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    • 5. 发明申请
    • CONTROLLING GEL TIMES OF REMEDIAL AQUEOUS RESIN COMPOSITIONS FOR SEALING OFF FLOW CHANNELS
    • 控制密封水凝胶组合物胶凝时间来封闭流动通道
    • WO2018085402A1
    • 2018-05-11
    • PCT/US2017/059534
    • 2017-11-01
    • SAUDI ARABIAN OIL COMPANYARAMCO SERVICES COMPANY
    • REDDY, B. RaghavaHILFIGER, Matthew Gary
    • C09K8/44C09K8/508C09K8/512C08L35/00
    • Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gel time control agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV, where each R 1 is independently -H, -O(C 1 -C 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 2 is independently-H, -O(C 1 - 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 3 is independently -OH or -O-M 1 , each M 1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R 4 is independently-NH2 or -OM 1 . The gel time control agent accelerates or retards formation of a gel from the composition compared to a composition having the same percentage by weight of the maleic anhydride copolymer and the amine crosslinker in the absence of the gel time control agent.
    • 用包含马来酸酐共聚物,胺交联剂和凝胶时间控制剂的组合物处理地下地层。 马来酸酐共聚物包括第一重复单元I和II以及第二重复单元III和IV中的至少一个,其中每个R 1独立地为-H,-O(C≡1) (C 1 -C 5)烷基或 - (C 1 -C 5)烷基; 每个R 2独立地为-H,-O(C 1〜5) - 烷基或 - (C 1〜 (C 1 -C 5)烷基; 每个R 3独立地为-OH或-OM 1,每个M 1独立地为碱金属,碱土金属,铵离子 ,或季铵离子; 并且每个R 4独立地为-NH 2或-OM 1。 与不含凝胶时间控制剂的马来酸酐共聚物和胺交联剂的重量百分比相同的组合物相比,凝胶时间控制剂加速或延迟了组合物形成凝胶。
    • 8. 发明申请
    • COMPOSITIONS AND METHODS FOR SEALING OFF FLOW CHANNELS IN CONTACT WITH SET CEMENT
    • 用于密封与集料水泥接触的流动通道的组合物和方法
    • WO2018085405A1
    • 2018-05-11
    • PCT/US2017/059539
    • 2017-11-01
    • SAUDI ARABIAN OIL COMPANYARAMCO SERVICES COMPANY
    • REDDY, B. RaghavaHILFIGER, Matthew Gary
    • C09K8/512C09K8/42
    • Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gelling agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R 1 is independently-H, -(XC 1 -C 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 2 is independently-H, -0(C 1 -C 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 3 is independently -OH or -O - M 1 , each M 1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently-NH 2 or -OM 1 . The gelling agent includes at least one of: a calcium chelating agent, a calcium precipitating agent, a pH buffer, an agent reactive with hydroxide, and an acid generating agent, and promotes formation of a gel from the maleic anhydride copolymer and the amine crosslinker in contact with set cement.
    • 用包含马来酸酐共聚物,胺交联剂和胶凝剂的组合物处理地下地层。 马来酸酐共聚物包括第一重复单元I和II以及第二重复单元III和IV中的至少一个:其中每个R 1独立地为-H, - (XC 1) (C 1 -C 5)烷基或 - (C 1 -C 5)烷基; 每个R 2独立地为-H,-O(C 1 -C 5)烷基或 - (C 1 -C 1) (C 1 -C 5)烷基; 每个R 3独立地为-OH或-O-M 1,每个M 1独立地为碱金属 ,碱土金属,铵离子或季铵离子; 并且每个R 4独立地是-NH 2或-OM 1。 胶凝剂包括钙螯合剂,钙沉淀剂,pH缓冲剂,与氢氧化物反应的试剂和酸生成剂中的至少一种,并促进由马来酸酐共聚物和胺交联剂形成凝胶 与固定水泥接触。
    • 9. 发明申请
    • WATER-BASED SEALING COMPOSITIONS WITH AMINOSILANE CROSSLINKERS
    • 含氨基硅烷交联剂的水基密封组合物
    • WO2018085404A1
    • 2018-05-11
    • PCT/US2017/059537
    • 2017-11-01
    • SAUDI ARABIAN OIL COMPANYARAMCO SERVICES COMPANY
    • REDDY, B. RaghavaHILFIGER, Matthew Gary
    • C09K8/44C09K8/508C09K8/512C08L35/00
    • Treating a subterranean formation with a composition including a maleic anhydride copolymer and an aminosilane crosslinker. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV, where each R 1 is independently -H, -O(C 1 -C? 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 2 is independently-H, -O(C 1 -C 5 ) alkyl, or -(C 1 -C 5 ) alkyl; each R 3 is independently -OH or -O-M 1 , each M 1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R 4 is independently-NH 2 or -OM 1 . The aminosilane crosslinker has at least one primary amine group. Siloxane bonds may be formed between the aminosilane crosslinker and a siliceous material in contact with the gelled composition in the subterranean formation.
    • 用包含马来酸酐共聚物和氨基硅烷交联剂的组合物处理地下地层。 马来酸酐共聚物包括第一重复单元I和II以及第二重复单元III和IV中的至少一个,其中每个R 1独立地为-H,-O(C≡1) (C 1 -C 5)烷基或 - (C 1 -C 5)烷基; 每个R 2独立地为-H,-O(C 1 -C 5)烷基或 - (C 1 -C 4) (C 1 -C 5)烷基; 每个R 3独立地为-OH或-OM 1,每个M 1独立地为碱金属,碱土金属,铵离子 ,或季铵离子; 并且每个R 4独立地为-NH 2或-OM 1。 氨基硅烷交联剂具有至少一个伯胺基团。 硅氧烷键可以在氨基硅烷交联剂和与地下地层中胶凝组合物接触的硅质材料之间形成。