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1. 发明申请

WO2010097363A1 POLYMER COMPOSITION 审中-公开
标题翻译：聚合物组合物
公开(公告)号：WO2010097363A1
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052199
申请日：2010-02-22
申请人： SOLVAY SA , MOORE, Theodore , REICHMANN, Mark G. , AVATANEO, Marco , MARCHIONNI, Giuseppe
发明人： MOORE, Theodore , REICHMANN, Mark G. , AVATANEO, Marco , MARCHIONNI, Giuseppe
IPC分类号： C08G65/323 , C08G65/40 , C08L71/02 , C08L81/06
CPC分类号： C08G65/007 , C08G2650/40 , C08G2650/48 , C08L71/00 , C08L71/02 , C08L79/08 , C08L81/06 , C08L2205/05 , C08L2666/22 , C08L81/00 , C08L2666/14
摘要： The invention pertains to a polymer composition comprising: - at least one polycondensation polymer having a heat deflection temperature (HDT) of above 80°C under a load of 1.82 MPa when measured according to ASTM D648 [polymer (P)]; at least one perfluoropolyether block copolymer [polymer (F)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R f ), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R a ) comprising recurring units of formula: -(CR 1 R 2 -CR 3 R 4 )- wherein R 1 , R 2 , R 3 , R 4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C 1 -C 6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl, to a process for its manufacture and to its use for manufacturing shaped articles, in particular by extrusion moulding or injection moulding techniques.
摘要翻译：本发明涉及一种聚合物组合物，其包含： - 当根据ASTM D648 [聚合物（P）]测量时，至少一种在1.82MPa负载下具有高于80℃的热变形温度（HDT）的缩聚聚合物; 至少一种全氟聚醚嵌段共聚物[聚合物（F）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rf），也就是说包含具有至少一个链烯键的重复单元的链段和至少一个碳氟化合物部分，和B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R 1，R 2，R 3，R 4彼此相同或不同，选自的H，卤素（优选F，Cl）; 任选地含有氟或其它杂原子，优选全氟烷基或（全）氟氧基烷基的C 1 -C 6（氢）碳基团，其制备方法及其用于制造成型制品的方法，特别是通过挤出成型或注射成型技术。

2. 发明申请

WO2011144681A1 PVDF COATING COMPOSITION 审中-公开
标题翻译： PVDF涂料组合物
公开(公告)号：WO2011144681A1
公开(公告)日：2011-11-24
申请号：PCT/EP2011/058094
申请日：2011-05-19
申请人： SOLVAY SA , ARCELLA, Vincenzo , IEVA, Eliana , LIN, Shiow-Ching , AVATANEO, Marco , MARCHIONNI, Giuseppe
发明人： ARCELLA, Vincenzo , IEVA, Eliana , LIN, Shiow-Ching , AVATANEO, Marco , MARCHIONNI, Giuseppe
IPC分类号： C09D127/16 , C08K9/08 , C09C3/10
CPC分类号： C09D127/16 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C08K3/32 , C08K9/08 , C08L33/00 , C09C1/3063 , C09C1/3072 , C09C1/3081 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C3/08 , C09C3/10 , C09C3/12 , C08L2666/04
摘要： The invention pertains to compositions comprising: - at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and - inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R f ), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R a ) comprising recurring units of formula: -(CR 1 R 2 -CR 3 R 4 )- wherein R 1 , R 2 , R 3 , R 4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, CI); C 1 -C 6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl, and to the use of the same as coating on various substrates.
摘要翻译：本发明涉及包含以下的组合物： - 至少一种偏二氟乙烯（VDF）聚合物[聚合物（F）]; 至少部分地涂覆有至少一种全氟聚醚嵌段共聚物[聚合物（E）]的无机颗粒，其包含：A）一种或多种（全）氟聚氧亚烷基链段（链Rf），也就是说，包含至少具有至少一个链烯键和至少一个氟碳部分，以及B）一个或多个包含式的重复单元的聚亚烷基链（链Ra）： - （CR 1 R 2 -CR 3 R 4） - 其中R 1，R 2，R 3，R 4等于或不同彼此之间选自H，卤素（优选F，Cl）; 任选地含有氟或其它杂原子，优选全氟烷基或（全）氟氧基烷基的C 1 -C 6（氢）碳基团，以及其用于各种基材上的涂层。

3. 发明申请

WO2008065163A1 FLUORINATED LUBRICANTS 审中-公开
标题翻译：氟化润滑剂
公开(公告)号：WO2008065163A1
公开(公告)日：2008-06-05
申请号：PCT/EP2007/062998
申请日：2007-11-29
申请人： SOLVAY SOLEXIS S.p.A. , AVATANEO, Marco , GUARDA, Pier Antonio , MARCHIONNI, Giuseppe , MACCONE, Patrizia , BOCCALETTI, Giovanni
发明人： AVATANEO, Marco , GUARDA, Pier Antonio , MARCHIONNI, Giuseppe , MACCONE, Patrizia , BOCCALETTI, Giovanni
IPC分类号： C08F283/06 , C08F293/00
CPC分类号： C08F293/00 , C08F214/182 , C08F283/06 , C08F293/005 , C08L53/00 , C10M107/38 , C10M119/22 , C10M2201/0616 , C10M2201/1026 , C10M2201/1056 , C10M2203/045 , C10M2203/065 , C10M2203/1006 , C10M2203/1025 , C10M2203/1045 , C10M2205/0285 , C10M2207/1206 , C10M2207/2805 , C10M2209/1033 , C10M2213/043 , C10M2213/046 , C10M2213/0606 , C10M2213/0613 , C10M2213/0626 , C10M2215/121 , C10M2217/0456 , C10M2229/025 , C10N2210/01 , C10N2210/02 , C10N2220/021 , C10N2220/022 , C10N2230/06 , C10N2230/74 , C10N2240/06 , C10N2240/202 , C10N2250/10 , C10N2250/121 , C08L2666/02 , C08L2666/04
摘要： Fluorinated lubricants of formula T-O-[A-B] z -[A-B'] z' -A-T' (I) wherein: A = -(X) a -O-A'-(X') b - A' is a perfluoropolyether chain comprising units (CF 2 O), (CF 2 CF 2 O), (CF 2 CF 2 CF 2 O), (CF 2 CF 2 CF 2 CF 2 O); X, X' = -CF 2 -, -CF 2 CF 2 -; a, b = 0 or 1; B derives from olefins, of which at least one homopolymerizable by radical route, of formula: -[(CR 1 R 2 -CR 3 R 4 ) j (CR 5 R 6 -CR 7 R 8 ) j ' ]- (Ia) wherein j = 1-5, j'= 0-4 and 2 1 -R 8 = halogen, H, C 1 -C 6 (per)haloalkyl, C 1 -C 6 alkyl, C 1 -C 6 oxy(per)-fluoroalkyl; z ≥ 2; z' is 0 or an integer; z, z' are such that the number average molecular weight of the polymer of formula (I) is in the range 500-500,000; B'= (Ia) but at least one of R 1 -R 8 has a meaning different than that in B and 2 ≤(j+j') 1 -C 3 perfluoroalkyl, C 1 -C 6 alkyl and compositions thereof.
摘要翻译：式（A）的氟化润滑剂：其中：A = - （X）-S-（A）其中：A = - （X） a'是包含单元（CF 2 O 2）的全氟聚醚链，（CF 2 O 2），（CF 3） 2 CF 2，O 2），（CF 2 CH 2 CF 2 O），（CF _{2 CF _{2 CF _{2 CF _{2 O）; X，X'= -CF 2 - ， - CF 2 2 CF 2 - 。 a，b = 0或1; B衍生自烯烃，其中至少一种可通过自由基路线均聚的式，其具有下式： - [（CR 1 R 2 R 2 -CR 3 R _{4 ）_{Ĵ（CR _{5 - [R _{6 -CR _{7 - [R _{8 “”}}}}}}}}}}

4. 发明申请

WO2012084749A1 THERMOPROCESSABLE PER(HALO)FLUOROPOLYMER COMPOSITION 审中-公开
标题翻译：（HALO）氟聚合物组合物
公开(公告)号：WO2012084749A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073146
申请日：2011-12-16
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , COLAIANNA, Pasqua , AVATANEO, Marco , DI NICOLO, Emanuele , BESANA, Giambattista , MARCHIONNI, Giuseppe
发明人： COLAIANNA, Pasqua , AVATANEO, Marco , DI NICOLO, Emanuele , BESANA, Giambattista , MARCHIONNI, Giuseppe
IPC分类号： C08L71/02 , C08G65/00 , C08L27/00
CPC分类号： C08L53/00 , C08G65/007 , C08G2650/48 , C08K3/04 , C08K2003/3045 , C08L27/00 , C08L27/18 , C08L71/02 , C08L2666/04
摘要： The invention pertains to a thermoprocessable composition comprising: - at least one thermoprocessable per(halo)fluoropolymer [polymer (A)]; - at least one inorganic filler [filler (I)]; and - at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R f ), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R a ) comprising recurring units of formula: -(CR 1 R 2 -CR 3 R 4 )- wherein R 1 , R 2 , R 3 , R 4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, CI); C 1 -C 6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyi or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种热可加工组合物，其包含： - 至少一种热可加工的每（卤）含氟聚合物[聚合物（A）]; - 至少一种无机填料[填料（I）]; 和 - 至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rf），也就是说包含具有至少一个链中键的重复单元的链段和至少一个碳氟化合物部分，和B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R 1，R 2，R 3，R 4彼此相同或不同，选自由H，卤素（优选F，Cl）组成的组; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧烷基。

5. 发明申请

WO2010057691A3 HYDROFLUOROALCOHOLS WITH IMPROVED THERMAL AND CHEMICAL STABILITY 审中-公开
公开(公告)号：WO2010057691A3
公开(公告)日：2010-05-27
申请号：PCT/EP2009/060302
申请日：2009-08-07
申请人： SOLVAY SOLEXIS S.P.A. , MARCHIONNI, Giuseppe , DE PATTO, Ugo , AVATANEO, Marco
发明人： MARCHIONNI, Giuseppe , DE PATTO, Ugo , AVATANEO, Marco
IPC分类号： C07C43/13
摘要： Hydrofluoro alcohols of formula : A-(R f ) a -CFX-O-R h O-(CFX-(R f ) a* -CFX-O-R h O-) n H (I) in which : R h is a hydrocarbon-based chain; X is F or a C 1 -C 6 (per)fluoroalkyl; a or a* is 0 or 1; R f is a (per)fluoro(poly)oxyalkylene chain or a (per)fluoroalkyl chain; A is chosen from -F, -C1 and -H (possible only when a = 1) or is HO- R h -O-CFX-; n is an integer from 0 to 200, with the condition that n = 0 when A is chosen from -F, -C1 and -H.

6. 发明申请

WO2008065165A1 FLUORINATED LUBRICANTS 审中-公开
标题翻译：氟化润滑剂
公开(公告)号：WO2008065165A1
公开(公告)日：2008-06-05
申请号：PCT/EP2007/063000
申请日：2007-11-29
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , GUARDA, Pier Antonio , AVATANEO, Marco
发明人： MARCHIONNI, Giuseppe , GUARDA, Pier Antonio , AVATANEO, Marco
IPC分类号： C08G65/00
CPC分类号： C08G65/007 , C08L27/12 , C08L71/02 , C08L2205/05 , C10M107/38 , C10M2213/043 , C10M2213/0606 , C10N2230/06 , C10N2230/74 , C10N2250/10 , C08L2666/04
摘要： Polymers of formula (I) Q-O-[A-B] z -[A-B'] z' -A-Q' (I) wherein: - A = -(X) a -O-A'-(X') b - with A'= perfluoropolyether chain and X, X'= -CF 2- , -CF 2 CF 2- ; a, b = 0.1 with the proviso that a = 1 if A is linked to Q-O-; b = 0 when A is linked to Q'; - B derives from homopolymerizable olefins by radical route, of formula: -[(CR 1 R 2- CR 3 R 4 ) j (CR 5 R 6 -CR 7 R 8 ) j' ]- (Ia) wherein j is an integer from 1 to 30, j' is an integer from 0 to 29 with the proviso that (j+j') is higher than 2 and lower than 30; R 1 -R 8 are halogen; H; C 1 -C 6 (per)haloalkyl; C 1 -C 6 alkyl; C 1 -C 6 oxy(per)fluoroalkyl; B'= B but at least one among R 1 -R 8 has a meaning different from that in B; - z, z' are such that the number average molecular weight of the polymer of formula (I) is between 500 and 150,000; - Q, Q'= C 1 -C 3 (per)fluoroalkyl or functional end group -(CFW)-D q -T k ; W = F, CF 3 ; k and q are integers, k ranges from 1 to 4, preferably 1 or 2, q is an integer and is equal to 0 or 1; with the proviso that at least one of Q, Q' is functional end group.
摘要翻译：式（I）的聚合物QO- [AB] z - [A-B'] Z'-AQ'（I）其中：-A = - （X） A'=全氟聚醚链和X，X'= -CF 2 - - - - （X'）b - ，-CF 2 CF 2 - ， - a，b = 0.1，条件是如果A连接到Q-O-，则a = 1; 当A连接到Q'时，b = 0; -B通过自由基途径衍生自均聚烯烃，式为： - [（CR 1 R 2 - NR 3 R 4） / SUB>）_{Ĵ（CR _{5 - [R _{6 -CR _{7 - [R _{8 （Ia）其中j为1至30的整数，j'为0至29的整数，条件是（j + j'）高于2且低于超过30 R 1 -R 8是卤素; H; C 1 -C 6 -C 6（全）卤代烷基; C 1 -C 6烷基; C 1 -C 6烷基; C 1 -C 6 -C 6氧基（全）氟代烷基; B'= B，但R 1至R 8中的至少一个具有与B中不同的含义; -z，z'使得式（I）的聚合物的数均分子量在500和150,000之间; - Q，Q'= C 1 -C 3（全）氟烷基或官能端基 - （CFW）-DQ q - SUB>ķ; W = F，CF 3 3; k和q是整数，k的范围是1至4，优选1或2，q是整数并且等于0或1; 条件是Q，Q'中的至少一个是官能端基。}}}}}

7. 发明申请

WO2012168130A1 STABLE ION EXCHANGE FLUORINATED POLYMERS AND MEMBRANES OBTAINED THEREFROM 审中-公开
标题翻译：稳定的离子交换荧光聚合物和其获得的膜
公开(公告)号：WO2012168130A1
公开(公告)日：2012-12-13
申请号：PCT/EP2012/060212
申请日：2012-05-31
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , AVATANEO, Marco , OLDANI, Claudio , MARCHIONNI, Giuseppe
发明人： AVATANEO, Marco , OLDANI, Claudio , MARCHIONNI, Giuseppe
IPC分类号： H01M8/10 , C08J5/22
CPC分类号： H01M8/1039 , B01D71/32 , C08J5/225 , C08J2327/18 , C08K5/1565 , H01M8/1018 , H01M2300/0082 , H01M2300/0091 , Y02E60/521
摘要： A composition comprising at least one fluorinated polymer comprising -SO 2 X functional groups, wherein X is selected from X' or from OM and wherein X' is selected from the group consisting of F, CI, Br, I and M is selected from the group consisting of H, alkaline metals, NH4, and at least one fluorinated aromatic compound. Ion conducting membranes comprising the composition have improved resistance towards radical degradation in fuel cell applications.
摘要翻译：一种组合物，其包含至少一种包含-SO 2 X官能团的氟化聚合物，其中X选自X'或选自OM，并且其中X'选自F，Cl，Br，I和M，其选自的H，碱金属，NH 4和至少一种氟化芳族化合物。包含该组合物的离子导电膜对燃料电池应用中的自由基降解具有改进的抗性。

8. 发明申请

WO2009112577A1 (PER)FLUORINATED ADDITION PRODUCTS 审中-公开
标题翻译：（PER）氟化添加剂
公开(公告)号：WO2009112577A1
公开(公告)日：2009-09-17
申请号：PCT/EP2009/052998
申请日：2009-03-13
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , AVATANEO, Marco , GUARDA, Pier Antonio
发明人： MARCHIONNI, Giuseppe , AVATANEO, Marco , GUARDA, Pier Antonio
IPC分类号： C08G65/00
CPC分类号： C08G65/007 , C08G65/3312 , C08G65/3331 , C08G65/337 , C08L2205/05
摘要： The invention pertains to a process for the addition of at least one (per)fluoropolyether peroxide comprising at least one peroxidic moiety and at least one fluoropolyoxyalkene chain (chain R f ) (i.e. a fluorocarbon segment comprising ether linkages in main chain) [peroxide (P)] onto a per(halo)fluorinated aromatic compound [compound (F)], so as to yield an addition compound of said compound (F), said addition compound [compound (A)] comprising at least one perfluorinated non-aromatic cyclic moiety having at least two substituents comprising a chain Rf and, optionally, conjugated or non conjugated double bond(s). Said addition compounds have been notably found useful as additives for (per)fluorinated fluids and lubricants or as base materials for the manufacture of gum and/or graft polymer compositions.
摘要翻译：本发明涉及添加至少一种（全）含氟聚醚过氧化物的方法，该过氧化物包含至少一个过氧化物部分和至少一个氟聚氧亚烷基链（链Rf）（即在主链中包含醚键的氟烃部分）[过氧化物（P ）]到全（卤）氟化芳族化合物[化合物（F）]]，得到所述化合物（F）的加成化合物，所述加成化合物[化合物（A）]包含至少一个全氟化非芳族环部分具有至少两个包含链R f的取代基和任选的共轭或非共轭双键。特别地，所述加成化合物可用作（全）氟化流体和润滑剂或用作制备胶和/或接枝聚合物组合物的基础材料的添加剂。

9. 发明申请

WO2012041821A1 A COMPOSITE POLYMERIZATION INITIATOR AND POLYMER BRUSH COMPOSITE OBTAINED THEREFROM 审中-公开
标题翻译：复合聚合反应器和聚合物刷组合物
公开(公告)号：WO2012041821A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066708
申请日：2011-09-27
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , AVATANEO, Marco , MARCHIONNI, Giuseppe , DENISOV, Evgeny , LIN, Shiow-Ching , SPADA, Fabrizio , KENT, Bradley, Lane
发明人： AVATANEO, Marco , MARCHIONNI, Giuseppe , DENISOV, Evgeny , LIN, Shiow-Ching , SPADA, Fabrizio , KENT, Bradley, Lane
IPC分类号： C07F7/12 , C08F220/14
CPC分类号： C07F19/00 , C07B2200/11 , C07F7/12 , C08F14/22 , C08F20/14
摘要： Composite polymerization initiators are disclosed suitable to prepare polymer brush composites. The composite initiators comprise groups of formula (1): -(L) n -CR 2 -B(R B1 ) 2 covalently anchored to the surface of a solid substrate. Disclosed are also a process for the preparation of the composite polymerization initiator as well as the polymerization process providing a polymer brush composite from said composite initiator.
摘要翻译：公开了适用于制备聚合物刷复合材料的复合聚合引发剂。复合引发剂包括共价键合到固体底物表面的式（1）基团： - （L）n-CR 2 -B（RB 1）2。还公开了制备复合聚合引发剂的方法以及从所述复合引发剂提供聚合物刷复合物的聚合方法。

10. 发明申请

WO2012007374A1 FLUOROELASTOMER COMPOSITION 审中-公开
标题翻译：荧光体组合物
公开(公告)号：WO2012007374A1
公开(公告)日：2012-01-19
申请号：PCT/EP2011/061597
申请日：2011-07-08
申请人： SOLVAY SOLEXIS S.P.A. , FANTONI, Matteo , APOSTOLO, Marco , AVATANEO, Marco , MARCHIONNI, Giuseppe
发明人： FANTONI, Matteo , APOSTOLO, Marco , AVATANEO, Marco , MARCHIONNI, Giuseppe
IPC分类号： C08L27/12
CPC分类号： C08K5/06 , C08L27/18 , C08L51/08 , C08L53/00
摘要： The invention pertains to a (per)fluoroelastomer composition comprising: - at least one (per)fluoroelastomer [fluoroelastomer (A)]; and - from 0.1 to 30 weight parts, per hundred parts of fluoroelastomer (A), of at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R a ) comprising recurring units of formula: -(CR 1 R 2 -CR 3 R 4 )- wherein R- 1 , R 2 , R 3 , R 4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, CI); C 1 -C 6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种（全）含氟弹性体组合物，其包含： - 至少一种（全）含氟弹性体[含氟弹性体（A）]; 和每100份含氟弹性体（A）0.1至30重量份的至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rf），即表示包含具有至少一个链状醚键和至少一个碳氟化合物部分的重复单元的链段，以及B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） 1，R2，R3，R4彼此相同或不同，选自H，卤素（优选F，Cl）; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。

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