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1. 发明申请

WO2008090106A1 PROCESS FOR THE PREPARATION OF DIARYL CARBONATE 审中-公开
标题翻译：制备二氧化碳的方法
公开(公告)号：WO2008090106A1
公开(公告)日：2008-07-31
申请号：PCT/EP2008/050604
申请日：2008-01-21
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis , VROUWENVELDER, Cornelis Leonardo Maria
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis , VROUWENVELDER, Cornelis Leonardo Maria
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C68/06 , Y02P20/127 , C07C69/96
摘要： The invention relates to a process for the preparation of a diaryl carbonate by transesterification of an aromatic alcohol with a dialkyl carbonate in the presence of a transesterification catalyst during a period of time [t a ], in which the aryl moiety is selected from unsubstituted phenyl and mono-, di- and trisubstituted phenyl groups, in which the alkyl moiety is selected from C 2 to C 4 linear and branched alkyl groups, in which the catalyst concentration is designated [c a ], expressed as gram catalyst per gram of aromatic alcohol and dialkyl carbonate, in which the period of time [t m ] and catalyst concentration [c m ] are determined to arrive at a pre-set approach to the equilibrium for the transesterification of the aromatic alcohol with dimethyl carbonate to methyl aryl carbonate and methanol, in which the product [c a ]*t a is at least 1.5* [c m ]*t m , under otherwise the same reaction conditions.
摘要翻译：本发明涉及一种通过在酯交换催化剂存在下在一段时间内酯交换芳族醇与碳酸二烷基酯来制备碳酸二芳基酯的方法，其中芳基部分选自未取代的苯基和单取代，二取代和三取代的苯基，其中烷基部分选自C 2〜C 4直链和支链烷基，其中催化剂浓度指定为[克/ a]，其表示为克催化剂/克芳族醇和碳酸二烷基酯，其中时间[t] 并确定催化剂浓度[℃]以得到芳族醇与碳酸二甲酯与碳酸甲基芳基酯和甲醇的酯交换的平衡的预设方法，其中产物[c 在其它方面相同的情况下，至少1.5 * [c m REA 条件条件。

2. 发明申请

WO2007096341A1 PROCESS FOR THE PRODUCTION OF ALKYLENE CARBONATE AND USE OF ALKYLENE CARBONATE THUS PRODUCED IN THE MANUFACTURE OF AN ALKANE DIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：生产亚烷基二醇和碳酸二乙酯生产中生产的亚烷基碳酸酯的方法
公开(公告)号：WO2007096341A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051583
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
发明人： VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
IPC分类号： C07D317/36 , C07C29/128 , C07C31/20
CPC分类号： C07C29/128 , C07D317/36 , Y02P20/584 , C07C31/202
摘要： An alkylene carbonate is produced by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium compound as catalyst in a process in which (a) the alkylene oxide, carbon dioxide and the phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and catalyst is withdrawn, (b) alkylene carbonate and a mixture of alkylene carbonate and phosphonium catalyst are separated from the product stream and, and (c) the alkylene carbonate, separated in step (b), is recovered as product, and (d) the mixture of alkylene carbonate and phosphonium catalyst is continuously recycled to the reaction zone. The alkylene carbonate thus produced is suitably reacted with an alkanol to produce an alkane diol and a dialkyl carbonate.
摘要翻译：在鏻化合物作为催化剂的存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烃酯，其中（a）将环氧烷，二氧化碳和鏻催化剂从取出含有碳酸亚烃酯和催化剂的产物流，（b）碳酸亚烷基酯和碳酸亚烃酯和鏻催化剂的混合物与产物流分离，和（c）在步骤（b）中分离的碳酸亚烃酯是作为产物回收，和（d）碳酸亚烷基酯和鏻催化剂的混合物连续循环到反应区。这样制得的碳酸亚烃酯适当地与烷醇反应生成烷烃二醇和碳酸二烷基酯。

3. 发明申请

WO2007096343A1 PROCESS FOR THE PRODUCTION OF DIALKYL CARBONATE AND ALKANEDIOL 审中-公开
标题翻译：生产碳酸二烷基酯和阿尔卡尼醇的方法
公开(公告)号：WO2007096343A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051586
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
IPC分类号： C07C68/06 , C07C69/96 , C07C29/128
CPC分类号： C07C68/065 , C07C29/128 , C07C68/08 , Y02P20/127 , Y02P20/142 , C07C69/96 , C07C31/205
摘要： An alkylene carbonate and an alkanol are subjected to transesterification to yield a dialkyl carbonate and alkanediol in a process comprising (a) the alkylene carbonate and an alkanol feedstock are introduced into a reaction zone to react in the presence of a transesterification catalyst to yield an alkanediol-rich stream and a stream comprising dialkyl carbonate and alkanol, which streams are separated; (b) the stream comprising dialkyl carbonate and alkanol is passed to an extractive distillation zone in which an extractant is added to the stream; (c) from the extractive distillation zone an alkanol-rich vapour stream is obtained and a bottom stream containing the extractant and the dialkyl carbonate; (d) the bottom stream from step (c) is separated in a second non-extractive distillation zone to yield a dialkyl carbonate-rich top stream and a extractant-rich bottom stream; (e) the extractant-rich bottom stream is at least partly recycled to the extractive distillation zone, wherein the extractant-rich bottom stream is used as heat source for the alkanol feedstock. The process is suitable for the production of propylene glycol and dimethyl and diethyl carbonate from propylene carbonate and methanol or ethanol, respectively.
摘要翻译：将碳酸亚烷基酯和链烷醇进行酯交换反应，得到碳酸二烷基酯和链烷二醇，该方法包括（a）将碳酸亚烷基酯和链烷醇原料引入反应区，在酯交换催化剂存在下进行反应得到链烷二醇并且包含碳酸二烷基酯和链烷醇的物流，该物流被分离; （b）将包含碳酸二烷基酯和链烷醇的料流送入萃取蒸馏区，其中将萃取剂加入料流中; （c）从萃取蒸馏区获得富链烷醇蒸气流，含有萃取剂和碳酸二烷基酯的塔底料流; （d）来自步骤（c）的底部物流在第二非萃取蒸馏区中分离以产生富含二烷基碳酸盐的顶部物流和富含萃取剂的底部物流; （e）富萃取剂底部料流至少部分地再循环到萃取蒸馏区，其中富萃取剂底部料流用作链烷醇原料的热源。该方法适用于分别从碳酸亚丙酯和甲醇或乙醇生产丙二醇和碳酸二甲酯和碳酸二乙酯。

4. 发明申请

WO2007096342A1 PROCESS FOR THE PREPARATION OF AN ALKANEDIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：制备阿尔卡尼醇和碳酸二乙酯的方法
公开(公告)号：WO2007096342A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051585
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
IPC分类号： C07C68/06
CPC分类号： C07C68/065 , Y02P20/127 , C07C69/96
摘要： An alkanediol and a dialkyl carbonate are prepared in a process comprising: (a) contacting an alkylene carbonate with an alkanol feedstock under transesterification conditions in a reactive distillation zone to obtain a top stream comprising dialkyl carbonate and the alkanol and a bottom stream comprising the alkanediol; (b) separating the top stream comprising dialkyl carbonate and the alkanol into an alkanol-rich stream and a dialkyl carbonate-rich stream; (c) recovering the dialkyl carbonate, optionally after further purification, from the dialkyl carbonate-rich stream; and (d) recycling at least part of the alkanol-rich stream to the reactive distillation zone as part of the alkanol feedstock, wherein the alkanol-rich stream is split in at least two portions, and at least one portion is condensed and freed from compounds with a lower boiling point than the alkanol. The process is especially suitable for the production of propylene glycol and dimethyl carbonate from propylene carbonate and methanol.
摘要翻译：制备烷基二醇和碳酸二烷基酯的方法包括：（a）在反应蒸馏区中在酯交换反应条件下使烯烃碳酸酯与链烷醇原料接触，以获得包含碳酸二烷基酯和链烷醇的顶部料流和包含链烷二醇 ; （b）将包含碳酸二烷基酯和链烷醇的顶部料流分离成富链烷醇流和富含碳酸二烷基酯的料流; （c）任选地进一步纯化后从富含碳酸二烷基酯的流中回收碳酸二烷基酯; 和（d）作为链烷醇原料的一部分将至少部分富含链烷醇的料流再循环至反应性蒸馏区，其中富链烷醇流分成至少两部分，并且至少一部分被冷凝并从沸点低于链烷醇的化合物。该方法特别适用于从碳酸丙烯酯和甲醇生产丙二醇和碳酸二甲酯。

5. 发明申请

WO2010046320A1 PROCESS FOR REMOVING AN ALKANOL IMPURITY FROM AN ORGANIC CARBONATE STREAM 审中-公开
标题翻译：从有机碳酸盐流中去除碱金属污染物的方法
公开(公告)号：WO2010046320A1
公开(公告)日：2010-04-29
申请号：PCT/EP2009/063606
申请日：2009-10-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , VAPORCIYAN, Garo , Garbis , VROUWENVELDER, Cornelis , Leonardus , Maria
发明人： VAN DER HEIDE, Evert , VAPORCIYAN, Garo , Garbis , VROUWENVELDER, Cornelis , Leonardus , Maria
IPC分类号： C07C68/08 , C07C68/06 , C07C69/96
CPC分类号： C07C68/06 , C07C68/065 , C07C68/08 , C07C69/96
摘要： The invention relates to a process for removing an alkanol impurity from a stream containing an organic carbonate and the alkanol impurity, comprising contacting the stream with a catalyst to effect reaction of the alkanol impurity with the organic carbonate.
摘要翻译：本发明涉及一种从含有机碳酸盐和链烷醇杂质的流中除去烷醇杂质的方法，包括使该物流与催化剂接触以使链烷醇杂质与有机碳酸酯反应。

6. 发明申请

WO2007096346A1 PROCESS FOR THE PREPARATION OF AN ALKANEDIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：制备阿尔卡尼醇和碳酸二乙酯的方法
公开(公告)号：WO2007096346A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051590
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C68/065 , Y02P20/127 , C07C69/96
摘要： A process for the preparation of an alkanediol and a dialkyl carbonate is provided, which process comprises: (a) contacting an alkylene carbonate with an alkanol feedstock under transesterification conditions in a reactive distillation column to obtain an upwardly moving stream comprising dialkyl carbonate and the alkanol and a downwardly moving stream comprising the alkanediol; (b) recovering the alkanediol at the bottom of the column; (c) withdrawing a dialkyl carbonate- and alkanol-containing product stream at the upper part of the column, which upper part is below the top of the column; and (d) removing lower-boiling compounds at the top of the column.
摘要翻译：提供了一种制备链烷二醇和碳酸二烷基酯的方法，该方法包括：（a）在反应性蒸馏塔中的酯交换条件下使碳酸亚烷基酯与链烷醇原料接触，以获得包含碳酸二烷基酯和链烷醇和包含所述链烷二醇的向下移动的流; （b）回收柱底部的链烷二醇; （c）在柱的上部排出碳酸二烷基酯和含链烷醇的产物流，该上部在塔的顶部下方; 和（d）除去塔顶部的低沸点化合物。

7. 发明申请

WO2007104730A1 PROCESS FOR THE PRODUCTION OF ALKYLENE CARBONATE AND USE OF ALKYLENE CARBONATE THUS PRODUCED IN THE MANUFACTURE OF AN ALKANE DIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：生产亚烷基二醇和碳酸二乙酯的方法生产碳酸亚烷基酯和使用生产的烷基二醇的方法
公开(公告)号：WO2007104730A1
公开(公告)日：2007-09-20
申请号：PCT/EP2007/052270
申请日：2007-03-12
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael
发明人： VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael
IPC分类号： C07D317/36 , C07C68/04 , C07C69/96 , C07C31/18 , C07C29/12
CPC分类号： C07C68/065 , B01J31/0268 , B01J31/4053 , B01J2231/324 , C07C29/128 , C07D317/36 , Y02P20/584 , C07C31/20 , C07C69/96
摘要： An alkylene carbonate is produced by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium catalyst in a process in which (a) the alkylene oxide, carbon dioxide and the phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and used phosphonium catalyst is withdrawn, (b) alkylene carbonate and a stream containing used phosphonium catalyst are separated from the product stream, (c) the alkylene carbonate, separated in step (b), is recovered as product, (d) at least a part of the stream containing used phosphonium catalyst is subjected to purification, to obtain purified phosphonium catalyst, and (e) purified phosphonium catalyst is recycled to the reaction zone, optionally in combination with another part of the stream containing used phosphonium catalyst.
摘要翻译：在鏻催化剂存在下，通过烯化氧与二氧化碳的反应，在（a）将环氧烷，二氧化碳和鏻催化剂连续引入反应区的方法中，生成碳酸亚烷基酯，取出含有碳酸亚烃酯和使用的鏻催化剂的产物流，（b）将碳酸亚烷基酯和含有用过的鏻催化剂的料流与产物流分离，（c）将步骤（b）中分离的碳酸亚烃酯作为产物回收，（d）将含有二氧化鏻催化剂的物流的至少一部分进行纯化，以获得纯化的鏻催化剂，和（e）将纯化的鏻催化剂再循环至反应区，任选地与含有已用鏻催化剂的流的另一部分组合鏻催化剂。

8. 发明申请

WO2007025941A1 INTEGRATED PROCESS FOR THE PREPARATION OF A POLYESTER RESIN 审中-公开
标题翻译：用于制备聚酯树脂的一体化方法
公开(公告)号：WO2007025941A1
公开(公告)日：2007-03-08
申请号：PCT/EP2006/065708
申请日：2006-08-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert
发明人： VAN DER HEIDE, Evert
IPC分类号： C08G63/78 , C08G63/42 , C08G63/58 , C08L67/06
CPC分类号： C08G63/78 , C08G63/42 , C08G63/58 , C08L63/00 , C08L67/06 , C08L75/00 , Y02P20/125 , C08L2666/02
摘要： An integrated process for the preparation of a polyester resin, comprising the steps of (a) reacting an alkene with a suitable oxidant in the presence of an epoxidation catalyst to form an alkylene oxide, and (b) separating a crude alkylene oxide fraction comprising from 95% by weight to 99.95% by weight of alkylene oxide, and (c) reacting the crude alkylene oxide fraction with one or more compounds selected from the group consisting of dicarboxylic acids, dicarboxylic acid anhydrides and polyhydric alcohols to obtain a polyester resin.
摘要翻译：一种用于制备聚酯树脂的整合方法，包括以下步骤：（a）在环氧化催化剂存在下使烯烃与合适的氧化剂反应以形成环氧烷烃，和（b）将包含 95重量％至99.95重量％的烯化氧，和（c）使粗环氧烷馏分与一种或多种选自二羧酸，二羧酸酐和多元醇的化合物反应，得到聚酯树脂。

9. 发明申请

WO2006069991A3 INTEGRATED SEPARATION AND PREPARATION PROCESS 审中-公开
公开(公告)号：WO2006069991A3
公开(公告)日：2006-07-06
申请号：PCT/EP2005/057173
申请日：2005-12-27
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BUIJS, Andre , CHEWTER, Leslie, Andrew , HARMSEN, Gerrit, Jan , VAN DER HEIDE, Evert , MENARD, Jean-Francois , MULDER, Dominicus, Fredericus , SPIERING, Wouter
发明人： BUIJS, Andre , CHEWTER, Leslie, Andrew , HARMSEN, Gerrit, Jan , VAN DER HEIDE, Evert , MENARD, Jean-Francois , MULDER, Dominicus, Fredericus , SPIERING, Wouter
IPC分类号： B01D53/22 , B01D53/92 , C07C7/144 , C07C7/00 , C07C5/02 , C07C31/10 , C07C45/00
摘要： Integrated separation and preparation process comprising a gas separation process wherein a first component is separated from a mixture of components by diffusion of the first component through a porous partition into a stream of sweeping component; and a preparation process wherein the sweeping component is used as feed. Separation unit and device for use in such a process and industrial set-up for use in such a process.

10. 发明申请

WO2012088108A1 PROCESS FOR THE PRODUCTION OF ALCOHOLS FROM BIOMASS 审中-公开
标题翻译：生物质生产酒精的方法
公开(公告)号：WO2012088108A1
公开(公告)日：2012-06-28
申请号：PCT/US2011/066150
申请日：2011-12-20
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , CHHEDA, Juben Nemchand
发明人： VAN DER HEIDE, Evert , CHHEDA, Juben Nemchand
IPC分类号： C12P7/10
CPC分类号： C12P7/10 , C12P19/02 , C12P19/14 , C12P2201/00 , Y02E50/16
摘要： Alcohols useful as fuel compositions are produced from biomass by pretreating the biomass prior to hydrolysis and fermentation. In the pretreatment, the biomass is contacted with an aqueous solution containing a dilute acid with concentration of up to 10wt% producing a predigested stream containing an aqueous liquor that contains at least a portion of hemicelluloses and a residual biomass that contains celluloses and lignin; separating at least a portion of the aqueous liquor from the residual biomass providing an aqueous liquor stream and a pre-digested biomass stream; then contacting the pre-digested biomass stream with a cooking liquor containing at least one alkali selected from the group consisting of sodium hydroxide, sodium carbonate, sodium sulfide, potassium hydroxide, potassium carbonate, ammonium hydroxide, and mixtures thereof and water. A process that allows for higher recovery of carbohydrates and thereby increased yields is provided.
摘要翻译：可用作燃料组合物的醇通过在水解和发酵之前预处理生物质由生物质产生。在预处理中，生物质与含有浓度高达10重量％的稀酸的水溶液接触，产生含有含有至少一部分半纤维素和含有纤维素和木质素的残余生物质的含水液体的预消化流; 从剩余生物质中分离至少一部分含水液体，提供含水液体流和预消化的生物物流; 然后将预消化的生物物流与含有选自氢氧化钠，碳酸钠，硫化钠，氢氧化钾，碳酸钾，氢氧化铵及其混合物和水中的至少一种碱的蒸煮液接触。提供了允许碳水化合物更高回收率并由此提高收率的方法。

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