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    • 4. 发明专利
    • BRPI0612444A2
    • 2010-11-23
    • BRPI0612444
    • 2006-05-12
    • SAUDI ARABIAN OIL CO
    • MARTINIE GARY DAL-SHAHRANI FAHRAN MDABBOUSI BASHIR O
    • C02F1/461
    • A continuous method for the treatment of a spent aqueous caustic stream used to scrub a hydrocarbon process stream to remove oxidizable sulfur-containing compounds includes: a. mixing an oxidizing hypochlorous acid stream produced from an aqueous brine solution with the aqueous caustic stream to form a reactive mixed feedstream; b. contacting the reactive mixed feedstream with at least one catalyst to promote the oxidation of the sulfur-containing compounds and the neutralization of the sodium hydroxide; and c. recovering a neutral treated product stream comprising aqueous sodium sulfate, sodium carbonate and sodium chloride that is odorless, non-toxic and environmentally acceptable for discharge into the sea or into a conventional sewage treatment system. Preferably, the hypochlorous acid is produced by an electrolyzer that also produces a (1) hydrogen stream that is directed to a PEM fuel cell to generate at least a portion of the electrical power requirement of the electrolyzer, and (2) water that is combined with fresh sodium hydroxide from the electrolyzer to form a fresh caustic stream for use in scrubbing the hydrocarbon process stream.
    • 8. 发明专利
    • NO20075881L
    • 2008-02-11
    • NO20075881
    • 2007-11-15
    • SAUDI ARABIAN OIL CO
    • AL-SHAHRANI FAHRAN MDABBOUSI BASHIR O
    • C02F1/467C02F1/72
    • A continuous method for the treatment of a spent aqueous caustic stream used to scrub a hydrocarbon process stream to remove oxidizable sulfur-containing compounds includes: a. mixing an oxidizing hypochlorous acid stream produced from an aqueous brine solution with the aqueous caustic stream to form a reactive mixed feedstream; b. contacting the reactive mixed feedstream with at least one catalyst to promote the oxidation of the sulfur-containing compounds and the neutralization of the sodium hydroxide; and c. recovering a neutral treated product stream comprising aqueous sodium sulfate, sodium carbonate and sodium chloride that is odorless, non-toxic and environmentally acceptable for discharge into the sea or into a conventional sewage treatment system. Preferably, the hypochlorous acid is produced by an electrolyzer that also produces a (1) hydrogen stream that is directed to a PEM fuel cell to generate at least a portion of the electrical power requirement of the electrolyzer, and (2) water that is combined with fresh sodium hydroxide from the electrolyzer to form a fresh caustic stream for use in scrubbing the hydrocarbon process stream.