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1. 发明授权

KR860000517B1 1-치환-1-트리아졸릴스티렌류의 기하이성체의 제조방법 失效
公开(公告)号：KR860000517B1
公开(公告)日：1986-05-02
申请号：KR800001147
申请日：1980-03-19
申请人： SUMITOMO CHEMICAL CO
发明人： FUNAKI YUJI , TANAKA SHIZUYA , HIROFUMI OSHITA , KATO TOSHIRO
IPC分类号： C07D249/08 , A01N43/64 , A01N43/653 , A61K31/41 , A61P17/00 , A61P31/04 , C07D521/00

2. 发明授权

US3899582A Aromatic imidocarbonate composition and method of use for combatting fungi 失效
标题翻译：芳香酰亚胺碳酸酯组合物和用于对抗真菌的方法
公开(公告)号：US3899582A
公开(公告)日：1975-08-12
申请号：US43842574
申请日：1974-01-31
申请人： SUMITOMO CHEMICAL CO
发明人： TANAKA SHIZUYA , OZAKI TOSHIAKI , MINE AKIHIKO , TANAKA KATSUTOSHI , YAMAMOTO SIGEO , OOISHI TADASHI , HINO NAGANORI , SATOMI TAKEO
IPC分类号： C07D213/74 , A01N9/22
CPC分类号： C07D213/74
摘要： Novel imidocarbonate derivatives having the formula:

wherein Y and Z, which may be the same or different, are individually an oxygen or sulfur atom; Ar is an unsubstituted or a halogen- or lower C1 - C4 alkyl (straight or branched)substituted benzene or pyridine nucleus, the number of the substituents being 1 to 3; R2 is a C1 - C18 alkyl (straight or branched), a C1 - C18 alkyl(straight or branched) having 1 to 3 hydroxy radicals or 1 to 3 alkoxycarbonyl (the alkoxy has 1 to 4 carbon atoms) radicals in the carbon chain, a C3 - C10 cycloalkyl, a C2 - C5 alkenyl (straight or branched), a C3 - C6 alkynyl (straight or branched), a phenylalkyl, the benzene nucleus of which may be unsubstituted or substituted by 1 to 4 halogen atoms, 1 to 4 lower C1 - C4 alkyl (straight or branched) radicals or a nitro radical, or a halogen- or lower C1 - C4 alkyl (straight or branched)-substituted phenoxyalkyl; R3 is a C1 - C18 alkyl (straight or branched) having 1 to 3 hydroxy radicals or 1 to 3 alkoxycarbonyl (the alkoxy has 1 to 4 carbon atoms) radicals in the carbon chain, a C2 - C5 alkenyl (straight or branched), a C3 - C6 alkynyl (straight or branched) or a phenylalkyl, the benzene nucleus of which may be unsubstituted or substituted by 1 to 4 halogen atoms, 1 to 4 lower C1 - C4 alkyl (straight or branched) radicals, a nitro radical or a C2 - C4 alkylene radical, provided that in case Ar is an unsubstituted or substituted benzene nucleus and R2 and R3 are phenylalkyl groups, the benzene nucleus of at least one of said phenylalkyl groups has a substituent, have strong microbicidal activities on a wide scope of microorganisms.
摘要翻译：具有下式的新型亚氨基碳酸酯衍生物：Y-R2 Ar-N = C ANGLE Z-R3其中Y和Z可以相同或不同，分别为氧或硫原子; Ar是未取代的或卤素 - 或低级C 1 -C 4烷基（直链或支链）取代的苯或吡啶核，取代基数为1至3; R2是碳链中具有1至3个羟基或1至3个烷氧基羰基（烷氧基具有1至4个碳原子）的C1-C18烷基（直链或支链），C1-C18烷基（直链或支链） C3-C10环烷基，C2-C5烯基（直链或支链），C3-C6炔基（直链或支链），苯基烷基，其苯核可以是未取代的或被1-4个卤素原子取代，1〜 4个低级C1-C4烷基（直链或支链）基或硝基，或卤素 - 或低级C1-C4烷基（直链或支链）取代的苯氧基烷基; R3是碳链中具有1至3个羟基或1至3个烷氧基羰基（烷氧基具有1至4个碳原子）基团的C1-C18烷基（直链或支链），C2-C5链烯基（直链或支链） C 3 -C 6炔基（直链或支链）或苯基烷基，其苯核可以是未取代的或被1至4个卤素原子取代，1至4个低级C 1 -C 4烷基（直链或支链）基团，硝基或如果Ar是未取代或取代的苯核，且R 2和R 3为苯基烷基，则所述苯基烷基中的至少一个的苯核具有取代基，在宽范围内具有强的杀微生物活性的微生物。

3. 发明授权

US3567744A Process for producing furoic acid derivatives 失效
标题翻译：生产丙酸衍生物的方法
公开(公告)号：US3567744A
公开(公告)日：1971-03-02
申请号：US3567744D
申请日：1968-07-15
申请人： SUMITOMO CHEMICAL CO
发明人： TANAKA SHIZUYA , YOSHIOKA HIROSUKE , HIGO AKIO , MAGARA OSAMU
IPC分类号： C07D307/68 , C07D317/30 , C07D5/18 , C07D5/20
CPC分类号： C07D307/68 , C07D317/30
摘要： A NOVEL PROCESS FOR PRODUCING 5-SUBSTITUTED 3-FUROIC ACID DERIVATIVES USEFUL AS INTERMEDIATES IN A SYNTHESIS OF INSECTICIDES. FOR EXAMPLE 5-BENZYL-3-FUROIC ACID IS PRODUCED BY REACTING ETHYLENE KETAL OF ETHYL LEVULINATE WITH ETHYL FORMATE IN THE PRESENCE OF SODIUM HYDRIDE TO YIELD ETHYLENE KETAL OF ETHYL A-FORMYL-LEVULINATE, RING-CLOSING THE RESULTANT ETHYLENE KETAL OF ETHYL A-FORMYL-LEVULINATE BY CONTACTING IT WITH HYDROCHLORIC ACID TO YIELD ETHYL 5-METHYL-3FUROATE, BROMINATING THE RESULTANT ETHYL 5-METHYL-3FUROATE TO YIELD ETHYL 2-BROMO-5-BROMOMETHYL-3-FUROATE, REACTING THE RESULTANT ETHYL 2 - BROMO-5-BROMO-METHYL-3FUROATE WITH BENZENE IN THE PRESENCE OF ALUMINUM CHLORIDE TO YIELD ETHYL 2-BROMO-5-BENZYL-3-FUROATE AND, AFTER HYDROLYZING THE ESTER TO AN ACID, REACTING THE RESULTANT 2BROMO - 5 - BENZYL - 3-FUROIC ACID WITH ZINC POWDER IN AN AQUEOUS AMMONIA SOLUTION TO YIELD 5-BENZYL-3-FUROIC ACID.

4. 发明专利

DK157811B 未知
公开(公告)号：DK157811B
公开(公告)日：1990-02-19
申请号：DK118580
申请日：1980-03-19
申请人： SUMITOMO CHEMICAL CO
发明人： FUNAKI YUJI , OSHITA HIROFUMI , YAMAMOTO SHIGEO , TANAKA SHIZUYA , KATO TOSHIRO
IPC分类号： A01N43/653 , C07D249/08 , C07D521/00

5. 发明专利

RO84686B PROCEDEU PENTRU PREPARAREA IZOMERILOR GEOMETRICI- IA DE 1-TRIAZOLILSTIRENI 1-SUBSTITUITI 未知
公开(公告)号：RO84686B
公开(公告)日：1984-09-30
申请号：RO10053080
申请日：1980-03-19
申请人： SUMITOMO CHEMICAL CO
发明人： FUNAKI YUJI , OSHITA HIROFUMI , YAMAMOTO SHIGEO , TANAKA SHIZUYA , KATO TOSHIRO
IPC分类号： C07D249/08 , A01N43/64 , A01N43/653 , A61K31/41 , A61P17/00 , A61P31/04 , C07D521/00

6. 发明专利

CA1154449A GEOMETRICAL ISOMER OF 1-SUBSTITUTED-1- TRIAZOLYLSTYRENES, AND THEIR PRODUCTION AND USE AS FUNGICIDE, HERBICIDE AND/OR PLANT GROWTH REGULANT 未知
公开(公告)号：CA1154449A
公开(公告)日：1983-09-27
申请号：CA347897
申请日：1980-03-18
申请人： SUMITOMO CHEMICAL CO
发明人： FUNAKI YUJI , OSHITA HIROFUMI , YAMAMOTO SHIGEO , TANAKA SHIZUYA , KATO TOSHIRO
IPC分类号： A01N43/653 , C07D249/08 , C07D521/00
摘要： The present invention relates to one of the two geometrical isomers (a compound defined as I-A isomer in the description below) of a triazole compound represented by the formula (I) or (II), (I) (II) wherein R1 is a hydrogen atom, a C1-C4 alkyl, C3-C4 alkenyl or 2-propynyl group, R2 is a C1-C6 alkyl, cyclopropyl or 1-methylcyclopropyl group, R3, which may be the same or different, is a halogen atom, a C1-C4 alkyl, halogen-substituted C1-C3 alkyl, C1-C4 alkoxy, phenoxy, phenyl, cyano or nitro group, n is an integer of 0 to 3, and the term, halogen, means chlorine bromine and fluorine atoms, its salts, production thereof and a fungicide, herbicide and/or plant growth regulator for agriculture and horticulture containing said compound as an active ingredient.

7. 发明专利

FR2457859A1 未知
公开(公告)号：FR2457859A1
公开(公告)日：1980-12-26
申请号：FR8015966
申请日：1980-07-18
申请人： SUMITOMO CHEMICAL CO
发明人： FUNAKI YUKI , OSHITA HIROFUMI , YAMAMOTO SHIGEO , TANAKA SHIZUYA , KATO TOSHIRO
IPC分类号： A01N43/64 , A01N43/653 , C07D249/08 , C07D521/00

8. 发明专利

CA975372A IMIDOCARBONATES 未知
公开(公告)号：CA975372A
公开(公告)日：1975-09-30
申请号：CA110725
申请日：1971-04-19
申请人： SUMITOMO CHEMICAL CO
发明人： TANAKA SHIZUYA , OZAKI TOSHIAKI , MINE AKIHIKO , YAMAMOTO SIGEO , HINO NAGANORI , TANAKA KATSUTOSHI , OOISHI TADASHI , SATOMI TAKEO
IPC分类号： A01N37/18 , A01P3/00 , C07C257/06 , C07C323/27 , C07C329/00 , C07D213/74

9. 发明专利

CA967960A ISOTHIOUREA COMPOUNDS AND THEIR PRODUCTION AND USE 未知
公开(公告)号：CA967960A
公开(公告)日：1975-05-20
申请号：CA140
申请人： SUMITOMO CHEMICAL CO
发明人： TANAKA SHIZUYA , YAMAMOTO SIGEO , TANAKA KATSUTOSHI , TAKEDA HISAMI
IPC分类号： C07D213/74
摘要： 1346958 1-Pyridyl-2-benzyl-isothioureas SUMITOMO CHEMICAL CO Ltd 12 April 1972 [30 April 1971] 16934/72 Heading C2C [Also in Division A5] Novel compounds of Formula (I) wherein M is a group of the formula -NR 1 R 2 in which R 1 is a hydrogen atom, a C 1-20 alkyl, cyano (C 1-5 )alkyl, C 1-5 alkenyl, C 1-5 alkynyl, or phenyl (C 1-5 ) alkyl group wherein the benzene ring is optionally substituted by one or more identical or different C 1-5 alkyl groups, one or more nitro groups and/or one or more identical or different halogen atoms, and in which R 2 is a C 1-20 alkyl, cyano (C 1-5 ) alkyl, C 1-5 alkenyl, C 1-5 alkynyl or phenyl (C 1-5 ) alkyl group wherein the benzene ring is optionally substituted by one or more identical or different C 1-5 alkyl groups, one or more nitro groups and/or one or more identical or different halogen atoms; or wherein M is a 3-6 membered heterocyclic group containing nitrogen as a heteroatom and optionally one or more further heteroatoms, the aforesaid heterocyclic group being bonded to the remainder of the isothiourea molecule by the said nitrogen heteroatom thereof; wherein X is a hydrogen atom, a halogen atom or a C 1-5 alkyl group; and wherein Y 1 , Y 2 and Y 3 are, each independently, a hydrogen atom, a nitro group, a halogen atom or a C 1-5 alkyl group, are prepared by reacting a thiourea of Formula (III) with a benzyl halide of Formula (IV) wherein Z is a halogen atom The preparation is preferably carried out in an inert solvent (e.g. MeOH, EtOH, THF, dioxane, DMSO or DMF) in the presence of a basic substance (e.g. NaOH, KOH, NaOMe, KOMe, NaOEt, Ca(OH) 2 ) generally using a molar ratio of base to benzyl halide to thiourea of 1-1À5: 1-2 : 1 respectively. The examples describe the preparation of many 1-(3 1 -pyridyl)-isothioureas which are effective against phyto-pathogenic bacteria or fungi or acarids.

10. 发明专利

DE2166237A1 未知
公开(公告)号：DE2166237A1
公开(公告)日：1973-07-26
申请号：DE2166237
申请日：1971-07-30
申请人： SUMITOMO CHEMICAL CO
发明人： OHNO NOBUO , ITAYA NOBUSHIGE , MIZUTANI TOSHIO , OKUNO YOSITOSI , FUJIMOTO KEIMEI , KAWANAMI TORU , TANAKA SHIZUYA
IPC分类号： C07D333/16 , A01N53/04 , C07D307/42 , C07D307/45 , C07D307/56 , C07D5/16
摘要： A cyclopropanecarboxylate represented by the formula, WHEREIN R1 is hydrogen atom, methyl or ethyl group, R2 is methyl, ethyl, 2-methyl-1-propenyl or 2-methoxycarbonyl-1-propenyl group when R1 is hydrogen atom, or R2 is methyl or ethyl group when R1 is methyl or ethyl group, and R3 and R4 are respectively hydrogen atom, methyl or ethyl group, provided that the case where R1, R3 and R4 are simultaneously hydrogen atom is excluded, R5 is a lower alkynyl or a lower alkenyl group, R6 is a lower alkynyl, a lower alkenyl or a lower alkoxyalkyl group, R7 is hydrogen atom, a lower alkyl or a lower alkoxy group or a halogen atom, n is 1 or 2, and X is oxygen or sulfur atom, which is useful as an active ingredient of insecticides.

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