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    • 1. 发明申请
    • POLYARYLETHERSULFONE OIL AND GAS RECOVERY ARTICLES, METHOD OF PREPARATION AND METHOD OF USE
    • 聚烯烃油和气体回收制品,制备方法和使用方法
    • WO2015010977A1
    • 2015-01-29
    • PCT/EP2014/065206
    • 2014-07-16
    • SOLVAY SPECIALTY POLYMERS USA, LLCSOLVAY SA
    • THOMAS, David B.LOUIS, ChantalEL-HIBRI, Mohammad Jamal
    • C08G75/23E21B33/12E21B34/00E21B43/00E21B1/00
    • E21B41/00E21B17/00
    • An oil and gas recovery article comprising at least one part made of a poly(arylether sulfone) polymeric material comprising at least one poly(arylether sulfone) polymer, wherein said (t-PAES) polymer comprising more than 50 % moles of recurring units (R t ) of formula (S t ): -E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ] m -Ar 4 wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group and E is of formula (E t ), wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4.
    • 一种油和气回收制品,其包含由包含至少一种聚(芳基醚砜)聚合物的聚(芳基醚砜)聚合物材料制成的至少一部分,其中所述(t-PAES)聚合物包含超过50%摩尔的重复单元 式(St)的Rt):-E-Ar 1 -SO 2 - [Ar 2 - (T-Ar 3)n -SO 2] m -Ar 4其中n和m彼此相同或不同,独立地为0或整数 1〜5中,Ar 1,Ar 2,Ar 3,Ar 4各自相同或不同,在每个出现时均为芳香部分,T为键或二价基团,E为式(Et) R'彼此相同或不同,选自卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐 碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵盐; j'为零或为1〜4的整数。
    • 5. 发明申请
    • CHEMICAL PROCESSING ARTICLES
    • 化学加工品
    • WO2015011004A2
    • 2015-01-29
    • PCT/EP2014/065307
    • 2014-07-16
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • THOMAS, David B.LOUIS, ChantalEL-HIBRI, Mohammad Jamal
    • C08G75/23
    • C08G75/23B05D1/265B29C45/0001B29C47/0016B29K2081/06C08L81/06F04C27/004
    • A chemical processing article comprising at least one part made of a poly(arylether sulfone) polymeric material comprising at least one poly(arylether sulfone) polymer, wherein said (t-PAES) polymer comprising more than 50% moles of recurring units (R t ) of formula (S t ):-E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 )n-SO 2 ] m -Ar 4 wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group and E is of formula (E t ) wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4.
    • 一种化学处理制品,其包含由包含至少一种聚(芳基醚砜)聚合物的聚(芳基醚砜)聚合物材料制成的至少一部分,其中所述(t-PAES)聚合物包含超过50%摩尔的重复单元(Rt) 的式(St):-E-Ar 1 -SO 2 - [Ar 2 - (T-Ar 3)n -SO 2] m -Ar 4,​​其中n和m彼此相同或不同,独立地为0或1〜 如图5所示,Ar 1,Ar 2,Ar 3和Ar 4中的每一个彼此相同或不同,为芳香部分,T为键或二价基团,E为式(Et),其中R', 卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱或碱金属盐 碱土金属膦酸盐,烷基膦酸盐,胺和季铵; j'为零或为1〜4的整数。
    • 6. 发明申请
    • POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS
    • 聚亚甲基醚(PAES)组合物
    • WO2014180725A1
    • 2014-11-13
    • PCT/EP2014/058803
    • 2014-04-30
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • EL-HIBRI, Mohammad JamalLOUIS, ChantalTHOMAS, David B.PATEL, Hemantkumar
    • C08G75/23C08L81/06C08K3/40C08K7/14
    • C08L81/06C08K7/14
    • A composition [composition (C), herein after] comprising from 30 to 95% by weight of at least one poly(arylether sulfone) polymer, wherein said polymer comprising more than 50% moles of recurring units (R t ) of formula (S t ): -E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ] m -Ar 4 -(formula S t ) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom;and E is of formula (E t ): herein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, from to 50%wt. of at least one reinforcing filler, and wherein all% wt. are based on the total weight of the composition(C).
    • 包含30至95重量%的至少一种聚(芳基醚砜)聚合物的组合物[组合物(C)),其中所述聚合物包含大于50%摩尔的式(St)的重复单元(R t) :-E-Ar1-SO2- [Ar2-(T-Ar3)n-SO2] m-Ar4-(式St)其中n和m彼此相同或不同,分别为0或1〜 如图5所示,Ar1,Ar2,Ar3和Ar4中的每一个彼此等于或不同,并且在每次出现时均为芳族部分,T为任选包含一个或多于一个杂原子的键或二价基团; E为式 (Et):本文中R'彼此相同或不同的每一个选自卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺,酰亚胺,碱或 碱土金属磺酸盐,烷基磺酸盐,碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵; j'为零或为1至4的整数,至50重量%。 的至少一种增强填料,并且其中所有的%wt。 基于组合物(C)的总重量。
    • 9. 发明申请
    • Process for the manufacture of terphenyl compounds
    • 制造三联苯化合物的方法
    • WO2015158580A1
    • 2015-10-22
    • PCT/EP2015/057567
    • 2015-04-08
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • LOUIS, ChantalTHOMAS, David B.
    • C07C37/01C07C39/15C07C67/42C07C45/68
    • C07C37/0555C07C37/01C07C39/15C07C45/68C07C67/42C07C49/784C07C69/16C07C67/12
    • A process for the manufacture of a terphenyl compound [compound (T), herein after] of formula (T): wherein each of R and R', equal to or different from each other, are selected from the group consisting of halogen, alkyl, aryl, ether, thioether, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; - each of j' and k, equal to or different from each other, are zero or are an integer from 1 to 4, including the steps of (i) reacting at least one organozinc compound of formula (I) with at least one dihalocompound of formula (II) in the presence of a catalyst compound; wherein Y is selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion, R2 is selected from selected from the group consisting of C 1 -C 10 -alkyl, C 3 -C 10 -cycloalkyl, C 1 -C 10 -halooalkyl and C 3 -C 10 halocyclo alkyl, each of Z, equal to or different from each other, are selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion; (ii) a Bayer-Villiger oxidation and (iii) hydrolysis or alcoholysis.
    • 制备式(T)的本文后三联苯化合物[化合物(T))的方法:其中R和R'彼此相同或不同的各自选自卤素,烷基 芳基,醚,硫醚,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵盐; - 彼此相同或不同的j'和k中的每一个为零或为1至4的整数,包括以下步骤:(i)使至少一种式(I)的有机锌化合物与至少一种二卤化合物 式(II)的化合物在催化剂化合物的存在下反应; 其中Y选自氯化物,溴化物,碘化物,链烷磺酸盐或氟烷基磺酸根阴离子,R2选自C1-C10-烷基,C3-C10-环烷基,C1-C10 卤代烷基和C 3 -C 10卤代环烷基,Z各自相同或不同,选自氯,溴,碘,烷烃磺酸盐或氟代烷基磺酸根阴离子; (ii)拜耳维利格(Bayer-Villiger)氧化和(iii)水解或醇解。