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1. 发明申请

WO2012156875A3 ALTERING A COMPOSITION AT A LOCATION ACCESSED THROUGH AN ELONGATE CONDUIT 审中-公开
标题翻译：通过一个最近的连接在一个位置改变一个组成
公开(公告)号：WO2012156875A3
公开(公告)日：2013-02-21
申请号：PCT/IB2012052334
申请日：2012-05-10
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , SCHLUMBERGER SEACO INC , HARTSHORNE ROBERT SETH , MEREDITH ANDREW , LAWRENCE NATHAN
发明人： HARTSHORNE ROBERT SETH , MEREDITH ANDREW , LAWRENCE NATHAN
IPC分类号： E21B43/22 , E21B43/20 , E21B49/00
CPC分类号： C09K8/58 , C09K8/685 , C09K8/805 , E21B41/00
摘要： A composition flowing along an elongate conduit to a location accessed by that conduit contains a precursor substance which, arriving at the location, is converted electrochemically to chemically reactive intermediate. This intermediate reacts with another constituent of the composition, thereby bringing about a change in the composition. The reactive intermediate may be a cross-linking agent for a polymeric constituent of the composition so that the electrochemical reaction and subsequent cross-linking increases the viscosity of the composition as it arrives at the location where it is required.
摘要翻译：沿着细长管道流动到由该管道接近的位置的组合物含有前体物质，其到达该位置时被电化学转化为化学反应中间体。该中间体与组合物的另一成分反应，从而导致组合物的变化。反应性中间体可以是用于组合物的聚合物组分的交联剂，使得当组合物到达需要的位置时，电化学反应和随后的交联增加了组合物的粘度。

2. 发明申请

WO2011064632A3 PREPARATION OF SETTING SLURRIES 审中-公开
标题翻译：定型流程的准备
公开(公告)号：WO2011064632A3
公开(公告)日：2011-11-17
申请号：PCT/IB2010002658
申请日：2010-10-15
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , SCHLUMBERGER SEACO INC , VIDICK BENOIT , HARTSHORNE ROBERT SETH , LAWRENCE NATHAN , JOHNSON CARL , MONTEIRO GLEN , WOODROW JONATHAN
发明人： VIDICK BENOIT , HARTSHORNE ROBERT SETH , LAWRENCE NATHAN , JOHNSON CARL , MONTEIRO GLEN , WOODROW JONATHAN
IPC分类号： E21B33/14
CPC分类号： E21B33/14 , C04B40/0032 , C09K8/467 , C04B28/02 , C04B40/0039 , C04B2103/22
摘要： When preparing a settable slurry such as a cement slurry for cementing an oil well, cement or other solid powder is mixed with water and a set retarder. In order to be able to run a convenient and rapid check on the concentration of retarder after dilution at the site of use, a tracer material is mixed with the retarder in known amount during manufacture. The tracer is chosen to enable its concentration to be determined analytically after dilution at the site of use, thereby providing a way to determine the concentration of set retarder after such dilution. The tracer may be a redox-active material and its concentration may be determined by voltammetry. Tracer may likewise be mixed with additives other than set retarder.
摘要翻译：当准备可固化的浆料如用于固井的水泥浆料时，水泥或其它固体粉末与水和凝结缓凝剂混合。为了能够在使用地点对稀释后的缓凝剂的浓度进行方便快捷的检查，在制造过程中将示踪物质与已知量的缓凝剂混合。选择示踪剂以使其浓度在稀释后在使用部位分析确定，从而提供一种确定稀释后凝固缓凝剂浓度的方法。示踪剂可以是氧化还原活性物质，其浓度可以通过伏安法测定。示踪剂同样可以与除阻滞剂之外的添加剂混合。

3. 发明申请

WO2010026456A2 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2010026456A2
公开(公告)日：2010-03-11
申请号：PCT/IB2009006637
申请日：2009-08-26
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , SCHLUMBERGER SEACO INC , ROBINSON KAY , LAWRENCE NATHAN , MEREDITH ANDREW
发明人： ROBINSON KAY , LAWRENCE NATHAN , MEREDITH ANDREW
IPC分类号： G01N27/26 , G01N27/74
CPC分类号： G01N33/24
摘要： The present invention provides an electrochemical sensor having a solid electrically conductive substrate and a compound immobilized thereon which has binding affinity for an analyte species to be detected and also displays electrochemical behaviour which is modified upon binding of that analyte species, so that binding of an analyte species can be detected by measuring electrochemical properties, such as by voltammetry. Desirably the immobilised compound contains both a first moiety with binding affinity for the analyte and a separate second moiety which is a redox system whose electrochemical oxidation/reduction properties become modified when the first moiety binds the analyte. The analyte binding moiety may be a diol or polyol and preferably is a sugar. The electrochemical sensor finds use in methods of analysing reservoir and process fluids, particularly at a subterranean location. The electrochemical sensor may be a component of a downhole tool, adapted for deployment downhole.
摘要翻译：本发明提供了一种电化学传感器，其具有固体导电基体和固定在其上的化合物，该化合物对待检测的分析物种类具有结合亲和力，并且还显示出在结合该分析物种类时被修饰的电化学行为，从而使分析物物种可以通过测量电化学性质，例如伏安法来检测。理想地，固定的化合物含有对分析物具有结合亲和力的第一部分和分离的第二部分，该第二部分是当第一部分结合分析物时其电化学氧化/还原性质被改变的氧化还原系统。分析物结合部分可以是二醇或多元醇，并且优选是糖。电化学传感器可用于分析储层和过程流体的方法，特别是在地下位置。电化学传感器可以是适用于井下部署的井下工具的部件。

4. 发明申请

WO2011070408A3 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2011070408A3
公开(公告)日：2011-10-27
申请号：PCT/IB2010002641
申请日：2010-10-14
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , SCHLUMBERGER SEACO INC , LAFITTE VALERIE , LAWRENCE NATHAN
发明人： LAFITTE VALERIE , LAWRENCE NATHAN
IPC分类号： G01N27/30 , E21B47/00 , G01N33/18
CPC分类号： G01N27/3335 , G01N33/18
摘要： An electrochemical sensor for the presence or concentration of an analyte has at least one electrode and at least one electrochemically active species able to undergo electrochemical reaction in response to electrical potential applied to the electrode, where the said reaction is modified by the presence of the analyte. This sensor has the novel characteristic that at least one said electrochemically active species is encapsulated within polymer particles. These particles are preferably formed from an amorphous polymer with a glass transition temperature above the temperature of the fluid to which the sensor is exposed. The encapsulating polymer protects the analyte species from degradation, but a small analyte such as a hydrogen or bisulfide ion can pass through the polymer and undergo reaction at the active species.
摘要翻译：用于分析物的存在或浓度的电化学传感器具有至少一个电极和至少一种电化学活性物质，所述电化学活性物质能够响应于施加到电极的电势而发生电化学反应，其中所述反应通过存在分析物。该传感器具有新颖的特征，即至少一种所述电化学活性物质被包封在聚合物颗粒内。这些颗粒优选由玻璃化转变温度高于传感器所暴露的流体温度的无定形聚合物形成。封装聚合物保护分析物物质免于降解，但小分析物如氢或二硫化物离子可穿过聚合物并在活性物质处发生反应。

5. 发明申请

WO2011073746A3 CALIBRATION OF ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器的校准
公开(公告)号：WO2011073746A3
公开(公告)日：2011-10-13
申请号：PCT/IB2010002747
申请日：2010-10-25
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , SCHLUMBERGER SEACO INC , LAWRENCE NATHAN
发明人： LAWRENCE NATHAN
IPC分类号： G01N27/26 , E21B47/00 , G01N33/18 , G01V3/18
CPC分类号： G01N27/4163 , G01N27/308
摘要： This invention is concerned with electrochemical methods of analysing a fluid for an analyte. It utilises a sensor comprising electrodes and a mediator compound capable of undergoing a cycle of oxidation and reduction in response to varying potential applied to the electrodes, where the compound is also able to undergo a portion of the cycle through chemical reaction with the analyte. As is already known, the sensor is used in a method in which the sensor and the fluid are brought into contact sufficiently for the analyte to react chemically with the mediator, and in a voltammetry procedure, potential is applied to the electrodes while observing current flow with sufficient time for reaction between the mediator compound and the analyte, for thereby observing the concentration of the analyte. The novel characteristic of this invention is a step of calibrating the sensor by applying a rapidly changing potential to the electrodes and observing current flow, the change of this potential and observation of current being sufficiently fast to allow and observe electrochemical oxidation and reduction of the mediator taking place independently of the concentration of analyte, thereby observing the concentration of the mediator compound. The rapid change of potential maybe provided by pulse voltammetry or square wave voltammetry.
摘要翻译：本发明涉及分析流体用于分析物的电化学方法。它利用包括电极和介体化合物的传感器，该介体能够响应于施加到电极上的变化的电势而发生氧化和还原循环，其中化合物还能够通过与分析物发生化学反应而经历循环的一部分。如已知的那样，传感器用于使传感器和流体充分接触以使分析物与介体化学反应的方法中，并且在伏安测量过程中，在观察电流的同时将电位施加到电极上具有足够的时间用于介体化合物和分析物之间的反应，从而观察分析物的浓度。本发明的新颖特征是通过向电极施加快速变化的电势并观察电流，校准传感器的步骤，该电势的变化和电流的观察足够快以允许和观察电化学氧化和介体的还原与分析物浓度无关地进行，从而观察介体化合物的浓度。可能由脉冲伏安法或方波伏安法提供电位的快速变化。

6. 发明申请

WO2012017306A4 ELECTROCHEMICAL SENSOR 审中-公开
公开(公告)号：WO2012017306A4
公开(公告)日：2012-07-05
申请号：PCT/IB2011001820
申请日：2011-08-04
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS LTD SHL , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES AND DEV LTD A BRITISH VIRGIN ISLANDS COMPANY , SCHLUMBERGER SEACO INC , LAWRENCE NATHAN , MEREDITH ANDREW
发明人： LAWRENCE NATHAN , MEREDITH ANDREW
IPC分类号： G01N27/30
CPC分类号： G01N27/302 , G01N27/4167
摘要： An electrochemical sensor for measuring an analyte in a fluid, the electrochemical sensor having a first working electrode that includes a redox species sensitive to the analyte to be measured and a second working electrode made from a conducting substrate absent the redox species. The electrochemical sensor being capable of operation so that electrochemical effects of active contaminants in the fluid can be removed/attenuated from electrochemical signals produced by the reduction/oxidation of the redox species in the presence of the analyte.

7. 发明申请

WO2012017306A3 ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2012017306A3
公开(公告)日：2012-05-24
申请号：PCT/IB2011001820
申请日：2011-08-04
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS LTD SHL , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES AND DEV LTD A BRITISH VIRGIN ISLANDS COMPANY , SCHLUMBERGER SEACO INC , LAWRENCE NATHAN , MEREDITH ANDREW
发明人： LAWRENCE NATHAN , MEREDITH ANDREW
IPC分类号： G01N27/30
CPC分类号： G01N27/302 , G01N27/4167
摘要： An electrochemical sensor for measuring an analyte in a fluid, the electrochemical sensor having a first working electrode that includes a redox species sensitive to the analyte to be measured and a second working electrode made from a conducting substrate absent the redox species. The electrochemical sensor being capable of operation so that electrochemical effects of active contaminants in the fluid can be removed/attenuated from electrochemical signals produced by the reduction/oxidation of the redox species in the presence of the analyte.
摘要翻译：一种用于测量流体中分析物的电化学传感器，该电化学传感器具有第一工作电极和第二工作电极，第一工作电极包括对待测分析物敏感的氧化还原物质，第二工作电极由缺少氧化还原物质的导电基底制成。电化学传感器能够操作，使得流体中活性污染物的电化学效应可以从在分析物存在下由氧化还原物质的还原/氧化产生的电化学信号中去除/衰减。

8. 发明申请

WO2010001082A8 ELECTROCHEMICAL SENSOR UTILISING A DUAL REDOX SYSTEM CONTAINED WITHIN A SINGLE MOLECULE 审中-公开
标题翻译：电化学传感器应用于单分子含有的双重氧化还原系统
公开(公告)号：WO2010001082A8
公开(公告)日：2011-03-31
申请号：PCT/GB2009001101
申请日：2009-05-01
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES & DEV LTD , LAFITTE VALERIE , LAWRENCE NATHAN
发明人： LAFITTE VALERIE , LAWRENCE NATHAN
IPC分类号： G01N27/403 , G01N27/416
CPC分类号： G01N27/48
摘要： An electrochemical sensor utilises a chemical compound which is not a macromolecule but rather is a single chemical compound of determinate structure, incorporating two redox systems which differ in their response to a species to be detected. In one form, one redox system displays a voltammetric wave which is pH dependent while another displays a voltammetric wave which is pH independent and acts as an internal reference. The sensor comprises a solid substrate, which may be carbonaceous, on which the compound is immobilized. The sensor may be incorporated into a tool to be suspended in a wellbore.
摘要翻译：电化学传感器利用不是大分子的化合物，而是具有确定结构的单一化学化合物，其结合了两种不同于待检测物种的氧化还原体系。在一种形式中，一种氧化还原系统显示pH依赖性的伏安波，而另一种显示与pH无关的伏安波，并作为内部参考。传感器包括固体基质，其可以是碳质的，化合物固定在其上。传感器可以结合到工具中以悬挂在井眼中。

9. 发明申请

WO2010106404A3 DERIVATISATION OF CARBON 审中-公开
标题翻译：碳的衍生物
公开(公告)号：WO2010106404A3
公开(公告)日：2011-01-20
申请号：PCT/IB2010000293
申请日：2010-02-12
申请人： SCHLUMBERGER TECHNOLOGY BV , SCHLUMBERGER HOLDINGS , SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , PRAD RES AND DEV LTD A BRITISH VIRGIN ISLANDS COMPANY , SCHLUMBERGER SEACO INC , ZOU FENGLOU , LAWRENCE NATHAN , JONES TIMOTHY
发明人： ZOU FENGLOU , LAWRENCE NATHAN , JONES TIMOTHY
IPC分类号： C01B31/02 , B82B3/00 , C01B31/04
CPC分类号： C07C201/12 , B82Y30/00 , B82Y40/00 , C01B31/0273 , C01B31/04 , C01B32/156 , C01B32/174 , C01B32/194 , C01B32/20 , C01B32/21 , C01B32/28 , C01B32/354 , G01N27/308
摘要： A molecular species is covalently attached to elemental carbon by exposing the carbon to a reaction mixture containing a strong base and a compound of the formula (I) or (II) in which X denotes a covalently attached atom or group capable of forming an X- anion and each Z is a moiety comprising a plurality of atoms, but which does not have a hydrogen atom directly attached to the atom which itself is directly attached to the -CH2X or -CHX group. The carbon substrate may be graphite or carbon nanotubes.
摘要翻译：通过将碳暴露于含有强碱和式（I）或（II）的化合物的反应混合物中，分子物质共价连接到元素碳上，其中X表示共价连接的原子或能够形成X- 阴离子，每个Z是包含多个原子的部分，但不具有与本身直接连接到-CH 2 X或-CHX基团的原子直接相连的氢原子。碳衬底可以是石墨或碳纳米管。

10. 发明申请

WO2016048655A9 TEMPERATURE INVARIANT INFRARED FILTER 审中-公开
标题翻译：温度不变的红外滤光片
公开(公告)号：WO2016048655A9
公开(公告)日：2016-05-19
申请号：PCT/US2015049094
申请日：2015-09-09
申请人： SCHLUMBERGER CA LTD , SCHLUMBERGER SERVICES PETROL , SCHLUMBERGER HOLDINGS , SCHLUMBERGER TECHNOLOGY BV , PRAD RES & DEV LTD , SCHLUMBERGER TECHNOLOGY CORP , READING UNIVERSITY
发明人： JONES TIMOTHY , LAWRENCE NATHAN , HAWKINS GARY
IPC分类号： G02B5/20
CPC分类号： G02B5/285 , G01N33/2823
摘要： A narrow bandpass filter that may be used in a mid-infrared sensor for monitoring a species, which may be a component of a fluid or a solid material. The filter comprises a cavity comprising a low refractive index material. By providing a high ratio of low refractive index material in the filter with respective to high refractive index material, the filter is configured so that wavelength transmission remains constant with varying temperature. Materials used for the low and/or high refractive index provide a temperature invariant filter that transmits mid-infrared spectra without serious degradation.
摘要翻译：一种窄带通滤光片，可用于中红外传感器，用于监测物质，可能是流体或固体物质的组成部分。滤光器包括包含低折射率材料的腔。通过在滤光器中提供相对于高折射率材料的高折射率材料的高比率，滤波器被配置为使得随着温度变化波长传输保持恒定。用于低折射率和/或高折射率的材料提供温度不变过滤器，其透射中红外光谱而没有严重降解。

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