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    • 3. 发明申请
    • 4-(3,3-DIHALO-ALLYLOXY)PHENOXY ALKYL DERIVATIVES
    • 4-(3,3-DIHALO-ALLYLOXY)苯氧基衍生物
    • WO2004002943A1
    • 2004-01-08
    • PCT/EP2003/006846
    • 2003-06-27
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • ZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • C07C233/75
    • C07D207/27C07C217/84C07C233/25C07C233/29C07C233/75C07C271/28C07D207/325C07D207/444C07D207/452C07D263/22C07D307/68C07D333/38
    • Compounds of formula (I), wherein A 1 , A 2 and A 3 are each independently of the others a bond or a C 1 -C 6 alkylene bridge; A 4 is a C 1 -C 6 alkylene bridge; Di s CH or N; W is, for example, O, NR 7 or S; T is, for example, a bond, O, NH or NR 7 ; Q is O, NR 7 , S, SO or SO 2 ; Y is O, NR 7 , S, SO, or SO 2 ; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; R 1 , R 2 and R 3 ar, for example, H, halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; R 4 is, for example, H, halogen, CN, nitro or C 1 -C 6 alkyl; R 5 and R 6 are, for example, H, CN, OH, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl-C 1 -C 6 alkyl, C 1 -C 6 haloalky, C 1 -C 6 alkoxy or C 1 -C 6 haloalkoxy; R 7 is H, C 1 -C 6 alkyl, C 1 -C 6 alkoxyalkyl or C 1 -C 6 alkylcarbonyl; k, when D is nitrogen, is 1, 2 or 3; or, when D is CH, is 1, 2, 3 or 4; and m is 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)的化合物,其中A1,A2和A3各自独立地为键或C1-C6亚烷基桥; A4是C1-C6亚烷基桥; Di s CH或N; W是例如O,NR7或S; T是例如键,O,NH或NR 7; Q是O,NR7,S,SO或SO2; Y是O,NR7,S,SO或SO2; X1和X2各自独立地为氟,氯或溴; R1,R2和R3Ar,例如H,卤素,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基或C2-C6链烯基; R4是例如H,卤素,CN,硝基或C1-C6烷基; R 5和R 6是例如H,CN,OH,C 1 -C 6烷基,C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷氧基或C 1 -C 6卤代烷氧基; R 7是H,C 1 -C 6烷基,C 1 -C 6烷氧基烷基或C 1 -C 6烷基羰基; k,当D为氮时,为1,2或3; 或当D为CH时,为1,2,3或4; m为1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 4. 发明申请
    • DIHALO-ALLYLOXY-PHENOL DERIVATIVES HAVING PESTICIDAL ACTIVITY
    • 具有杀虫活性的二氢 - 全氟代苯酚衍生物
    • WO2004052816A1
    • 2004-06-24
    • PCT/EP2003/014009
    • 2003-12-10
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • ZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • C07C43/225
    • A01N37/34C07C43/225C07C43/23C07C43/315C07C45/29C07C45/71C07C49/255C07C69/76C07C205/32C07C251/40C07C255/37C07C255/41C07C271/16C07C2601/02C07D213/57C07D261/08C07D307/54C07D307/81C07D333/24C07C49/84
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other a bond or a C 1 -C 6 alkylene bridge; A 3 is a C 1 -C 6 alkylene bridge; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; Y is O, NR 7 , S, SO or SO 2 ; R 1 , R 2 and R 3 are each independently of the others, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; Q is O, NR 5 , S, SO or SO 2 ; W is, for example, O, NR 5 or SO; T is for example, a bond, O or NR 5 ; D is CH or N; R 4 is, for example, H, halogen, OH, SH, CN or nitro; R 5 and R 7 are, for example, H, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; k is 1, 2, 3 or 4; m is 1 or 2; R 10 is a radical which contains O, N or S; R 11 is, for example, H, C 1 -C 12 alkyl or a radical which contains from one to three hetero atoms selected from O, N and S; or R 11 together with R 12 is a bond; R 12 is, for example, H, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 -alkyl; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free from or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof; a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)化合物,其中A1和A2各自独立地为一个键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; X1和X2各自独立地为氟,氯或溴; Y是O,NR7,S,SO或SO2; R 1,R 2和R 3各自独立地为H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基羰基或C 2 -C 6烯基; Q是O,NR5,S,SO或SO2; W是例如O,NR5或SO; T为例如O或NR5的键; D是CH或N; R4是例如H,卤素,OH,SH,CN或硝基; R5和R7是例如H,C1-C6烷基或C1-C3卤代烷基; k为1,2,3或4; m为1或2; R10是含有O,N或S的基团; R 11是例如H,C 1 -C 12烷基或含有1至3个选自O,N和S的杂原子的基团; 或R11与R12一起为键; R 12是例如H,C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6 - 烷基; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体在每种情况下不含或以盐形式,制备这些化合物的方法及其用途,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分; 制备这些组合物及其用途的方法,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 5. 发明申请
    • PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES
    • 杀虫活性酮和氧化衍生物
    • WO2004113273A1
    • 2004-12-29
    • PCT/EP2004/006749
    • 2004-06-22
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerHALL, Roger, GrahamRENOLD, PeterTRAH, Stephan
    • ZAMBACH, WernerHALL, Roger, GrahamRENOLD, PeterTRAH, Stephan
    • C07C251/44
    • C07D333/58A01N33/24A01N35/10A01N37/52A01N41/06A01N43/10A01N43/40A01N43/78A01N43/80C07C49/753C07C49/755C07C49/84C07C235/84C07C251/44C07C251/48C07C251/54C07C251/58C07C311/04C07C311/05C07C311/09C07C323/47C07D213/50C07D213/53C07D213/61C07D213/64C07D261/08C07D277/24C07D277/28C07D307/52C07D307/81C07D333/22
    • Compounds of formula (I), wherein A 0 , A 1 , and A 2 are each independently of the others a bond or a C l -C 6 alkylene bridge; A 3 is a C l -C 6 alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C 3 -C 8 cycloalkyl; Y is, for example, 0, S, SO or S0 2 ; M is 0 or NOR 6 , X 1 , and X 2 are each independently of the other fluorine, chlorine or bromine; R 1 , R 2 and R 3 are, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C l -C 6 haloalkyl, C l -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl or C 2 -C 6 alkynyl; Q is, for example, O, S, SO or SO 2 ; W is, for example, 0, S, SO, SO 2 , -C(=O)-O- or -0-C(=O)-; T is, for example, a bond, 0, S, SO, S0 2 , -C(=O)-O­or -0-C(=O)-; D is CH or N; R 4 is, for example, H, halogen, OH, SH, CN, nitro, C l -C 6 alkyl or C 1 -C 6 haloalkyl; R 5 is, for example, C l -C l2 alkyl, C 3 -C 8 cycloalkyl or -N(R 7 ) 2 ; R 7 is H, C 1 -C 6 alkyl, C l -C 3 haloalkyl, C l -C 6 alkylcarbonyl, C l -C 3 haloalkylcarbonyl, C l -C 6 alkoxycarbonyl, C 3 -C 8 Cycloalkyl, C 3 -C 8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)的化合物,其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如0,S,SO或SO 2; M为0或NOR6,X1和X2各自独立地为氟,氯或溴; R 1,R 2和R 3是例如H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基羰基,C 2 -C 6烯基,C 2 -C 6卤代烯基或C 2 -C 6炔基; Q是例如O,S,SO或SO 2; W是例如0,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; T是例如键,0,S,SO,SO 2,-C(= O)-O或-O-C(= O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从那些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的植物繁殖材料和控制害虫的方法。
    • 6. 发明申请
    • HETEROCYCLIC ALLYL DERIVATIVES
    • 杂环衍生物
    • WO2005068445A2
    • 2005-07-28
    • PCT/EP2005/000094
    • 2005-01-07
    • SYNGENTA PARTICIPATIONS AGHALL, Roger, GrahamTRAH, StephanZAMBACH, WernerTULEJA, Juraj
    • HALL, Roger, GrahamTRAH, StephanZAMBACH, WernerTULEJA, Juraj
    • C07D285/12
    • C07D271/113C07D233/72C07D237/14C07D239/36C07D241/18C07D249/12C07D273/04C07D285/13
    • The invention relates to compounds of formula (I) wherein Het, A 1 , A 2 , A 3 , A 4 , D, W, T, Q, Y, X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.
    • 本发明涉及式(I)化合物,其中Het,A1,A2,A3,A4,D,W,T,Q,Y,X1,X2,R1,R2,R3,R4,k和m如上所定义 ,以及(如适用)可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备和使用这些化合物的方法 ,E / Z异构体,E / Z异构体和/或互变异构体的混合物,其中活性成分选自那些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物的农药组合物 游离形式或农业可用盐形式的情况,制备和使用这些组合物的方法,用这些组合物处理的繁殖材料,控制害虫的方法,中间体以及在适用的情况下 可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备那些 磅,E / Z异构体,E / Z异构体和/或互变异构体的混合物,以及制备和使用那些中间体的方法,以及可能的E / Z异构体,E / Z异构体的混合物 和/或其互变异构体。
    • 7. 发明申请
    • PESTICIDALLY ACTIVE PHENOL DERIVATIVES
    • 杀虫活性酚醛衍生物
    • WO2005019147A2
    • 2005-03-03
    • PCT/EP2004/009500
    • 2004-08-25
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerTRAH, StephanHALL, Roger, GrahamLUTZ, William
    • ZAMBACH, WernerTRAH, StephanHALL, Roger, GrahamLUTZ, William
    • C07C43/00
    • A01N37/20A01N31/16A01N35/10A01N43/10A01N43/40A01N43/54A01N43/56A01N43/653A01N43/713A01N43/80A01N43/82A01N43/84C07C43/225C07C49/255C07C49/84C07C69/65C07C205/37C07C233/22C07C251/48C07C255/54C07D213/53C07D213/64C07D231/20C07D239/38C07D249/12C07D257/04C07D261/18C07D271/07C07D295/096C07D333/22C07D401/04C07F7/0818
    • There are described compounds of formula (I) wherein X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; A 1 and A 2 are, for example, a bond or a C 1 -C 6 alkylene bridge; A 3 is a C 1 -C 6 alkylene bridge; R 1 and R 2 are, for example, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkyl-carbonyl, C 2 ­C 6 alkenyl, C 2 -C 6 haloalkenyl or C 3 -C 6 alkynyl; R, 3 is, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl or C 1 -C 6 haloaikyl; R 4 and R 5 are, for example, H, halogen, cyano, nitro, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; m is 1 or 2; Y is, for example, O, S, SO or SO 2 ; Q is, for example, O, S, SO or SO 2 ; W is, for example, a bond, O, S, SO, S02, -C(=O)-O- or -O-C(=O)-; T is, for example, a bond, O, S, SO, SO 2 , -C(=O)-O- or -O-C(=O)-; and E is aryl unsubstituted or substituted from one to five times or heterocyclyl unsubstituted or, depending upon the possibilities of substitution on the ring, substituted from one to four times; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 描述了式(I)的化合物,其中X 1和X 2各自独立地为其它氟,氯或溴; A1和A2是例如键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; R 1和R 2是例如卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基 - 羰基,C 2 C 6烯基,C 2 -C 6卤代烯基或C 3 -C 6炔基; R 3是例如H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基或C 1 -C 6卤代烷基; R4和R5是例如H,卤素,氰基,硝基,C1-C6烷基或C1-C3卤代烷基; m为1或2; Y是例如O,S,SO或SO 2; Q是例如O,S,SO或SO 2; W是例如键,O,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; T是例如键,O,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; 并且E是未取代的或未取代的取代的芳基或未取代的杂环基,或取决于环上取代的可能性,取代1-4次; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物及其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 8. 发明申请
    • PESTICIDALLY ACTIVE AMINOACETONITRILES
    • 农药活性氨基嘌呤
    • WO2003004474A1
    • 2003-01-16
    • PCT/EP2002/007515
    • 2002-07-05
    • SYNGENTA PARTICIPATIONS AGSTEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • STEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • C07D239/28
    • C07D239/28C07D237/14C07D239/34C07D241/16C07D241/18C07D241/24C07D333/32
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other unsubstituted or mono- to penta-substituted aryl or unsubstituted or, depending upon the possibility of substitution at the ring, mono- to tetra-substituted heteroaryl bonded via a ring carbon atom; X and y are each independently of the other a bond, C 1 -C 6 alkylene, C 2 -C 6 alkenylene, C 2 -C 6 alkynylene, phenylene, -O-, -S- or C(=O)-; R 1 is, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 alkyl; R2 is, for example, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 alkyl; V is C 1 -C 6 alkylene, C 2 -C 6 alkenylene or C 2 -C 6 Alkynylene; W is O, S, -S(O)-, -S(O)-, -S(O 2 )- or N(R 3 ); and R 3 is hydrogen, C 1 -C 6 alkyl, -C(=O)-C 1 -C 6 alkyl or C 1 -C 6 alkyl or C 1 -C 6 alkyl-O-C 1 -C 6 alkyl; n is 0 or 1; and, when n is 1, R 4 and R 5 are, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 akyl; and, where applicable, diastereoisomers, E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form; a process for the preparation of those compounds and their tautomers and the use thereof; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers, and a process for the preparation of such compositions and the use thereof; intermediates, in free form or in salt form, for the preparation of such compounds and, where applicable, their tautomers, in free form or in salt form are described.
    • 式(I)化合物,其中A 1和A 2各自独立地为另一个未取代或单 - 或五 - 取代的芳基或未被取代的或根据在环上取代的可能性,通过一个或多个 - 环碳原子; X和Y各自独立地为键,C1-C6亚烷基,C2-C6亚烯基,C2-C6亚炔基,亚苯基,-O - , - S-或C(= O) - ; R 1是例如氢,C 1 -C 6烷基或卤代-C 1 -C 6烷基; R 2是例如C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6烷基; V是C 1 -C 6亚烷基,C 2 -C 6亚烯基或C 2 -C 6亚炔基; W是O,S,-S(O) - , - S(O) - , - S(O 2) - 或N(R 3)。 且R 3为氢,C 1 -C 6烷基,-C(= O)-C 1 -C 6烷基或C 1 -C 6烷基或C 1 -C 6烷基-O-C 1 -C 6烷基; n为0或1; 当n为1时,R 4和R 5为例如氢,C 1 -C 6烷基或卤代C 1 -C 6烷基; 和/或互变异构体,在各种情况下均为游离形式或盐形式;以及(如适用)非对映异构体,E / Z异构体,E / Z异构体混合物和/或互变异构体。 制备这些化合物及其互变异构体的方法及其用途; 活性成分选自那些化合物及其互变异构体的杀虫组合物及其制备方法及其用途; 描述了游离形式或盐形式的中间体,用于制备这些化合物,并且在适用的情况下,其互变异构体以游离形式或盐形式。