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1. 发明申请

WO2012175534A1 (PER)FLUOROPOLYETHER BLOCK COPOLYMERS 审中-公开
标题翻译：（PER）氟聚醚嵌段共聚物
公开(公告)号：WO2012175534A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/061782
申请日：2012-06-20
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , TONELLI, Claudio Adolfo Pietro , FONTANA, Simonetta, Antonella , GALIMBERTI, Marco , GAVEZOTTI, Piero
发明人： TONELLI, Claudio Adolfo Pietro , FONTANA, Simonetta, Antonella , GALIMBERTI, Marco , GAVEZOTTI, Piero
IPC分类号： C08G65/08 , C08G65/18
CPC分类号： C07C271/24 , C07C41/22 , C07C43/126 , C07C55/32 , C07C67/00 , C07C69/708 , C07C269/02 , C08G65/007
摘要： The invention relates to (per)fluoropolyether block copolymers comprising: A) a fluoropolyoxyalkylene segment (chain R a ) comprising one or more units of formula (CHXCF 2 CF 2 O)- in which X is hydrogen or fluorine; B) a (per)fluoropolyoxyalkylene segment (chain Rf), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, said (per)fluoropolyoxyalkylene segment being different from chain R a and having a molecular weight higher than 400 g/mol. These copolymers are endowed with improves lubricant properties or with improved water and oil-repellence properties.
摘要翻译：本发明涉及（全）含氟聚醚嵌段共聚物，其包含：A）包含一种或多种式（CHXCF 2 CF 2 O）单元的氟聚氧亚烷基链（链Ra），其中X是氢或氟; B）（全）氟聚氧亚烷基链段（链Rf），也就是说包含具有至少一个链状醚键的重复单元和至少一个碳氟化合物部分的链段，所述（全）氟聚氧亚烷基链段不同于链Ra，并具有分子量高于400g / mol。这些共聚物具有改善的润滑剂性能或具有改善的防水和防油性能。

2. 发明申请

WO2012168156A1 HYDROXY COMPOUNDS OBTAINED FROM 2,2,3,3-TETRAFLUOROOXETHANE AND DERIVATIVES THEREOF 审中-公开
标题翻译：由2,2,3,3-四氢呋喃和其衍生物获得的羟基化合物
公开(公告)号：WO2012168156A1
公开(公告)日：2012-12-13
申请号：PCT/EP2012/060379
申请日：2012-06-01
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , FONTANA, Simonetta, Antonella , TONELLI, Claudio Adolfo Pietro , GAVEZOTTI, Piero
发明人： FONTANA, Simonetta, Antonella , TONELLI, Claudio Adolfo Pietro , GAVEZOTTI, Piero
IPC分类号： C07F9/06
CPC分类号： C07C43/137 , C07C41/02 , C07C41/26 , C07C51/58 , C07F9/091 , C07F9/65814 , C09D7/63 , D06P5/00 , C07C59/135
摘要： The invention relates to a hydroxy compound of formula (I) wherein n is an integer equal to or higher than 1 as an intermediate for the preparation of compounds of formulae (lla) and (IIb) as defined in the specification that can be used as water and oil resistance agents. The invention further relates to water and oil resistance compositions containing compounds (lla) and (IIb).
摘要翻译：本发明涉及式（I）的羟基化合物，其中n是等于或高于1的整数，作为制备如说明书中定义的式（Ⅰa）和（Ⅱb）化合物的中间体，其可以用作耐水和耐油剂。本发明还涉及含有化合物（Ia）和（IIb）的耐水和耐油组合物。

3. 发明申请

WO2013017470A9 COMPOSITIONS OF IONISABLE FLUOROPOLYMERS 审中-公开
公开(公告)号：WO2013017470A9
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064462
申请日：2012-07-24
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , TONELLI, Claudio Adolfo Pietro , BARBIERI, Solange
发明人： TONELLI, Claudio Adolfo Pietro , BARBIERI, Solange
IPC分类号： C08G18/08 , C08G18/50 , C08G65/00 , C08L27/12 , C08L75/04 , C08L33/16
摘要： The invention relates to a composition of ionisable fluoropolymers, in particular to polymer compositions comprising: a) at least one fluorinated ionisable polymer (A), which comprises recurring fluorinated blocks and recurring functional blocks, each of said recurring functional blocks comprising at least one ionisable anionic group, and in which polymer (A) at least one of the said recurring functional blocks is comprised between two fluorinated blocks; b) at least one fluorinated ionisable polymer (B), which comprises recurring fluorinated blocks and recurring functional blocks, each of said recurring functional blocks comprising at least one ionisable cationic group, and in which polymer (B) at least one of the said recurring functional blocks is comprised between two fluorinated blocks; wherein the ratio between the ionic equivalents of polymer (A) and the ionic equivalents of polymer (B) ranges from 1.1 to 0.9.

4. 发明申请

WO2013017401A1 (PER)FLUOROPOLYMER COMPOSITION 审中-公开
标题翻译：（PER）氟聚合物组合物
公开(公告)号：WO2013017401A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/063951
申请日：2012-07-17
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , ARCELLA, Vincenzo , TONELLI, Claudio Adolfo Pietro , BARBIERI, Solange
发明人： ARCELLA, Vincenzo , TONELLI, Claudio Adolfo Pietro , BARBIERI, Solange
IPC分类号： C08G65/333 , C08K5/16 , C08L71/00 , C08L27/12
CPC分类号： C08G65/00 , C08G65/007 , C08G65/33303
摘要： The present invention relates to (per)fluoropolymer compositions, in particular to (per)fluoropolyether compositions comprising: - a (per)fluoropolymer having more than two carboxy groups and - a polyamine. The invention further relates to processes for preparing said compositions and to moulded articles obtained from said compositions.
摘要翻译：本发明涉及（全）含氟聚合物组合物，特别是涉及（全）含氟聚醚组合物，其包含： - 具有多于两个羧基的（全）含氟聚合物和 - 多胺。本发明还涉及制备所述组合物的方法和由所述组合物获得的模塑制品。

5. 发明申请

WO2012072532A1 TRIAZINE DERIVATIVE 审中-公开
公开(公告)号：WO2012072532A1
公开(公告)日：2012-06-07
申请号：PCT/EP2011/071107
申请日：2011-11-28
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , VALSECCHI, Roberto , MUTTA, Fabrizio , TONELLI, Claudio Adolfo Pietro
发明人： VALSECCHI, Roberto , MUTTA, Fabrizio , TONELLI, Claudio Adolfo Pietro
IPC分类号： C08G65/00
CPC分类号： C10M133/42 , C08G65/00 , C08G65/007 , C08G65/33317 , C10M2213/0606 , C10M2215/2225
摘要： The invention pertains to certain (per)fluoropolyether triazine derivatives comprising at least one triazine group and at least one fluoropolyoxyalkene chain (chain R f ) comprising a fluorocarbon segment having ether linkages in main chain, said chain R f comprising at least one hydroxyl group, to a method for their manufacture and to their use in lubrication, in particular for lubricating sliding or moving parts of magnetic recording media.
摘要翻译：本发明涉及包含至少一种三嗪基团和至少一种含氟聚氧亚烷基链（链Rf）的（全）氟聚醚三嗪衍生物，其包含在主链中具有醚键的氟碳链段，所述链Rf包含至少一个羟基，至其制造方法及其在润滑中的使用，特别是用于润滑滑动或磁记录介质的运动部件。

6. 发明申请

WO2010136392A1 PROTECTIVE FILM FOR A SOLAR CELL MODULE 审中-公开
标题翻译：太阳能电池模块的保护膜
公开(公告)号：WO2010136392A1
公开(公告)日：2010-12-02
申请号：PCT/EP2010/057022
申请日：2010-05-21
申请人： SOLVAY SOLEXIS S.p.A. , FONTANA, Simonetta, Antonella , TONELLI, Claudio Adolfo Pietro
发明人： FONTANA, Simonetta, Antonella , TONELLI, Claudio Adolfo Pietro
IPC分类号： C08J5/18 , H01L31/048
CPC分类号： C08J5/18 , C08J2371/02 , H01L31/0481 , Y02E10/50
摘要： The invention relates to a protective film for a solar cell module, to a process for manufacturing said protective film and to a solar cell module comprising said protecting film. The protective film comprises at least one layer comprising a perf luoropolyether (PFPE) polymer [polymer (F)], said polymer being obtainable by cross-linking a composition [composition (C) ] comprising : a) at least one functional perfluoropolyether compound [compound (E) ], said compound (E) comprising a (per) fluoropolyoscyalkylene chain [chain (Rf)], and at least one unsaturated moiety, said compound (E) being present in an amount included in the range of 10 % to 95 % wt with respect to composition (C); b) at least one nonfuorinated compound [compound (M) ] having at least one unsaturated moiety, provided that said nonf luorinated compound (M) has at least two unsaturated moieties if compound (E) has one unsaturated moiety; and c) at least one crosslinking initiator.
摘要翻译：本发明涉及一种用于太阳能电池模块的保护膜，制造所述保护膜的方法以及包括所述保护膜的太阳能电池组件。保护膜包括至少一层包含全氟聚醚（PFPE）聚合物[聚合物（F）]的层，所述聚合物可通过交联组合物（组合物（C）]获得，所述组合物包含：a）至少一种功能性全氟聚醚化合物[ 化合物（E）]，所述化合物（E）包含（全）氟多聚亚烷基链[链（Rf）]和至少一个不饱和部分，所述化合物（E）的含量范围为10％相对于组合物（C）为95重量％ b）至少一种具有至少一个不饱和部分的非有机化合物[化合物（M）]，条件是如果化合物（E）具有一个不饱和部分，所述非脱硫化合物（M）具有至少两个不饱和部分; 和c）至少一种交联引发剂。

7. 发明申请

WO2010130628A1 PROCESS FOR THE PURIFICATION OF POLYOL PFPE DERIVATIVES 审中-公开
标题翻译：多元醇PFPE衍生物的纯化方法
公开(公告)号：WO2010130628A1
公开(公告)日：2010-11-18
申请号：PCT/EP2010/056185
申请日：2010-05-06
申请人： SOLVAY SOLEXIS S.p.A. , TONELLI, Claudio Adolfo Pietro , VEZZULLI, Graziano Giuseppe , PICOZZI, Rosaldo , GAVEZOTTI, Piero
发明人： TONELLI, Claudio Adolfo Pietro , VEZZULLI, Graziano Giuseppe , PICOZZI, Rosaldo , GAVEZOTTI, Piero
IPC分类号： C08G65/30
CPC分类号： C08G65/007 , C08G65/30
摘要： The invention pertains to a process for the purification of a polyol (per)fluoropolyether derivative [polyol (P)], said polyol (P) comprising one or more hydroxyl (per)fluoropolyether derivatives [PFPEs (OH)] comprising at least one (per)fluoropolyoxyalkylene chain (chain R f ) and at least one end-group having formula -CF 2 CH 2 OCH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 OH (t 3 ), from a mixture of hydroxyl (per)fluoropolyether derivatives [mixture (M)], said mixture (M) comprising said polyol (P) and at least one hydroxyl (per)fluoropolyether derivative [PFPE (OH)] different from polyol (P) and comprising at least one (per)fluoropolyoxyalkylene chain (chain R f ) and at least one end-group selected from those having formulae -CF 2 CH 2 OH (t 1 ) and -CF 2 CH 2 OCH 2 CH(OH)CH 2 OH (t 2 ), said process comprising the following steps: step 1 : reacting the mixture (M) with a ketone and/or an aldehyde so as to yield corresponding mixture of cyclic ketal/acetal (per)fluoropolyether derivatives [PFPEs (OH) p ] [protected mixture (P)]; step 2: submitting the protected mixture (P) to adsorption on silica gel so as to yield an adsorbed protected product [adsorbed product (P p )] and then recovering a desorbed protected product [desorbed product (P p )] by subsequent desorption from silica gel of said adsorbed product (P p ); step 3: distilling the desorbed product (P p ) under reduced pressure so as to isolate a protected product residue [product (P r )]; step 4: hydrolyzing the product (P r ) so as to obtain polyol (P).
摘要翻译：本发明涉及纯化多元醇（全）氟聚醚衍生物[多元醇（P）]的方法，所述多元醇（P）包含一种或多种羟基（全）含氟聚醚衍生物[PFPE（OH）]，其包含至少一种（（OH）CH 2 OH（t3）的至少一个末端基团，由羟基（全）氟代聚醚衍生物[混合物（M）]的混合物，所述混合物（P）和至少一种不同于多元醇（P）的羟基（全）氟聚醚衍生物[PFPE（OH）]并且包含至少一个（全）氟聚氧化烯链（链Rf）和至少一个末端 - 基团选自具有式-CF 2 CH 2 OH（t 1）和-CF 2 CH 2 OCH 2 CH（OH）CH 2 OH（t 2）的那些，所述方法包括以下步骤：步骤1：使混合物（M）与酮和/或醛反应，产生相应的环缩酮/缩醛（全）氟代聚醚衍生物[PFPE（OH）p] [保护的混合物（P） ]。步骤2：将保护的混合物（P）提交到硅胶上吸附，得到吸附的保护产物[吸附产物（Pp）]，然后通过随后的硅胶解吸回收解吸的保护产物[解吸产物（Pp）] 的所述吸附产物（Pp）; 步骤3：在减压下蒸馏除油产物（Pp），以分离受保护的产物残渣[产物（Pr）]; 步骤4：水解产物（Pr）以获得多元醇（P）。

8. 发明申请

WO2010130625A1 PROCESS FOR THE PURIFICATION OF POLYOL PFPE DERIVATIVES 审中-公开
标题翻译：多元醇PFPE衍生物的纯化方法
公开(公告)号：WO2010130625A1
公开(公告)日：2010-11-18
申请号：PCT/EP2010/056177
申请日：2010-05-06
申请人： SOLVAY SOLEXIS S.P.A. , VEZZULLI, Graziano Giuseppe , GAVEZOTTI, Piero , MUTTA, Fabrizio , TONELLI, Claudio Adolfo Pietro
发明人： VEZZULLI, Graziano Giuseppe , GAVEZOTTI, Piero , MUTTA, Fabrizio , TONELLI, Claudio Adolfo Pietro
IPC分类号： C08G65/30
CPC分类号： C08G65/007 , C08G65/30
摘要： The invention pertains to a process for the purification of a polyol (per)fluoropolyether derivative [polyol (P)], said polyol (P) comprising one or more hydroxyl (per)fluoropolyether derivatives [PFPE (OH)] comprising at least one (per)fluoropolyoxyalkylene chain (chain R f ) and at least one end-group having formula -CF 2 CH 2 OCH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 OH (t3), from a mixture of hydroxyl (per)fluoropolyether derivatives [mixture (M)], said mixture (M) comprising said polyol (P) and at least one hydroxyl (per)fluoropolyether derivative [PFPE (OH)] different from polyol (P) and comprising at least one (per)fluoropolyoxyalkylene chain (chain Rf) and at least one end-group selected from those having formulae -CF 2 CH 2 OH (t 1 ) and -CF 2 CH 2 OCH 2 CH(OH)CH 2 OH (t 2 ), said process comprising the following steps: step 1 : reacting the mixture (M) with a ketone and/or an aldehyde so as to yield corresponding mixture of cyclic ketal/acetal (per)fluoropolyether derivatives [PFPEs (OH) p ] [protected mixture (P)]; step 2: molecular distillation of the protected mixture (P) so as to isolate a protected product heavy residue [product (P r )]; step 3: hydrolyzing the product (P r ) so as to yield a deprotected product [product (P d )]; step 4: distillation under reduced pressure of the product (P d ) so as to obtain polyol (P).
摘要翻译：本发明涉及纯化多元醇（全）氟聚醚衍生物[多元醇（P）]的方法，所述多元醇（P）包含一种或多种羟基（全）含氟聚醚衍生物[PFPE（OH）]，其包含至少一种（（OH）CH 2 OH（t3）的至少一个末端基团，由羟基（全）氟代聚醚衍生物[混合物（M）]的混合物，所述混合物（P）和至少一种不同于多元醇（P）的羟基（全）氟聚醚衍生物[PFPE（OH）]并且包含至少一个（全）氟聚氧化烯链（链Rf）和至少一个末端 - 基团选自具有式-CF 2 CH 2 OH（t 1）和-CF 2 CH 2 OCH 2 CH（OH）CH 2 OH（t 2）的那些，所述方法包括以下步骤：步骤1：使混合物（M）与酮和/或醛反应，产生相应的环缩酮/缩醛（全）氟聚醚衍生物[PFPE（OH）p] [保护的混合物（P） ]。步骤2：保护的混合物（P）的分子蒸馏，以分离受保护的产物重残渣[产物（Pr）]; 步骤3：水解产物（Pr）以产生脱保护的产物[产物（Pd）]; 步骤4：在减压下蒸馏产物（Pd），得到多元醇（P）。

9. 发明申请

WO2018172172A1 FLUORINATED POLYMERS AND USES THEREOF 审中-公开
公开(公告)号：WO2018172172A1
公开(公告)日：2018-09-27
申请号：PCT/EP2018/056493
申请日：2018-03-15
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： TONELLI, Claudio Adolfo Pietro , WLASSICS, Ivan Diego , MARCHIONNI, Giuseppe
IPC分类号： C08G65/00 , C08G65/333 , C08G65/334
CPC分类号： C08G65/007 , C08G65/33389 , C08G65/33396 , C08G65/3346 , C08G65/3348 , C08G2650/48
摘要： The present invention relates to fluorinated polymers, in particular to (per)fluoropolyethers to be used as lubricants or as additives for (per)fluorinated oils or greases.

10. 发明申请

WO2014170196A1 MODIFIED HYDROGEN-BASED LUBRICANTS 审中-公开
标题翻译：改性氢化润滑剂
公开(公告)号：WO2014170196A1
公开(公告)日：2014-10-23
申请号：PCT/EP2014/057233
申请日：2014-04-10
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： AVATANEO, Marco , DENISOV, Evgeny , VICINO, Davide , TONELLI, Claudio Adolfo Pietro , MARCHIONNI, Giuseppe
IPC分类号： C10M105/50 , C10M105/54 , C10M107/38 , C10M177/00 , C10N30/06 , C10N30/08 , C10N30/10 , C10N40/04 , C10N40/25 , C10N40/30 , C10N50/10
CPC分类号： C10M169/042 , C10M107/38 , C10M109/02 , C10M2211/0206 , C10M2211/0245 , C10M2211/0406 , C10M2211/0445 , C10N2220/022 , C10N2230/06 , C10N2230/08 , C10N2230/10 , C10N2240/04 , C10N2240/06 , C10N2240/10 , C10N2240/102 , C10N2240/14 , C10N2240/30
摘要： The present invention related to a process for the manufacture of hydrogen-based lubricants modified with per(halo)fluorinated aromatic compounds, to the modified lubricants thereby obtained and to the use of the modified lubricants for the preparation of lubricant compositions.
摘要翻译：本发明涉及用于制备用全（卤）氟化芳族化合物改性的氢基润滑剂的方法，由此得到的改性润滑剂以及改性润滑剂用于制备润滑剂组合物的用途。

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