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    • 5. 发明申请
    • AVERMECTIN AND AVERMECTIN MONOSACCHARIDE DERIVATIVES SUBSTITUTED IN THE 4”- OR 4’-POSITION HAVING PESTICIDAL PROPERTIES
    • 在具有农药性质的4“或4”位置中取代的AVERMECTIN和AVERMECTIN单糖衍生物
    • WO2004067543A1
    • 2004-08-12
    • PCT/EP2004/000890
    • 2004-01-30
    • SYNGENTA PARTICIPATIONS AGPITTERNA, ThomasMURPHY KESSABI, FionaMAIENFISCH, PeterCASSAYRE, JéromeQUARANTA, LauraJUNG, Pierre
    • PITTERNA, ThomasMURPHY KESSABI, FionaMAIENFISCH, PeterCASSAYRE, JéromeQUARANTA, LauraJUNG, Pierre
    • C07H17/08
    • A01N43/90C07H17/08
    • What is described are a compound of the formula (I) Wherein U is -N(R 2 )OR 3 or -N + (O - )=C(R E )R Z ); n is 0 or 1; X-Y is -CH=CH- or -CH 2 -CH 2 -; R 1 is C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl; R 2 and R 3 are, for example; independently from each other, -Q, -C(=O)-Z-Q or -CN; R Z and R E are, independently from each other, -Q, -C(=O)-Z-Q or -CN; or R Z and R E together are a three- to seven membered alkylene or alkenylene bridge, which is unsubstituted or mono- to tri-substituted; Z is a bond, O or -NR 4 -; Q is H, C 1 -C 12 alkyl, C 2 -C 12 alkenyl, C 2 -C 12 alkynyl, C 3 -C 12 -cycloalkyl, C 5 -C 12 -cycloalkenyl, aryl, or heterocyclyl, which are unsubstituted or mono- to pentasubstituted; R 4 is for example H, C 1 -C 8 alkyl, hydroxy-C l -C 8 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 8 alkenyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.
    • 描述的是式(I)的化合物,其中U是-N(R 2)OR 3或-N +(O - )= C(RE)R Z); n为0或1; X-Y是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R2和R3例如是: 独立地为-Q,-C(= O)-Z-Q或-CN; RZ和RE彼此独立地为-Q,-C(= O)-Z-Q或-CN; 或RZ和RE一起是三至七元的亚烷基或亚烯基桥,其是未取代的或一至三取代的; Z是O或-NR4-键; Q是未被取代的或被一或五取代的H,C 1 -C 12烷基,C 2 -C 12烯基,C 2 -C 12炔基,C 3 -C 12环烷基,C 5 -C 12 - 环烯基,芳基或杂环基, R4是例如H,C1-C8烷基,羟基-C1-C8烷基,C3-C8环烷基或C2-C8链烯基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。
    • 7. 发明申请
    • AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4”- OR 4’-POSITION
    • 在4“或4”位置具有烷氧基甲基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物
    • WO2004056844A1
    • 2004-07-08
    • PCT/EP2003/014613
    • 2003-12-19
    • SYNGENTA PARTICIPATIONS AGMAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • MAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • C07H17/08
    • C07H17/08
    • What is described are a compound of the formula (I): wherein n is 0 or 1; A-B is -CH=CH- or -CH 2 -CH 2 -; R 1 is C 1 -C 12 -alkyl, C 3 -C 8 -cycloalkyl or C 2 -C 12 -alkenyl; R 2 is for example C 1 -C 12 -alkyl, C 2 -C 12 -alkenyl or C 2 -C 12 -alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, -N 3 , -N0 2 , C 3 -C 8 -Cycloalkyl, norbornylenyl-, C 3 -C 8­ Cycloalkenyl; C 3 -C 8 - halocycloalkyl, C l -C 12 -alkoxy, C 1 -C 6 -alkoxy-C 1 -C 6 -alkoxy, C 3 -C 8 -cycloalkoxy, C 1 -C 12 -­haloalkoxy, C 1 -C 12 -alkylthio, C 3 -C 8 -cycloalkylthio, C 1 -C 12 -haloalkylthio, C l -C 12 alkylsulfinyl, C 3 -C 8 -cycloalkylsulfinyl, C 1 -C 12 -haloalkylsulfinyl, C 3 -C 8 - halocycloalkylsulfinyl, C l -C 12 -alkylsulfonyl, C 3 -C 8 -cycloalkylsulfonyl, C 1 -C 12 ­haloalkylsulfonyl, C 3 -C 8 -halocycloalkylsulfonyl, -NR 4 R 6 , -X-C(=Y)-R 4 , -X-C(=Y)-Z-R 4 , -P(=O)(OC l -C 6 -alkyl) 2 , aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R 3 is for example H, C 1 -C 12 -alkyl or C 1 -C 12 -alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.
    • 描述的是式(I)的化合物:其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片烯基 - ,C 3 -C 8环烯基的取代基取代; C 3 -C 8 - 卤代环烷基,C 1 -C 12 - 烷氧基,C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8 - 环烷氧基,C 1 -C 12 - 卤代烷氧基,C 1 -C 12 - 烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基,C 3 -C 8卤代环烷基磺酰基, NR4R6,-XC(= Y)-R4,-XC(= Y)-Z-R4,-P(= O)(OCl-C6-烷基)2,芳基,杂环基,芳氧基,芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。