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1. 发明申请

WO2014180725A1 POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS 审中-公开
标题翻译：聚亚甲基醚（PAES）组合物
公开(公告)号：WO2014180725A1
公开(公告)日：2014-11-13
申请号：PCT/EP2014/058803
申请日：2014-04-30
申请人： SOLVAY SPECIALTY POLYMERS USA, LLC
发明人： EL-HIBRI, Mohammad Jamal , LOUIS, Chantal , THOMAS, David B. , PATEL, Hemantkumar
IPC分类号： C08G75/23 , C08L81/06 , C08K3/40 , C08K7/14
CPC分类号： C08L81/06 , C08K7/14
摘要： A composition [composition (C), herein after] comprising from 30 to 95% by weight of at least one poly(arylether sulfone) polymer, wherein said polymer comprising more than 50% moles of recurring units (R t ) of formula (S t ): -E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ] m -Ar 4 -(formula S t ) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom;and E is of formula (E t ): herein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, from to 50%wt. of at least one reinforcing filler, and wherein all% wt. are based on the total weight of the composition(C).
摘要翻译：包含30至95重量％的至少一种聚（芳基醚砜）聚合物的组合物[组合物（C）），其中所述聚合物包含大于50％摩尔的式（St）的重复单元（R t）：-E-Ar1-SO2- [Ar2-（T-Ar3）n-SO2] m-Ar4-（式St）其中n和m彼此相同或不同，分别为0或1〜如图5所示，Ar1，Ar2，Ar3和Ar4中的每一个彼此等于或不同，并且在每次出现时均为芳族部分，T为任选包含一个或多于一个杂原子的键或二价基团; E为式（Et）：本文中R'彼此相同或不同的每一个选自卤素，烷基，烯基，炔基，芳基，醚，硫醚，羧酸，酯，酰胺，酰亚胺，碱或碱土金属磺酸盐，烷基磺酸盐，碱金属或碱土金属膦酸盐，烷基膦酸盐，胺和季铵; j'为零或为1至4的整数，至50重量％。的至少一种增强填料，并且其中所有的％wt。基于组合物（C）的总重量。

2. 发明申请

WO2014180726A1 POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS 审中-公开
标题翻译：聚亚甲基醚（PAES）组合物
公开(公告)号：WO2014180726A1
公开(公告)日：2014-11-13
申请号：PCT/EP2014/058805
申请日：2014-04-30
申请人： SOLVAY SPECIALTY POLYMERS USA, LLC
发明人： LOUIS, Chantal , EL-HIBRI, Mohammad Jamal , THOMAS, David B. , PATEL, Hemantkumar
IPC分类号： C08G75/23
CPC分类号： C08G75/23
摘要： A poly(arylether sulfone) polymeric material comprising polymer molecules wherein more than 50 % moles of the recurring units of said polymer molecules are recurring units (Rt), equal to or different from each other, complying with formula (S t ) : -E-Ar 1 -S0 2 -[Ar 2 -(T-Ar 3 ) n -S0 2 ] m -Ar 4 -(formula S t ) wherein : n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom - E is of formula (E t ) : wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4; and wherein the fraction of polymer molecules having a molecular weight of below 5 000 [% fraction M , hereinafter] with respect to all the polymer molecules in said polymeric material is of at most 10 % weight, and wherein said % fraction M is of at least [3.02-PDI] % when the polymeric material possesses a polydispersity index (PDI) of below 3.02.
摘要翻译：包含聚合物分子的聚（芳基醚砜）聚合物材料，其中超过50％摩尔的所述聚合物分子的重复单元是重复单元（Rt），其等于或不同，符合式（St）：-E- Ar1-SO2- [Ar2-（T-Ar3）n-SO2] m-Ar4-（式St）其中：n和m彼此相同或不同，分别为0或1〜5的整数 Ar 1，Ar 2，Ar 3和Ar 4彼此相同或不同，并且在每次出现时均为芳族部分，T为任选包含一个或多于一个杂原子的键或二价基团 - E为式（Et）：其中R'彼此相同或不同的每一个选自卤素，烷基，烯基，炔基，芳基，醚，硫醚，羧酸，酯，酰胺，酰亚胺，碱金属或碱土金属磺酸盐烷基磺酸盐，碱金属或碱土金属膦酸盐，烷基膦酸盐，胺和季铵; j'为0或1〜4的整数; 并且其中相对于所述聚合物材料中的所有聚合物分子，分子量低于5000 [％分数M <5000，以下]的聚合物分子的分数为至多10重量％，并且其中所述％当聚合物材料具有低于3.02的多分散指数（PDI）时，5000至少为[3.02-PDI]％。

3. 发明申请

WO2014180724A2 POLYARYLENE ETHER SULFONE (PAES) POLYMERS 审中-公开
标题翻译：聚亚烷基醚（PAES）聚合物
公开(公告)号：WO2014180724A2
公开(公告)日：2014-11-13
申请号：PCT/EP2014/058799
申请日：2014-04-30
申请人： SOLVAY SPECIALTY POLYMERS USA, LLC
发明人： LOUIS, Chantal , EL-HIBRI, Mohammad Jamal , THOMAS, David B. , PATEL, Hemantkumar
CPC分类号： C08G75/23 , B05D1/12 , B29C43/003 , B29C45/0001 , B29C47/0004 , B29C64/106 , B29K2081/06 , B33Y10/00 , B33Y70/00 , G01N30/02
摘要： A poly(arylether sulfone) polymer [(t-PAES) polymer, herein after], wherein more than 70 % moles of the recurring units are recurring units (R t ) of formula (St) : -E-Ar 1 -S0 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ]m-Ar 4 - (formula S t ) wherein : n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom; - E is of formula (E t ), wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, and said (t-PAES) polymer having a number average molecular weight (M n ) ranging from 41 000 to 90 000.
摘要翻译：聚（芳基醚砜）聚合物[（t-PAES）聚合物，此后]其中多于70％摩尔的重复单元是式（St）的重复单元（R t）：-E-Ar 1 -SO 2 - [Ar 2 - （T-Ar 3）n-SO 2] m -Ar 4 - （式St）其中：n和m彼此相同或不同，分别为0或1〜5的整数，Ar 1，Ar 2，Ar 3 和Ar 4彼此相同或不同，并且在每次出现时均为芳族部分，T为任选包含一个或多于一个杂原子的键或二价基团; - E为式（Et），其中R'彼此相同或不同，各自选自卤素，烷基，烯基，炔基，芳基，醚，硫醚，羧酸，酯，酰胺酰亚胺，碱金属或碱土金属磺酸盐，烷基磺酸盐，碱金属或碱土金属膦酸盐，烷基膦酸盐，胺和季铵盐; j'为0或1〜4的整数，所述（t-PAES）聚合物的数均分子量（Mn）为41000〜90000。

4. 发明授权

EP2994500B1 POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS 失效
标题翻译：聚芳醚砜（PAES）组合物
公开(公告)号：EP2994500B1
公开(公告)日：2017-01-04
申请号：EP14721821.8
申请日：2014-04-30
申请人： Solvay Specialty Polymers USA, LLC.
发明人： LOUIS, Chantal , EL-HIBRI, Mohammad Jamal , THOMAS, David B. , PATEL, Hemantkumar
IPC分类号： C08G75/23
CPC分类号： C08G75/23

5. 发明公开

EP2994500A1 POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS 失效
标题翻译：聚芳醚砜（PAES）组合物
公开(公告)号：EP2994500A1
公开(公告)日：2016-03-16
申请号：EP14721821.8
申请日：2014-04-30
申请人： Solvay Specialty Polymers USA, LLC.
发明人： LOUIS, Chantal , EL-HIBRI, Mohammad Jamal , THOMAS, David B. , PATEL, Hemantkumar
IPC分类号： C08G75/23
CPC分类号： C08G75/23
摘要： A poly(arylether sulfone) polymeric material comprising polymer molecules wherein more than 50 % moles of the recurring units of said polymer molecules are recurring units (Rt), equal to or different from each other, complying with formula (S
t ) : -E-Ar
1 -S0
2 -[Ar
2 -(T-Ar
3 )
n -S0
2 ]
m -Ar
4 -(formula S
t ) wherein : n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar
1 , Ar
2 , Ar
3 and Ar
4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom - E is of formula (E
t ) : wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4; and wherein the fraction of polymer molecules having a molecular weight of below 5 000 [% fraction M
, hereinafter] with respect to all the polymer molecules in said polymeric material is of at most 10 % weight, and wherein said % fraction M
is of at least [3.02-PDI] % when the polymeric material possesses a polydispersity index (PDI) of below 3.02.
摘要翻译：一种包含聚合物分子的聚（芳醚砜）聚合物材料，其中所述聚合物分子的重复单元的多于50％摩尔是彼此相同或不同的重复单元（Rt），符合式（S t）：-E -Ar 1 -SO 2 2- [Ar 2-（T-Ar 3）n -SO 2] m -Ar 4-（式S t）其中：n和m彼此相同或不同，独立地为0或 1至5的整数，Ar 1，Ar 2，Ar 3和Ar 4中的每一个彼此相同或彼此不同并且在每次出现时为芳族部分，T为键或任选地包含一个或多个（E t）：其中每个R'彼此相同或不同，选自卤素，烷基，烯基，炔基，芳基，醚，硫醚，羧酸，酯，酰胺，酰亚胺，碱金属或碱土金属磺酸盐，烷基磺酸盐，碱金属或碱土金属膦酸盐，烷基膦酸盐，胺和季铵; j'为零或是从1到4的整数; 并且其中相对于所述聚合物材料中的所有聚合物分子，分子量低于5000 [％组分M <5000，下文]的聚合物分子的分数为至多10重量％，并且其中所述组分M < 5000在聚合物材料具有低于3.02的多分散指数（PDI）时至少为[3.02-PDI]％。

6. 发明公开

EP2994499A1 POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS 无效
标题翻译：聚芳醚砜（PAES）的组合物
公开(公告)号：EP2994499A1
公开(公告)日：2016-03-16
申请号：EP14721820.0
申请日：2014-04-30
申请人： Solvay Specialty Polymers USA, LLC.
发明人： EL-HIBRI, Mohammad Jamal , LOUIS, Chantal , THOMAS, David B. , PATEL, Hemantkumar
IPC分类号： C08G75/23 , C08L81/06 , C08K3/40 , C08K7/14
CPC分类号： C08L81/06 , C08K7/14
摘要： A composition [composition (C), herein after] comprising from 30 to 95% by weight of at least one poly(arylether sulfone) polymer, wherein said polymer comprising more than 50% moles of recurring units (R
t ) of formula (S
t ): -E-Ar
1 -SO
2 -[Ar
2 -(T-Ar
3 )
n -SO
2 ]
m -Ar
4 -(formula S
t ) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar
1 , Ar
2 , Ar
3 and Ar
4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom;and E is of formula (E
t ): herein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, from to 50%wt. of at least one reinforcing filler, and wherein all% wt. are based on the total weight of the composition(C).

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