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1. 发明申请

WO2012095744A2 PROCESS FOR THE HYDRATION OF MIXED BUTENES TO PRODUCE MIXED ALCOHOLS 审中-公开
标题翻译：混合丁基水解生产混合醇的方法
公开(公告)号：WO2012095744A2
公开(公告)日：2012-07-19
申请号：PCT/IB2012000145
申请日：2012-01-09
申请人： SAUDI ARABIAN OIL CO , ARAMCO SERVICES CO , XU WEI , AL-SHAHRANI FARHAN M , BOURANE ABDENNOUR , VOGEL STEPHAN RALF
发明人： XU WEI , AL-SHAHRANI FARHAN M , BOURANE ABDENNOUR , VOGEL STEPHAN RALF
IPC分类号： C07C29/04 , C07C31/12 , C10L1/182
CPC分类号： C07C29/04 , C07C31/10 , C10G50/00 , C10L1/143 , C10L1/1641 , C10L1/1691 , C10L1/1817 , C10L1/1824 , C10L1/1852 , C10L10/10 , C07C31/12
摘要： Mixed butenes from a cracking process, or raffinates of MTBE or tert-butyl alcohol (TBA), are simultaneously hydrated using water in the presence of a catalyst to produce sec-butyl alcohol (SBA) and ter-butyl alcohol as the principal products, the mixed butanols having utility as fuel additives, e.g., as oxygenates and octane enhancers to replace MTBE, and as a neat fuel.
摘要翻译：来自裂化工艺的混合丁烯或MTBE或叔丁醇（TBA）的提余液在催化剂存在下使用水同时水合以产生仲丁醇（SBA）和叔丁醇作为主要产物，混合的丁醇具有用作燃料添加剂的用途，例如用作含氧化合物和辛烷增强剂以替代MTBE，并且用作纯净燃料。

2. 发明申请

WO2012082685A3 INTEGRATED DESULFURIZATION AND DENITRIFICATION PROCESS INCLUDING MILD HYDROTREATING AND OXIDATION OF AROMATIC-RICH HYDROTREATED PRODUCTS 审中-公开
标题翻译：综合脱硫和脱硫工艺，包括加氢处理和氧化芳香族氢化产物的加氢脱硫
公开(公告)号：WO2012082685A3
公开(公告)日：2014-01-03
申请号：PCT/US2011064543
申请日：2011-12-13
申请人： SAUDI ARABIAN OIL CO , KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
发明人： KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
IPC分类号： C10G45/00
CPC分类号： C10G45/22 , B01J19/006 , B01J19/18 , B01J2219/00768 , B01J2219/00777 , C10G21/00 , C10G21/16 , C10G21/20 , C10G21/27 , C10G27/04 , C10G27/12 , C10G27/14 , C10G45/02 , C10G53/04 , C10G53/14 , C10G67/04 , C10G67/0418 , C10G67/12 , C10G67/14 , C10G2300/1096 , C10G2300/202 , C10G2300/44
摘要： Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur- containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.
摘要翻译：通过在温和条件下操作的加氢处理反应区中首先使整个进料与加氢处理催化剂接触，以使不稳定的有机硫和有机氮化合物转化，从而进一步从烃进料中还原含硫和含氮化合物。在加氢处理反应区下游的萃取区分离富含芳烃的级分，其中含有大量剩余的难熔有机硫和有机氮化合物。芳香族贫馏分基本上不含有机硫和有机氮化合物，因为非芳族有机硫和有机氮化合物是不稳定的有机硫和有机氮化合物，最初通过轻度加氢处理除去。将富含芳烃的馏分氧化，将难熔有机硫和有机氮化合物转化为氧化的含硫和含氮烃化合物。随后除去这些氧化的有机硫和有机氮化合物。

3. 发明申请

WO2012082684A3 INTEGRATED DESULFURIZATION AND DENITRIFICATION PROCESS INCLUDING MILD HYDROTREATING OF AROMATIC-LEAN FRACTION 审中-公开
标题翻译：综合脱硫和脱水过程，包括芳族化合物水解加氢
公开(公告)号：WO2012082684A3
公开(公告)日：2014-01-03
申请号：PCT/US2011064542
申请日：2011-12-13
申请人： SAUDI ARABIAN OIL CO , KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
发明人： KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
IPC分类号： C10G45/00
CPC分类号： C10G45/22 , B01J19/006 , B01J19/18 , B01J2219/00768 , B01J2219/00777 , C10G21/00 , C10G21/16 , C10G21/20 , C10G21/27 , C10G27/04 , C10G27/12 , C10G27/14 , C10G45/02 , C10G67/0418 , C10G67/12 , C10G67/14 , C10G2300/1096 , C10G2300/202 , C10G2300/44
摘要： Deep desulfurization of hydrocarbon feeds containing undesired organosulfur and organonitrogen compounds to produce a hydrocarbon product having low levels of sulfur-containing and nitrogen-containing compounds, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the refractory organosulfur and organonitrogen compounds and an aromatic-lean fraction containing a substantial amount of the labile organosulfur and organonitrogen compounds. The aromatic-lean fraction is contacted with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized organosulfur and organonitrogen compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed, producing a stream containing reduced levels of organosulfur and organonitrogen compounds.
摘要翻译：通过首先使整个进料进入萃取区，分离含有富含烯烃的富含芳烃的馏分，从而实现含有不需要的有机硫和有机氮化合物的烃进料的深度脱硫以产生具有低含量含硫和含氮化合物的烃产物大量的难熔有机硫和有机氮化合物和含有大量不稳定有机硫和有机氮化合物的芳族贫乏馏分。将芳族贫馏分与在温和条件下操作的加氢处理反应区中的加氢处理催化剂接触以转化不稳定的有机硫和有机氮化合物。富含芳烃的级分被氧化，将难熔有机硫和有机氮化合物转化为氧化有机硫和有机氮化合物。随后除去这些氧化的有机硫和有机氮化合物，产生含有降低水平的有机硫和有机氮化合物的物流。

4. 发明申请

WO2007103440A2 CATALYTIC PROCESS FOR DEEP OXIDATIVE DESULFURIZATION OF LIQUID TRANSPORTATION FUELS 审中-公开
标题翻译：液体输送燃料的深度氧化脱硫的催化方法
公开(公告)号：WO2007103440A2
公开(公告)日：2007-09-13
申请号：PCT/US2007005838
申请日：2007-03-05
申请人： SAUDI ARABIAN OIL CO , AL-SHAHRANI FARHAN M , XIAO TIANCUN , MARTINIE GARY D , GREEN MALCOLM L H
发明人： AL-SHAHRANI FARHAN M , XIAO TIANCUN , MARTINIE GARY D , GREEN MALCOLM L H
IPC分类号： C12N9/74
CPC分类号： C10G27/12 , C10G17/02 , C10G53/04 , C10G53/14 , C10G2400/04
摘要： Sulfur-containing compounds, including specifically thiophenic compounds, in a liquid hydrocarbon feedstream are catalytically oxidized by combining the hydrocarbon feedstream with a catalytic reaction mixture that includes a peroxide that is soluble in water or in a polar organic acid, at least one carboxylic acid, and a catalyst that is a transition metal salt selected from the group consisting of (NH 4 ) 2 WO 4 , (NH 4 ) 6 W 12 O 40 . H 2 O, Na 2 WO 4 , Li 2 WO 4 , K 2 WO 4 , MgWO 4 , (NH 4 ) 2 MoO 4 , (NH 4 ) 6 Mo 7 O 24 . 4H 2 O, MnO 0 and NaVO 3 ; the mixture is vigorously agitated for a time that is sufficient to oxidize the sulfur-containing compounds to form sulfoxides and sulfones; the reaction mixture is allowed to stand and separate into a lower aqueous layer containing the catalyst and an upper hydrocarbon layer that is recovered and from which the oxidized sulfur compounds are removed, as by solvent extraction, distillation or selective adsorption. The process can be used to reduce the sulfur content of liquid transportation fuels to 10 ppm, or less.
摘要翻译：通过将烃进料流与包含可溶于水或极性有机酸中的过氧化物的催化反应混合物，至少一种羧酸，或至少一种羧酸混合，催化氧化液态烃进料流中的含硫化合物，特别包括噻吩化合物，和作为选自（NH 4）4，过渡金属盐（NH 4），（NH 4，）_{6 W _{12 O _{40 。 H _{2 _{2 _{2 _{4 _{4 ，Li _{2 WO _{4 ，K 2，4，4，4，4，4，4，4，5，4， > 4 ，（NH _{4 ）_{6 Mo _{7 0 _{24 。 4H 2 O，MnO 0和NaVO 3; 剧烈搅拌该混合物一段足以氧化含硫化合物以形成亚砜和砜的时间; 通过溶剂萃取，蒸馏或选择性吸附将反应混合物静置并分离成含有催化剂和回收的上层烃层的下层水层，并从中除去氧化的硫化合物。该过程可用于将液体运输燃料的硫含量降至10 ppm或更低。}}}}}}}}}}}}}}

5. 发明申请

WO2007030229A2 DIESEL OIL DESULFURIZATION BY OXIDATION AND EXTRACTION 审中-公开
标题翻译：柴油机通过氧化和萃取除油
公开(公告)号：WO2007030229A2
公开(公告)日：2007-03-15
申请号：PCT/US2006029574
申请日：2006-07-28
申请人： SAUDI ARABIAN OIL CO , MARTINIE GARY D , AL-SHAHRANI FARHAN M , DABBOUSI BASHIR O
发明人： MARTINIE GARY D , AL-SHAHRANI FARHAN M , DABBOUSI BASHIR O
IPC分类号： C10G45/00 , C10G17/00
CPC分类号： C10G27/00 , C10G21/16 , C10G21/20 , C10G25/003 , C10G27/10 , C10G27/12 , C10G2300/1055 , C10G2300/202 , C10G2300/4006 , C10G2300/44 , C10G2400/04 , C10L1/08
摘要： The reduction in the sulfur-containing content of diesel fuel is achieved by oxidation in the presence of a catalyst followed by a liquid-liquid countercurrent extraction.
摘要翻译：柴油的含硫含量的降低通过在催化剂存在下进行氧化，然后进行液 - 液逆流萃取来实现。

6. 发明申请

WO2005066313A2 REACTIVE EXTRACTION OF SULFUR COMPOUNDS FROM HYDROCARBON STREAMS 审中-公开
标题翻译：从烃类烃中反应萃取硫化合物
公开(公告)号：WO2005066313A2
公开(公告)日：2005-07-21
申请号：PCT/US2004043718
申请日：2004-12-22
申请人： SAUDI ARABIAN OIL CO , MARTINIE GARY DEAN , AL-SHAHRANI FARHAN M
发明人： MARTINIE GARY DEAN , AL-SHAHRANI FARHAN M
IPC分类号： C10G5/04 , C10G21/02 , C10G21/06 , C10G21/18 , C10G29/06
CPC分类号： C10G21/08 , C10G21/06 , C10G29/06 , C10L3/10
摘要： A process to substantially reduce the sulfur content of a liquid hydrocarbon stream by contacting the hydrocarbon stream with an aqueous stream containing a mixture of one or more extraction agents selected from hypochlorites, cyanurates and alkali metal and alkaline earth metal hydroxides, optionally in the presence of a catalyst, to remove sulfur compounds.
摘要翻译：通过使烃流与含有选自次氯酸盐，氰尿酸盐和碱金属和碱土金属氢氧化物的一种或多种萃取剂的混合物的含水物流接触，显着降低液态烃物流的硫含量的方法，任选地在一种催化剂，去除硫化合物。

7. 发明专利

CA2662627C CATALYTIC PROCESS FOR DEEP OXIDATIVE DESULFURIZATION OF LIQUID TRANSPORTATION FUELS 未知
公开(公告)号：CA2662627C
公开(公告)日：2013-04-30
申请号：CA2662627
申请日：2007-03-05
申请人： SAUDI ARABIAN OIL CO , UNIV OXFORD
发明人： AL-SHAHRANI FARHAN M , XIAO TIANCUN , MARTINIE GARY D , GREEN MALCOLM L H
IPC分类号： C10G27/12 , B01J23/22 , B01J23/28 , B01J23/30
摘要： Sulfur-containing compounds, including specifically thiophenic compounds, in a liquid hydrocarbon feedstream are catalytically oxidized by combining the hydrocarbon feedstream with a catalytic reaction mixture that includes a peroxide that is soluble in water or in a polar organic acid, at least one carboxylic acid, and a catalyst that is a transition metal salt selected from the group consisting of (NH4)2WO4, (NH4)6 W12O40. H2O, Na2WO4, Li2WO4, K2WO4, MgWO4, (NH4)2MoO4, (NH4)6 Mo7O24. 4H2O, MnO0 and NaVO3; the mixture is vigorously agitated for a time that is sufficient to oxidize the sulfur-containing compounds to form sulfoxides and sulfones; the reaction mixture is allowed to stand and separate into a lower aqueous layer containing the catalyst and an upper hydrocarbon layer that is recovered and from which the oxidized sulfur compounds are removed, as by solvent extraction, distillation or selective adsorption. The process can be used to reduce the sulfur content of liquid transportation fuels to 10 ppm, or less.

8. 发明专利

EA016125B1 ОБЕССЕРИВАНИЕ ДИЗЕЛЬНОГО ТОПЛИВА С ИСПОЛЬЗОВАНИЕМ ОКИСЛЕНИЯ И ЭКСТРАКЦИИ 未知
公开(公告)号：EA016125B1
公开(公告)日：2012-02-28
申请号：EA200800771
申请日：2006-07-28
申请人： SAUDI ARABIAN OIL CO
发明人： MARTINIE GARY D , AL-SHAHRANI FARHAN M , DABBOUSI BASHIR O
IPC分类号： C10G29/22 , C07C7/08 , C10G45/00
摘要： Изобретениеотноситсяк снижениюсеросодержащегосодержимогодизельноготоплива, котороеосуществляетсяокислениемв присутствиикатализаторас последующейжидкостно-жидкостнойпротивоточнойэкстракцией.

9. 发明专利

CA2662627A1 CATALYTIC PROCESS FOR DEEP OXIDATIVE DESULFURIZATION OF LIQUID TRANSPORTATION FUELS 未知
公开(公告)号：CA2662627A1
公开(公告)日：2007-09-13
申请号：CA2662627
申请日：2007-03-05
申请人： SAUDI ARABIAN OIL CO , UNIV OXFORD
发明人： AL-SHAHRANI FARHAN M , GREEN MALCOLM L H , MARTINIE GARY D , XIAO TIANCUN
IPC分类号： C10G27/12 , B01J23/22 , B01J23/28 , B01J23/30
摘要： Sulfur-containing compounds, including specifically thiophenic compounds, in a liquid hydrocarbon feedstream are catalytically oxidized by combining the hydrocarbon feedstream with a catalytic reaction mixture that includes a peroxide that is soluble in water or in a polar organic acid, at least one carboxylic acid, and a catalyst that is a transition metal salt selected fro m the group consisting of (NH4)2WO4, (NH4)6 W12O40. H2O, Na2WO4, Li2WO4, K2W O4, MgWO4, (NH4)2MoO4, (NH4)6 Mo7O24. 4H2O, MnO0 and NaVO3; the mixture is v igorously agitated for a time that is sufficient to oxidize the sulfur-conta ining compounds to form sulfoxides and sulfones; the reaction mixture is all owed to stand and separate into a lower aqueous layer containing the catalys t and an upper hydrocarbon layer that is recovered and from which the oxidiz ed sulfur compounds are removed, as by solvent extraction, distillation or s elective adsorption. The process can be used to reduce the sulfur content of liquid transportation fuels to 10 ppm, or less.

10. 发明公开

EP2496538A4 HYDROCARBON RECOVERY FROM SULFONES FORMED BY OXIDATIVE DESULFURIZATION PROCESS 审中-公开
标题翻译：烃采收由氧化脱硫形砜
公开(公告)号：EP2496538A4
公开(公告)日：2013-04-24
申请号：EP10829070
申请日：2010-11-04
申请人： SAUDI ARABIAN OIL CO , UNIV OXFORD
发明人： AL-SHAHRANI FARHAN M , XIAO TIANCUN , SHI HUAHONG , GREEN MALCOLM L H
IPC分类号： C07C37/01 , C07C39/15
CPC分类号： C07C37/01 , C07C39/15
摘要： The process provided herein is concerned with recovery of hydrocarbons from sulfones using an individual alkali and alkaline-earthy base and a mixture of thereof. As the starting materials are sulfones generated by ODS and commercially inexpensive alkali and alkaline-earth bases, the cost and ecological impact of solid waste disposal is minimized.

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