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1. 发明授权

US06332976B1 Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst 有权
标题翻译：含有磷的催化剂和使用催化剂的石油进料的工艺加氢处理
公开(公告)号：US06332976B1
公开(公告)日：2001-12-25
申请号：US09310105
申请日：1999-05-12
申请人： Samuel Mignard , Nathalie George-Marchal , Virginie Harle , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Virginie Harle , Slavik Kasztelan
IPC分类号： C10G4508
CPC分类号： B01J27/188 , B01J35/002 , B01J35/1019 , B01J35/1061 , B01J35/108 , C10G45/08 , C10G49/04
摘要： The invention concerns an alumina based catalyst containing, expressed as the oxide content by weight, 2-10% by weight of cobalt oxide CoO, 10-30% by weight of molybdenum oxide MoO3 and 4-10% of phosphorous oxide P2O5, with a BET surface area in the range 100-300 m2/g, a crushing strength CSH of more than 1.4 MPa, and an average pore diameter in the range 8-11 nm, the pore volume of pores with diameter of more than 14 nm being less than 0.08 ml/g, or less than 22% of total pore volume, the volume of pores with a diameter of less than 8 nm being at most 0.05 ml/g, or less than 10% of total pore volume, the volume of pores with diameter less than 10 nm being in the range of 20%-70%, the volume of pores with diameter between 10 nm and 13 nm being in the range of 20%-60%, and the volume of pores with a diameter which is in the range 8 to 14 nm being in the range 0.20 ml/g to 0.8 ml/g. The invention also concerns a hydrotreatment process using the catalyst, in particular hydrodesulphuration.
摘要翻译：本发明涉及一种氧化铝基催化剂，其含有氧化物含量为2-10重量％的氧化钴CoO，10-30重量％的氧化钼MoO 3和4-10重量％的氧化磷P2O5，其中a BET表面积在100-300m2 / g范围内，抗碎强度CSH大于1.4MPa，平均孔径在8-11nm范围内，孔径大于14nm的孔体积较小直径小于8nm的孔的体积至少为0.05ml / g，或小于总孔体积的10％，孔的体积小于0.08ml / g，或小于总细孔容积的22％直径小于10nm的范围在20％-70％的范围内，直径在10nm和13nm之间的孔的体积在20％-60％的范围内，直径的孔的体积是在8至14nm的范围内在0.20ml / g至0.8ml / g的范围内。本发明还涉及使用该催化剂，特别是加氢脱硫的加氢处理方法。

2. 发明授权

US5762902A Catalyst comprising a faujasite type zeolite and a ton type zeolite and a process for the hydroconversion of hydrocarbon petroleum feeds 失效
标题翻译：包含八面沸石型沸石和吨型沸石的催化剂以及烃石油原料的加氢转化方法
公开(公告)号：US5762902A
公开(公告)日：1998-06-09
申请号：US786646
申请日：1997-01-21
申请人： Eric Benazzi , Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
发明人： Eric Benazzi , Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： B01J29/08 , B01J29/70 , B01J29/80 , C01B39/20 , C10G47/20 , C10G49/16 , C01B33/36 , B01J29/06
CPC分类号： C10G49/16 , B01J29/80 , B01J29/084 , B01J29/70 , Y10S423/21 , Y10S423/35
摘要： The invention concerns a composition comprising at least one matrix, at least one faujasite type zeolite and at least one TON type zeolite. The TON type zeolite can be Nu-10, THETA-1, KZ-2, or ISI-1. The catalyst also contains at least one hydrogenating element from groups VIII and VI. The catalyst is particularly for use for hydrocracking to maximize the yield of middle distillates (kerosine and gas oil).
摘要翻译：本发明涉及包含至少一种基质，至少一种八面沸石型沸石和至少一种TON型沸石的组合物。 TON型沸石可以是Nu-10，THETA-1，KZ-2或ISI-1。催化剂还含有至少一个来自VIII和VI族的氢化元素。催化剂特别用于加氢裂化以使中间馏分（煤油和瓦斯油）的产率最大化。

3. 发明授权

US06174429B1 Catalyst and process for hydrocracking fractions that contain hydrocarbon 有权
$Catalyst and process for hydrocracking fractions that contain hydrocarbon$
标题翻译：含有烃的加氢裂化馏分的催化剂和方法
公开(公告)号：US06174429B1
公开(公告)日：2001-01-16
申请号：US09175468
申请日：1998-10-20
申请人： Nathalie George-Marchal , Samuel Mignard , Slavik Kasztelan
发明人： Nathalie George-Marchal , Samuel Mignard , Slavik Kasztelan
IPC分类号： C10G4700
CPC分类号： C10G47/20 , B01J29/166 , B01J35/108 , B01J2229/42
摘要： The invention relates to a hydrocracking catalyst that contains at least one metal of group VIB, and/or at least one metal of group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA (fluorine), and a zeolite Y that is not fully dealuminificated, with a crystalline parameter that is greater than 2,438 nm, an overall SiO2/Al2O3 ratio that is less than 8, and a framework SiO2/Al2O3 ratio that is less than 21 and greater than the overall SiO2/Al2O3 ratio. The invention also relates to a process for hydrocracking with this catalyst, in particular at low pressure of 7.5 to 11 MPa.
摘要翻译：本发明涉及加氢裂化催化剂，其含有至少一种VIB族金属和/或至少一种周期表第VIII族金属，氧化铝基质，磷，任选地至少一种来自VIIA族（氟）的元素，和未完全脱沥青的沸石Y，其结晶参数大于2,438nm，SiO 2 / Al 2 O 3的总体比小于8，骨架SiO 2 / Al 2 O 3比小于21且大于总体 SiO2 / Al2O3比例。本发明还涉及一种用该催化剂进行加氢裂化的方法，特别是在7.5至11MPa的低压下。

4. 发明授权

US6045687A Catalyst containing at least two dealuminated Y zeolites and a conventional hydroconversion process for petroleum cuts using this catalyst 失效
标题翻译：含有至少两种脱铝Y沸石的催化剂和使用该催化剂的石油馏分的常规加氢转化方法
公开(公告)号：US6045687A
公开(公告)日：2000-04-04
申请号：US955626
申请日：1997-10-22
申请人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
IPC分类号： B01J29/08 , B01J29/16 , B01J35/10 , C10G47/16 , C10G47/18 , C10G47/20
CPC分类号： C10G47/20 , B01J29/084 , C10G47/16 , B01J2229/26 , B01J2229/42
摘要： A catalyst support comprising at least one matrix, at least one Y zeolite with a lattice parameter which is in the range 24.15 .ANG. to 24.38 .ANG. (1 nm=10 .ANG.) and at least one Y zeolite with a lattice parameter of more than 24.38 .ANG. and less than or equal to 24.51 .ANG.. The invention also concerns a catalyst comprising said support and at least one hydro-dehydrogenating element, and a conventional hydroconversion process for petroleum cuts using said catalyst.
摘要翻译：一种催化剂载体，其包含至少一种基质，至少一种具有晶格参数的Y沸石，所述Y沸石的范围为24.15ng至24.38（1nm =10），和至少一个晶格参数大于24.38的Y沸石小于等于24.51安。本发明还涉及包含所述载体和至少一种氢脱氢元件的催化剂，以及使用所述催化剂进行石油切割的常规加氢转化方法。

5. 发明授权

US06420296B2 Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon 有权
标题翻译：催化剂包含全部非脱铝并含有硼和/或硅的沸石Y
公开(公告)号：US06420296B2
公开(公告)日：2002-07-16
申请号：US09305296
申请日：1999-05-05
申请人： Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： B01J2910
CPC分类号： C10G47/20 , B01J29/166
摘要： A catalyst comprising 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); 0.1-20% by weight of at least one group VIIB element, useful for hydrocracking processes, especially at low pressures of 7.5 to 11 MPa.
摘要翻译：包含0.1-99.7重量％的至少一种氧化铝基质的催化剂; 0.1-80重量％的至少一种全球非脱铝Y沸石，其晶格参数大于2.438nm，全球SiO 2 / Al 2 O 3摩尔比小于8，框架SiO 2 / Al 2 O 3摩尔比小于21，超过全球SiO2 / Al2O3摩尔比; 0.1-30重量％的至少一种VIII族金属和/或1-40重量％的至少一种VIB族金属（％氧化物）; 至少一种选自硼和硅（％氧化物）形成的基团的至少一种助催化剂元素; 0-20重量％的至少一种VIIA族元素; 0-20重量％的磷（氧化物％）; 0.1-20重量％的至少一种VIIB族元素，可用于加氢裂化过程，特别是在7.5至11MPa的低压下。

6. 发明授权

US6037300A Catalyst containing boron and silicon and its use for hydrotreating hydrocarbon feeds 失效
标题翻译：含有硼和硅的催化剂及其用于加氢处理烃进料的用途
公开(公告)号：US6037300A
公开(公告)日：2000-03-14
申请号：US992084
申请日：1997-12-17
申请人： Slavik Kasztelan , Samuel Mignard , Virginie Harle , Nathalie George-Marchal
发明人： Slavik Kasztelan , Samuel Mignard , Virginie Harle , Nathalie George-Marchal
IPC分类号： B01J23/652 , B01J21/04 , B01J23/24 , B01J23/85 , B01J23/88 , B01J23/883 , B01J27/12 , B01J27/188 , B01J27/19 , B01J37/00 , C10G49/02 , C10G49/04 , C10G49/06 , B01J21/02 , B01J23/00 , B01J27/132
CPC分类号： B01J23/24 , B01J23/85 , C10G49/02 , B01J21/04 , B01J23/883 , B01J37/0009
摘要： The invention concerns a hydrotreated catalyst comprising a support, at least one group VI metal, silicon, boron, optionally at least one metal from group VIII of the periodic table, optionally phosphorus, and optionally a halogen, also a particular preparation of this catalyst. The invention also concerns the use of the catalyst for hydrotreating hydrocarbon feeds.
摘要翻译：本发明涉及加氢处理的催化剂，其包含载体，至少一种第Ⅵ族金属，硅，硼，任选地至少一种来自元素周期表Ⅷ族的金属，任选的磷，以及任选的卤素，也是该催化剂的具体制剂。本发明还涉及催化剂用于加氢处理烃进料的用途。

7. 发明授权

US5954947A Process for mild hydrocracking of petroleum cuts using a catalyst containing at least two dealuminated Y zeolites 失效
标题翻译：使用含有至少两种脱铝Y沸石的催化剂轻度加氢裂化石油馏分的方法
公开(公告)号：US5954947A
公开(公告)日：1999-09-21
申请号：US955623
申请日：1997-10-22
申请人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
IPC分类号： B01J29/16 , B01J29/08 , B01J29/40 , B01J29/80 , B01J37/20 , C10G47/16 , C10G47/18 , C10G47/20
CPC分类号： B01J29/80 , C10G47/16 , C10G47/20 , B01J2229/16 , B01J2229/26 , B01J2229/42 , B01J29/084 , B01J29/40
摘要： A mild hydroconversion process for petroleum cuts using a catalyst comprising at least one matrix, at least one Y zeolite with a lattice parameter which is in the range 24.15 .ANG. to 24.38 .ANG. (1 nm--10 .ANG.), at least one Y zeolite with a lattice parameter of more than 24.38 .ANG. and less than or equal to 24.51 .ANG., and at least one hydro-dehydrogenating element.
摘要翻译：用于使用包含至少一种基质，至少一种晶格参数的Y沸石的催化剂进行石油切割的温和加氢转化方法，所述Y沸石的范围为24.15至24.38（1nm-10），至少一个具有晶格参数大于24.38安培，小于或等于24.51安培，以及至少一个氢脱氢元件。

8. 发明授权

US06719895B2 Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon 有权
标题翻译：催化剂包含全部非脱铝并含有硼和/或硅的沸石Y
公开(公告)号：US06719895B2
公开(公告)日：2004-04-13
申请号：US09965804
申请日：2001-10-01
申请人： Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： C10G4716
CPC分类号： C10G47/20 , B01J29/166
摘要： The present invention relates to a hydrocracking process including contacting a hydrocarbon feed with a catalyst which is carried out at a pressure of at least 2 MPa, a temperature of at least 230° C., using a quantity of hydrogen of at least 100 Nl hydrogen/l of feed and with an hourly space velocity of 0.1-10 h−1. The catalyst includes 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); and 0.1-20% by weight of at least one group VIIB element.
摘要翻译：本发明涉及一种加氢裂化方法，包括使烃进料与催化剂接触，所述催化剂在至少2MPa的压力，至少230℃的温度下使用至少100N氢气的氢气进行 / l的饲料，每小时空速为0.1-10小时-1。催化剂包含0.1-99.7重量％的至少一个氧化铝基质; 0.1-80重量％的至少一种全部非脱铝Y沸石，其晶格参数大于2.438nm，全体SiO 2 / Al 2 O 3摩尔比小于8，并且SiO 2 / Al 2 O 3的骨架比小于21且大于全局SiO 2 / Al 2 O 3摩尔比; 0.1-30重量％的至少一种VIII族金属和/或1-40重量％至少一种VIB族金属（％氧化物）; 0.1-20％重量的选自硼和硅（氧化物％）的至少一种助催化剂元素; 0-20％重量的至少一种VIIA族元素 ; 0-20重量％的磷（％氧化物）; 和0.1-20重量％的至少一种VIIB族元素。

9. 发明授权

US06187708B1 Process for activation of catalysts with a nitrogenous compound and excess thionic compound the catalysts that is obtained and it use in hydroconversion 有权
标题翻译：用含氮化合物和过量的硫辛酸化合物活化催化剂的方法，所得催化剂及其在加氢转化中的应用
公开(公告)号：US06187708B1
公开(公告)日：2001-02-13
申请号：US09305285
申请日：1999-05-05
申请人： Samuel Mignard , Virginie Harle , Slavik Kasztelan , Nathalie Marchal-George
发明人： Samuel Mignard , Virginie Harle , Slavik Kasztelan , Nathalie Marchal-George
IPC分类号： B01J3720
CPC分类号： B01J37/20 , C10G47/12
摘要： The invention relates to a process for the sulfurization of hydroconversion catalysts, whereby said catalyst contains at least one element of group VIII of the periodic table and optionally an element of group VI, whereby said metal is present in the oxide state. Said process comprises at least one stage that is carried out in a hydrotreatment zone in the presence of at least one thionic compound and at least one nitrogenous compound. This process is carried out in such a way that before the final sulfurization temperature is reached, at least 130% of the stoichiometric amount of sulfur that is necessary for complete sulfurization of the catalyst is injected in said catalyst.
摘要翻译：本发明涉及一种加氢转化催化剂硫化方法，其中所述催化剂含有至少一种元素周期表第Ⅷ族元素和任选的第Ⅵ族元素，其中所述金属以氧化态存在。所述方法包括在至少一种硫辛酸化合物和至少一种含氮化合物的存在下在加氢处理区中进行的至少一个阶段。该方法是在达到最终硫化温度之前进行的，在催化剂中注入催化剂完全硫化所需的化学计量量的至少130％的硫。

10. 发明授权

US5789637A Process for the hydrogenation of aromatic compounds comprising chlorine injection, using catalysts based on a noble metal 失效
公开(公告)号：US5789637A
公开(公告)日：1998-08-04
申请号：US671501
申请日：1996-06-27
申请人： Samuel Mignard , Virginie France Harle , Slavik Kasztelan , Nathalie Marchal-George
发明人： Samuel Mignard , Virginie France Harle , Slavik Kasztelan , Nathalie Marchal-George
IPC分类号： B01J27/13 , C07B61/00 , C07C5/10 , C07C13/28 , C10G45/52
CPC分类号： C10G45/52
摘要： The invention concerns a process for the hydrogenation of aromatic compounds contained in feeds with an initial boiling point of more than 100.degree. C. and which contain at least 10% by weight of aromatic compounds. It consists of introducing chlorine in a concentration of 0.5-500 ppm by weight with respect to the feed at a temperature of between 200.degree. C. and 450.degree. C., a pressure in the range 1 MPa to 25 MPa, an HSV of between 0.1 h.sup.-1 and 10 h.sup.-1 and a volume ratio of hydrogen to feed of 100-2000. The catalyst used is a noble metal type and contains less than 1% of at least one halogen. Preferably, the catalyst is fluorinated or chlorinated.

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