - 硅氧烷 - 二氧化硅共聚物,倍半硅氧烷 - 硅氧烷共聚物,硅氧烷 - 硅氧烷共聚物。 聚(有机氧化硅)颗粒显着解决了紫外线稳定性差的问题,同时通过颗粒中所含的紫外线吸收剂保持紫外线吸收。 由于具有UV吸收基团的聚(有机氧化硅)颗粒不显示白色混浊,因此它们可以有效地用于化妆品中。 根据本发明,与现有方法相比,具有UV吸收基团的聚(有机氧化硅)颗粒可以经济地制备。
    • 9. 发明申请
    • ULTRAVIOLET ABSORBING POLY (ORGANIC OXIDIZED SILICON) PARTICLES HAVING IMPROVED ULTRAVIOLET STABILITY, AND METHOD FOR PREPARING SAME
    • 具有改进的超紫外线稳定性的超紫外线吸收聚(有机氧化硅)颗粒及其制备方法
    • US20130109824A1
    • 2013-05-02
    • US13810177
    • 2011-07-15
    • Young Baek KimGoo Jin JeongIn Whan Kim
    • Young Baek KimGoo Jin JeongIn Whan Kim
    • A61K8/898A61Q17/04A61K8/81
    • A61K8/898A61K8/025A61K8/8158A61K8/893A61K2800/612A61Q17/04C08G77/26C08G77/80
    • The present invention relates to a method for preparing poly(organic oxidized silicon) particles having UV-absorbing groups, including reacting an organoalkoxysilane precursor having a UV-absorbing group selected from a group consisting of organotrialkoxysilane, diorganoalkoxysilane and a mixture thereof, in the presence of a base, with a silane compound selected from a group consisting of tetraalkoxysilane, alkyltrialkoxysilane, tetraalkoxysilane, aryltrialkoxysilane, dialkyldialkoxysilane, diaryldialkoxysilane, arylalkyldialkoxysilane and a mixture thereof, serving as a crosslinking regulator and UV stability enhancer, so as to prepare poly(organic oxidized silicon) particles selected from a group consisting of polysilsesquioxane, silsesquioxane-siloxane copolymer, silsesquioxane-silica copolymer, silsesquioxane-siloxane-silica copolymer and silsesquioxane-siloxane copolymer, having UV-absorbing groups. The poly(organic oxidized silicon) particles significantly solves the problem of poor UV stability, while maintaining UV absorption by the UV-absorbing group contained in the particles. Since the poly(organic oxidized silicon) particles having UV-absorbing groups do not exhibit white turbidity, they can be effectively used in cosmetics. In accordance with the present invention, the poly(organic oxidized silicon) particles having UV-absorbing groups can be prepared economically as compared to the existing methods.
    • 本发明涉及一种制备具有UV吸收基团的聚(有机氧化硅)颗粒的方法,包括使有机烷氧基硅烷前体具有选自有机三烷氧基硅烷,二有机基烷氧基硅烷及其混合物的UV吸收基团的有机烷氧基硅烷前体, 的基团,其具有选自四烷氧基硅烷,烷基三烷氧基硅烷,四烷氧基硅烷,芳基三烷氧基硅烷,二烷基二烷氧基硅烷,二芳基二烷氧基硅烷,芳基烷基二烷氧基硅烷及其混合物的硅烷化合物,用作交联调节剂和UV稳定性增强剂,以制备聚(有机氧化 选自聚倍半硅氧烷,倍半硅氧烷 - 硅氧烷共聚物,倍半硅氧烷 - 二氧化硅共聚物,倍半硅氧烷 - 硅氧烷 - 二氧化硅共聚物,倍半硅氧烷 - 硅氧烷共聚物,硅氧烷 - 硅氧烷共聚物。 聚(有机氧化硅)颗粒显着解决了紫外线稳定性差的问题,同时通过颗粒中所含的紫外线吸收剂保持紫外线吸收。 由于具有UV吸收基团的聚(有机氧化硅)颗粒不显示白色混浊,因此它们可以有效地用于化妆品中。 根据本发明,与现有方法相比,具有UV吸收基团的聚(有机氧化硅)颗粒可以经济地制备。