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    • 7. 发明申请
    • METHOD FOR CONTROLLING NOx REDUCTION SYSTEM
    • 控制NOx还原系统的方法
    • US20090308054A1
    • 2009-12-17
    • US12375315
    • 2007-07-30
    • Naohiro SatohOsami YamamotoKoichi InabaHiroshi Ohno
    • Naohiro SatohOsami YamamotoKoichi InabaHiroshi Ohno
    • F02D41/00F01N3/10
    • B01D53/9422B01D2255/10B01D2255/2065B01D2255/20738B01D2255/9022B01J23/63B01J37/0244B01J37/0246F01N3/0814F01N3/0842F01N3/0864F01N3/2073F01N2240/25F01N2510/0684F01N2570/18F02B37/00Y02A50/2325Y02T10/22Y02T10/24
    • To provide a method for controlling a NOx reduction system which can remove NOx with a satisfactorily high efficiency even under low-temperature operating conditions as in diesel cars. The NOx reduction system comprises NOx treatment means disposed in an exhaust passage in an internal combustion engine, and air-fuel ratio control means for bringing the air-fuel ratio of an exhaust gas to a lean or rich state. The NOx treatment means comprises at least a first catalyst layer containing a solid acid catalyst capable of adsorbing ammonia and a second catalyst layer containing a noble metal and a cerium oxide material. The second catalyst layer and the first catalyst layer are stacked in that order on a carrier, and the first catalyst layer constitutes the uppermost layer. The air-fuel ratio control means controls so that the lean state and the rich state are repeated at predetermined intervals. According to the above constitution, NOx is passed through the first catalyst layer in the lean state and is temporarily stored in the second catalyst layer. Thereafter, in the rich state, NOx is converted to NH3 and is restored in the first catalyst layer. When the state is again returned to the lean state, NH3 is converted to nitrogen which is finally released from the first catalyst layer.
    • 提供一种用于控制NOx还原系统的方法,其可以在如柴油车辆中的低温操作条件下以令人满意的高效率除去NOx。 NOx还原系统包括设置在内燃机的排气通道中的NOx处理装置,以及用于使排气的空燃比变为稀薄或浓缩状态的空燃比控制装置。 NOx处理装置至少包括含有能够吸附氨的固体酸催化剂的第一催化剂层和含有贵金属和氧化铈材料的第二催化剂层。 第二催化剂层和第一催化剂层依次层叠在载体上,第一催化剂层构成最上层。 空燃比控制装置进行控制,使得以预定间隔重复稀薄状态和浓气状态。 根据上述结构,NOx以贫态通过第一催化剂层,暂时保存在第二催化剂层中。 此后,在富状态下,将NOx转化为NH 3并在第一催化剂层中恢复。 当状态再次返回到贫态时,NH 3转化为最终从第一催化剂层释放的氮。