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    • 1. 发明申请
    • Process for Producing Thick-Film Tape-Shaped Re-Type (123) Superconductor
    • 生产厚膜带状再型(123)超导体的工艺
    • US20090286686A1
    • 2009-11-19
    • US12086294
    • 2006-12-07
    • Ryo TeranishiYuji AokiJunko MatsudaKoichi NakaokaTeruo IzumiYuh Shiohara
    • Ryo TeranishiYuji AokiJunko MatsudaKoichi NakaokaTeruo IzumiYuh Shiohara
    • H01L39/24
    • H01L39/2451
    • This invention provides a production process of a thick-film tape-shaped RE-type (123) superconductor having a high critical current value. The production process comprises providing a composite substrate comprising Gd2Zr2O7 and CeO2 stacked in that order onto a Hastelloy substrate, coating a raw material solution prepared by dissolving a trifluoroacetate of Y and Ba and a naphthenate of Cu onto the composite substrate, heat treating the coated composite substrate by calcination, then subjecting the calcined assembly to intermediate heat-treatment at a temperature below the temperature of heat-treatment for superconductor production, and then heat treating the assembly in an argon gas atmosphere under conditions of highest heating temperature 760° C., water vapor partial pressure 13.5%, and oxygen partial pressure 0.09% for superconductor production to produce a tape-shaped RE-type (123) superconductor comprising a YBCO superconducting film having a thickness of more than about 2 μm.
    • 本发明提供具有高临界电流值的厚膜带状RE型(123)超导体的制造方法。 制造方法包括:将包含Gd 2 Zr 2 O 7和CeO 2的复合基板依次层叠在Hastelloy基板上,涂布通过将Y和Ba的三氟乙酸盐和Cu的环烷酸盐溶解在复合基板上而制备的原料溶液, 通过煅烧,然后在低于制备超导体的热处理温度的温度下对煅烧组件进行中间热处理,然后在氩气气氛中在最高加热温度760℃的条件下热处理该组件, 水蒸汽分压为13.5%,氧分压为0.09%,生产超薄膜超薄膜的带状RE型(123)超导体,超导体的厚度大于2μm。
    • 2. 发明授权
    • Process for producing thick-film tape-shaped re-type (123) superconductor
    • 生产厚膜带状再型(123)超导体的方法
    • US08409657B2
    • 2013-04-02
    • US12086294
    • 2006-12-07
    • Ryo TeranishiYuji AokiJunko MatsudaKoichi NakaokaTeruo IzumiYuh Shiohara
    • Ryo TeranishiYuji AokiJunko MatsudaKoichi NakaokaTeruo IzumiYuh Shiohara
    • B05D5/12H01L39/24
    • H01L39/2451
    • A production process of a thick-film tape-shaped RE-type (123) superconductor having a high critical current value. The production process has the steps of providing a composite substrate having Gd2Zr2O7 and CeO2 stacked in that order onto a Hastelloy substrate, coating a raw material solution prepared by dissolving a trifluoroacetate of Y and Ba and a naphthenate of Cu onto the composite substrate, heat treating the coated composite substrate by calcination, then subjecting the calcined assembly to intermediate heat-treatment at a temperature below the temperature of heat-treatment for superconductor production, and then heat treating the assembly in an argon gas atmosphere under conditions of highest heating temperature 760° C., water vapor partial pressure 13.5%, and oxygen partial pressure 0.09% for superconductor production to produce a tape-shaped RE-type (123) superconductor having a YBCO superconducting film having a thickness of more than about 2 μm.
    • 具有高临界电流值的厚膜带状RE型(123)超导体的制造方法。 该制造方法具有以下步骤:将具有Gd 2 Zr 2 O 7和CeO 2的复合基板依次层叠在Hastelloy基板上,涂布通过将Y和Ba的三氟乙酸盐和Cu的环烷酸盐溶解在复合基板上而制备的原料溶液, 通过煅烧对涂覆的复合基材进行煅烧,然后在低于制备超导体的热处理温度的温度下对煅烧组件进行中间热处理,然后在氩气气氛中在最高加热温度760℃的条件下热处理该组件 C,水蒸气分压为13.5%,氧分压为0.09%,制造出具有厚度大于约2μm的YBCO超导膜的带状RE型(123)超导体。
    • 4. 发明授权
    • Method of and apparatus for manufacturing tape-formed oxide superconductor
    • 制造带状氧化物超导体的方法和装置
    • US08124171B2
    • 2012-02-28
    • US11385742
    • 2006-03-22
    • Yuji AokiHiroshi FujiSukeharu NomotoRyo TeranishiTeruo IzumiYuh Shiohara
    • Yuji AokiHiroshi FujiSukeharu NomotoRyo TeranishiTeruo IzumiYuh Shiohara
    • B05D5/12H01L39/24
    • F27B9/04H01L39/2451Y10S505/73Y10S505/74Y10S505/741Y10T29/49014
    • A method of manufacturing a tape-formed oxide superconductor, in which a tape-formed wire material (6 in FIG. 1) is extended between a pair of reels (5a and 5b). Besides, a reactive gas is supplied form the gas supply ports of a reactive gas supply pipe (3a) vertically to the upper side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, a gas after the reaction is discharged from the gas discharge ports of discharge pipes (4a and 4b) for discharging the gas after the reaction. Likewise, the reactive gas is supplied vertically to the lower side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, the gas after the reaction is discharged from the gas discharge ports of discharge pipes (4c and 4d) for discharging the gas after the reaction. Even when the tape-formed wire material (6) is large in area, the tape-formed oxide superconductor has superconducting characteristics being uniform in it widthwise direction, and it can be manufactured at high speed.
    • 制造带状氧化物超导体的方法,其中带状线材(图1中的6)在一对卷轴(5a和5b)之间延伸。 此外,从反应性气体供给管(3a)的气体供给口向带状线材(6)的上侧膜表面垂直地供给反应性气体, 将导线材料形成为超导层,同时从反应后排出气体的排出管(4a,4b)的排气口排出反应后的气体。 同样地,将反应性气体垂直地供给到带状线材(6)的下侧膜表面,以使该带状线材的膜体与超导层反应,同时, 反应后的气体从排出管(4c,4d)的排气口排出,排出反应后的气体。 即使当带状线材(6)的面积大时,带状氧化物超导体也具有在宽度方向上均匀的超导特性,并且可以高速制造。
    • 5. 发明申请
    • Method of and apparatus for manufacturing tape-formed oxide superconductor
    • 制造带状氧化物超导体的方法和装置
    • US20060216407A1
    • 2006-09-28
    • US11385742
    • 2006-03-22
    • Yuji AokiHiroshi FujiSukeharu NomotoRyo TeranishiTeruo IzumiYuh Shiohara
    • Yuji AokiHiroshi FujiSukeharu NomotoRyo TeranishiTeruo IzumiYuh Shiohara
    • B05D5/12C23C16/00
    • F27B9/04H01L39/2451Y10S505/73Y10S505/74Y10S505/741Y10T29/49014
    • A method of manufacturing a tape-formed oxide superconductor, in which a tape-formed wire material (6 in FIG. 1) is extended between a pair of reels (5a and 5b). Besides, a reactive gas is supplied form the gas supply ports of a reactive gas supply pipe (3a) vertically to the upper side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, a gas after the reaction is discharged from the gas discharge ports of discharge pipes (4a and 4b) for discharging the gas after the reaction. Likewise, the reactive gas is supplied vertically to the lower side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, the gas after the reaction is discharged from the gas discharge ports of discharge pipes (4c and 4d) for discharging the gas after the reaction. Even when the tape-formed wire material (6) is large in area, the tape-formed oxide superconductor has superconducting characteristics being uniform in it widthwise direction, and it can be manufactured at high speed.
    • 一种制造带状氧化物超导体的方法,其中带状线材(图1中的6)在一对卷轴(5a和5b)之间延伸。 此外,从反应性气体供给管(3a)的气体供给口向带状线材(6)的上侧膜表面垂直地供给反应气体,以使该带的膜体反应 形成的导线材料进入超导层,同时反应之后的气体从排出管(4a和4b)的气体排出口排出,用于在反应之后排出气体。 同样地,将反应性气体垂直地供给到带状线材(6)的下侧膜表面,以使该带状线材的膜体与超导层反应,同时, 反应后的气体从排气管(4c和4d)的排气口排出,用于排出反应后的气体。 即使当带状线材(6)的面积大时,带状氧化物超导体也具有在宽度方向上均匀的超导特性,并且可以高速制造。