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    • 7. 发明申请
    • MOLDING WITH HARD-COATING LAYER AND PROCESS FOR PRODUCING THE SAME
    • 用硬涂层成型及其生产方法
    • WO1994014878A1
    • 1994-07-07
    • PCT/JP1993001870
    • 1993-12-24
    • NIPPON ZEON CO., LTD.KONISHI, YuichiroHOSAKA, TohruTADA, MitsushiNATSUUME, TadaoTAKAHASHI, NobukazuKOHARA, Teiji
    • NIPPON ZEON CO., LTD.
    • C08J07/04
    • C08J7/04C08J2365/00Y10T428/31667Y10T428/31924Y10T428/31935
    • A molding with a hard-coating layer having an adhesion of at least 50 squares per 100 squares in the cross cut adhesion test, an adhesion of at least 40 squares per 100 squares even after being held in water at 70 DEG C for 1 hour, a haze value of 1.0 % or less in Taber's abrasion resistance test and a pencil hardness of 2H or above. The production process comprises either modifying the surface of a base material comprising a thermoplastic norbornene resin by, for example, corona discharge to give a surface tension of at least 50 dyn/cm or forming on the surface a primary primer layer comprising a copolymer composed of a vinylaromatic compound and a conjugated diene and modified by introducing a polar group thereinto, then forming a primer layer for a silicone-base hard-coating agent on the modified surface or the formed primary primer layer, and finally forming thereon a silicone-base hard-coating layer.
    • 在十字切割粘合试验中,每100平方厘米具有至少50个正方形的粘合性的硬涂层的成型体,即使在70℃下保持1小时后,每100平方厘米至少40个正方形的粘合力, 泰伯耐磨性试验的浊度值为1.0%以下,铅笔硬度为2H以上。 生产方法包括通过例如电晕放电改变包含热塑性降冰片烯树脂的基材的表面,以产生至少50dyn / cm 2的表面张力,或在表面上形成包含 由乙烯基芳族化合物和共轭二烯构成的共聚物,并通过在其中引入极性基团进行改性,然后在改性表面或形成的初级底漆层上形成硅氧烷基硬涂​​层的底漆层,最后在其上形成硅氧烷 基硬涂层。