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1. 发明专利

CA1225399A CARBAMOYLTRIAZOLES, AND THEIR PRODUCTION AND USE 未知
公开(公告)号：CA1225399A
公开(公告)日：1987-08-11
申请号：CA464522
申请日：1984-10-02
申请人： SUMITOMO CHEMICAL CO
发明人： NAKAYAMA KOJI , YOSHIDA RYO , MORITA KOUICHI
IPC分类号： A01N47/38 , C07D249/12 , C07D405/12
摘要： : The invention provides novel compounds of the formula: wherein R1 and R2 are each a lower alkyl group or together they may represent a lower alkylene group so as to form a nitrogen-containing cyclic group with the nitrogen atom to which they are attached, R3 is a cycloalkyl(lower)alkyl group, an oxacycloalkyl(lower)alkyl group or a dioxacycloalkyl(lower)alkyl group and n is an integer of 0 to 2. These compounds are useful as herbicides.

2. 发明专利

DE3476542D1 CARBAMOYLTRIAZOLES, AND THEIR PRODUCTION AND USE 未知
公开(公告)号：DE3476542D1
公开(公告)日：1989-03-09
申请号：DE3476542
申请日：1984-10-02
申请人： SUMITOMO CHEMICAL CO
发明人： NAKAYAMA KOJI , YOSHIDA RYO , MORITA KOUICHI
IPC分类号： A01N47/38 , C07D249/12 , C07D405/12
摘要： A compound of the formula:wherein R, and R 2 are each a lower alkyl group or they may together represent a lower alkylene group so as to form a nitrogen-containing cyclic group with the nitrogen atom to which they attach, R 3 is a cycloalkyl(lower)alkyl group, an oxacycloalkyl(lower)alkyl group or a dioxacycloalkyl(lower)-alkyl group and n is an integer of 0 to 2, which is useful as a herbicide.

3. 发明专利

JP2007054022A Method for predicting carcinogenicity of test substance 有权
标题翻译：预测测试物质致癌性的方法
公开(公告)号：JP2007054022A
公开(公告)日：2007-03-08
申请号：JP2005246583
申请日：2005-08-26
申请人： Chemicals Evaluation & Research Institute , Mitsubishi Chemical Safety Institute Ltd , Sumitomo Chemical Co Ltd , 住友化学株式会社 , 株式会社三菱化学安全科学研究所 , 財団法人化学物質評価研究機構
发明人： MATSUMOTO HIROSHI , YAKABE YOSHIKUNI , SUDO YOSHIHISA , SAITO KOICHI , SUMITA YOSHIYO , NAKAYAMA KOJI , SEKIJIMA MASARU , SHIRAI TOMOYUKI
IPC分类号： C12Q1/68 , C12M1/00 , C12N15/09 , G01N21/78
CPC分类号： C12Q1/6886 , C12Q2600/158
摘要： PROBLEM TO BE SOLVED: To provide a method for easily predicting the carcinogenicity of a test substance in a short period.
SOLUTION: The method comprises the first step of administering multiple carcinogens to respective carcinogen administration groups and sampling mRNA from the above groups after the lapse of a predetermined period to select expression-varied gene where mRNA expression level is increased or decreased, the second step of comparing the expression patterns of the expression-varied gene among the respective carcinogen administration groups, classifying the expression patterns into multiple groups based on the similarity of the expression patterns and preparing the expression pattern of the expression-varied gene for each group, and the third step of administering a test substance to test substance administration groups, obtaining expression patterns for the expression-varied gene by sampling mRNA from the test substance administration groups after the lapse of a predetermined period, comparing the expression patterns with previously prepared those of the expression-varied gene for each carcinogen administration group to calculate the consistency.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种在短期内容易地预测被测物质的致癌性的方法。解决方案：该方法包括在经过预定时间后，对各致癌物质给药组施用多种致癌物质并从上述组中取样mRNA的第一步骤，以选择mRNA表达水平升高或降低的表达变异基因，比较各致癌物质组之间表达变异基因的表达模式的第二步，根据表达模式的相似性，将表达模式分类为多组，制备各组表达变异基因的表达模式，以及将测试物质施用于测试物质给药组的第三步骤，通过在经过预定时间后从测试物质给药组中取样mRNA获得表达变异基因的表达模式，将表达模式与预先制备的每个ca的表达变异基因激素给药组计算一致性。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2556100B2 失效
公开(公告)号：JP2556100B2
公开(公告)日：1996-11-20
申请号：JP17314688
申请日：1988-07-11
申请人： SUMITOMO CHEMICAL CO
发明人： OOSUMI TADASHI , TSUSHIMA KAZUHIRO , NISHIDA SUMIO , NAKAYAMA KOJI , MACHIDA KYOTO , OOISHI TADASHI
IPC分类号： C07D213/803

5. 发明专利

JPH0434993B2 失效
公开(公告)号：JPH0434993B2
公开(公告)日：1992-06-09
申请号：JP20435884
申请日：1984-09-28
申请人： SUMITOMO CHEMICAL CO
发明人： NAKAYAMA KOJI , YOSHIDA AKIRA , MORITA KOICHI
IPC分类号： C07D249/12 , A01N47/38 , C07D249/00 , C07D317/00 , C07D319/00 , C07D405/12

6. 发明专利

JPH01213264A PRODUCTION OF SUBSTITUTED NICOTINIC ACID ESTER 失效
公开(公告)号：JPH01213264A
公开(公告)日：1989-08-28
申请号：JP4030888
申请日：1988-02-22
申请人： SUMITOMO CHEMICAL CO
发明人： OSUMI TADASHI , TSUSHIMA KAZUHIRO , NISHIDA SUMIO , NAKAYAMA KOJI , MAEDA KIYOTO , OISHI TADASHI
IPC分类号： C07D213/80
摘要： PURPOSE:To obtain the subject substance which is used as an intermediate of substituted nicotinic acid derivative having microbicidal activity, by allowing 2,3-dibromopropionaldehyde to react with 3-aminoacrylic acid ester derivative in the presence of an acid acceptor in a solvent. CONSTITUTION:The reaction between a compound of formula I and another compound of formula II (R1, R2 are lower alkyl) is carried out in the presence of an acid acceptor, preferably a tertiary amine, in a solvent such as aliphatic hydrocarbon which may be halogenated at 80-120 deg.C to give the compound of formula III. The amounts of the compound of formula II and the acid acceptor are 1mol. and more than 2mol. per mol. of the compound of formula I. The process according to the presence invention is inexpensive and excellent in operability.

7. 发明专利

JP2007252277A Method for predicting carcinogenicity of tested material 有权
标题翻译：预测材料致癌性的方法
公开(公告)号：JP2007252277A
公开(公告)日：2007-10-04
申请号：JP2006081537
申请日：2006-03-23
申请人： Chemicals Evaluation & Research Institute , Mitsubishi Chemical Safety Institute Ltd , Sumitomo Chemical Co Ltd , 住友化学株式会社 , 株式会社三菱化学安全科学研究所 , 財団法人化学物質評価研究機構
发明人： MATSUMOTO HIROSHI , YAKABE YOSHIKUNI , SAITO KOICHI , SUMITA YOSHIYO , NAKAYAMA KOJI , SEKIJIMA MASARU , SHIRAI TOMOYUKI
IPC分类号： C12Q1/68 , C12N15/09 , G01N21/78
摘要： PROBLEM TO BE SOLVED: To provide a method for predicting the carcinogenicity of a tested material. SOLUTION: The method for predicting the carcinogenicity of the tested material includes the following first to third steps at the prediction of the carcinogenicity of the tested material, after previously preparing expression patterns by administering a carcinogen (C+M+) positive to the Ames test and a carcinogen (C+M-) negative to the Ames test to test animals, and collecting mRNAs from the test animals after a prescribed time passes: the first step for subjecting the test material to the Ames test and determining whether the test material belongs to the positive or negative in the Ames test; the second step for obtaining the expression pattern by collecting the mRNA from a test animal to which the tested material is administered; and the third step for predicting the carcinogenicity of the tested material by calculating the identity frequency with the expression pattern of the mRNA of the carcinogen positive to the Ames test when the tested material is positive to the Ames test at the first step, and with the expression pattern of the mRNA of the carcinogen negative to the Ames test when the tested material is negative to the Ames test at the first step. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种预测被测材料的致癌性的方法。
解决方案：预测测试材料的致癌性的方法包括以下第一至第三步骤，在预测测试材料的致癌性之前，先前通过将致癌物（C + M +）施用于 Ames测试和对Ames测试阴性的致癌物（C + M-）进行测试，并在规定的时间过后从测试动物收集mRNA：第一步，将测试材料进行Ames测试，并确定测试材料属于Ames测试中的正或负值; 通过从施用被测试材料的测试动物中收集mRNA获得表达模式的第二步骤; 以及第三步，通过在第一步对Ames测试测试材料为阳性时，通过计算与Ames测试阳性的致癌物质mRNA表达模式的身份频率来预测测试材料的致癌性，并与当测试材料在第一步对Ames测试为阴性时，对Ames测试阴性的致癌物的mRNA的表达模式。版权所有（C）2008，JPO＆INPIT

8. 发明专利

JPH01316361A PRODUCTION OF SUBSTITUTED NICOTINIC ESTER 失效
公开(公告)号：JPH01316361A
公开(公告)日：1989-12-21
申请号：JP17314688
申请日：1988-07-11
申请人： SUMITOMO CHEMICAL CO
发明人： OSUMI TADASHI , TSUSHIMA KAZUHIRO , NISHIDA SUMIO , NAKAYAMA KOJI , MACHIDA KIYOTO , OISHI TADASHI
IPC分类号： C07D213/803
摘要： PURPOSE:To obtain the subject compound useful for intermediate of substituted nicotinic acid derivative having disinfection activity with simple operation in low cost and high yield by reacting malonaldehyde derivative and 3- aminoacrylate derivative in the presence of salt. CONSTITUTION:1mol malonaldehyde derivative expressed by formula I [A is O or (OR1)2 (R1 is lower alkyl); R2, R3 is H or R1] is reacted with 3- aminoacrylate derivative expressed by formula II (R4, R5 is R1) of equal molar amount to said compound in the presence of 0.01-0.2mol salt, usually at room temperature-260 deg.C, preferably 150-220 deg.C with distilling off by-produced alcohol to outside of reaction system to afford the aimed compound expressed by formula III. Salt of phosphoric acid and substituted pyridine derived from 2- ethylpyridine, 2-methylpyridine, 2,4-lutidine or 2,4,6-collidine, etc., is preferably used as said salt.

9. 发明专利

JPH01117864A SUBSTITUTED NICOTINIC ACID DERIVATIVE, ITS PRODUCTION AND AGRICULTURAL AND HORTICULTURAL FUNGICIDE CONTAINING SAID DERIVATIVE AS ACTIVE COMPONENT 失效
公开(公告)号：JPH01117864A
公开(公告)日：1989-05-10
申请号：JP22767487
申请日：1987-09-10
申请人： SUMITOMO CHEMICAL CO
发明人： OSUMI TADASHI , TSUSHIMA KAZUHIRO , NISHIDA SUMIO , NAKAYAMA KOJI , MAEDA KIYOTO , OISHI TADASHI
IPC分类号： C07D213/81 , A01N43/40
摘要： NEW MATERIAL:The substituted nicotinic acid derivative of formula I (R is CH3, C2H5, halogen, CF3, NO2, OCH3 or SCH3; R and R are H or CH3; X is O or S). EXAMPLE:N-(1,1,3-trimethyl-4-indanyl)-2-(trifluoromethyl)nicotinic acid amide. USE:A fungicide for agricultural and horticultural use. PREPARATION:The compound of formula IV which is one of the compound of formula I can be produced by reacting a compound of formula II or its reactive derivative with a compound of formula II. As necessary, the obtained compound is converted into another compound of formula I (i.e., the compound of formula V) by reacting with a thionation reagent such as phosphorus pentasulfide, 2,4-bis(methylthio)-1,3,2,4-dithiadiphosphetane-2,4-disulfide or 2,4-bis (p-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4.-d isulfide.

10. 发明专利

JPS63208564A ORGANIC SULFUR COMPOUND, ITS PRODUCTION AND HERBICIDE CONTAINING SAID COMPOUND AS ACTIVE 失效
公开(公告)号：JPS63208564A
公开(公告)日：1988-08-30
申请号：JP4374287
申请日：1987-02-25
申请人： SUMITOMO CHEMICAL CO
发明人： KIRINO OSAMU , HIRATSUKA MITSUNORI , NAKAYAMA KOJI , YOSHIDA AKIRA , HAMADA TATSUHIRO
IPC分类号： A01N41/10 , C07C67/00 , C07C313/00 , C07C315/02 , C07C317/24 , C07C317/44
摘要： NEW MATERIAL:The compound of formula I (R is oxoalkyl, oxocycloalkyl, alkoxycarbonyl, benzoyl-lower alkyl or cyano-lower alkyl; X is H or Cl; n is 1 or 2). EXAMPLE:2-(3-Oxo)butyl 2,6-dichlorobenzyl sulfoxide. USE:A herbicide having excellent herbicidal effect and exhibiting excellent selectivity between crops and weeds. It is useful especially against broad-leaved weeds in plowed field, e.g. wild buckwheat, common purslane, Indian mallow, etc., and is free from phytotoxicity to crops such as corn, wheat, cotton, beet, etc. PREPARATION:The compound of formula I can be produced by oxidizing a benzyl sulfide compound of formula II with a oxidizing agent (e.g. m- chloroperbenzoic acid) in a solvent (e.g. chloroform) at 0-150 deg.C for 0.5-16hr.

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