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1. 发明授权

US4675424A Method for making polysilazanes 失效
标题翻译：聚硅氮烷的制备方法
公开(公告)号：US4675424A
公开(公告)日：1987-06-23
申请号：US841545
申请日：1986-03-19
申请人： Roswell E. King, III , Bernard Kanner , Steven P. Hopper , Curtis L. Schilling, Jr.
发明人： Roswell E. King, III , Bernard Kanner , Steven P. Hopper , Curtis L. Schilling, Jr.
IPC分类号： C04B35/589 , C07F7/10 , C08G77/48 , C08G77/62
CPC分类号： C08G77/62 , C04B35/589 , C07F7/10
摘要： A method of preparing silazane polymers, with 3 or more repeating units, of the general formula--((CH.sub.3).sub.2 N).sub.e Si(R).sub.a (R'HN).sub.f H.sub.c (NR').sub.g --and a (CH.sub.3).sub.2 NH byproduct group where R is hydrogen, an alkyl group having 1-6 carbon atoms or an aryl group having 6-12 carbon atoms, a=0, or 1, b=2-4, C=0-2, d=0 or 1, e=0-2, f=0-2, g=1-3 and a+c+e+f+g=4 for the polymer units; and R' is hydrogen or methyl, whereby the silazane polymer is substantially free of halide impurities, and wherein this method comprises:transaminating an aminosilane of the general formula (R).sub.a ((CH.sub.3).sub.2 N).sub.b H.sub.c S; where R is defined as above and a+b+c=4 with an amine of the general formula (CH.sub.3).sub.d NH.sub.3-d whereby d is defined as above and the amine has a molecular weight lower than 45 all in the presence of an acid catalyst or the ammonium salt of the acid and thereafter condensing to form the polymer.
摘要翻译：制备具有3个以上重复单元的具有通式 - （（CH 3）2 N）e Si（R）a（R'HN）fHc（NR'）g - 和（CH 3）2 NH副产物基团）的硅氮烷聚合物的方法其中R是氢，具有1-6个碳原子的烷基或具有6-12个碳原子的芳基，a = 0或1，b = 2-4，C = 0-2，d = 0或1，对于聚合物单元，e = 0-2，f = 0-2，g = 1-3和a + c + e + f + g = 4; 并且R'是氢或甲基，由此硅氮烷聚合物基本上不含卤化物杂质，并且其中该方法包括：将通式（R）a（（CH 3）2 N）b H c S的氨基硅烷转氨酸; 其中R如上所定义，a + b + c = 4与通式（CH3）dNH3-d的胺反应，其中d如上定义，胺在酸存在下全部分子量低于45 催化剂或酸的铵盐，然后冷凝形成聚合物。

2. 发明授权

US4789564A Hydridoaminosilane treatment for rendering surfaces water-repellent 失效
标题翻译：氢化氨基硅烷处理使表面防水
公开(公告)号：US4789564A
公开(公告)日：1988-12-06
申请号：US32377
申请日：1987-03-31
申请人： Bernard Kanner , Roswell E. King, III , Steven P. Hopper
发明人： Bernard Kanner , Roswell E. King, III , Steven P. Hopper
IPC分类号： C04B41/49 , C04B41/84 , C07F7/02 , C07F7/10 , C09K3/18 , D06M15/643 , D21H17/13 , D21H21/16 , D21H23/44 , B05D3/02 , C23C16/00
CPC分类号： C04B41/84 , C04B41/4944 , C09K3/18 , D06M15/6436 , D21H17/13 , D21H21/16 , D21H23/44
摘要： Surfaces containing hydroxyl groups are rendered water-repellent through exposure to hydridoaminosilanes of the general formulaH.sub.x Si(NRH).sub.y (NR.sub.2.sup.1).sub.3-yIn particular, tris(dimethylamino)silane and its derivatives have been found to make substrates with hydroxyl-containing surfaces hydrophobic without adversely effecting the physical properties of the substrate being treated and without the necessity of and pre- or post-treatment steps (i.e. moisturizing, neutralizing, etc.).

3. 发明授权

US4895885A Polymer compositions stabilized with polysiloxanes containing sterically hindered heterocyclic moiety 失效
标题翻译：用含空间位阻杂环部分的聚硅氧烷稳定的聚合物组合物
公开(公告)号：US4895885A
公开(公告)日：1990-01-23
申请号：US240739
申请日：1988-09-06
申请人： George N. Foster , Herbert E. Petty , Roswell E. King, III
发明人： George N. Foster , Herbert E. Petty , Roswell E. King, III
IPC分类号： C08L23/00 , C08G77/388 , C08K5/3435 , C08K5/5419 , C08K5/544 , C08L23/02 , C08L87/00
CPC分类号： C08K5/3435 , C08G77/388 , C08K5/5442 , C08L23/02
摘要： The present invention relates to olefin polymers stabilized with polysiloxanes containing sterically hindered heterocyclic moieties, said polysiloxanes represented by the general formula M*.sub.v D.sub.x D*.sub.y T.sub.z Q.sub.w M*.sub.v.

4. 发明授权

US5003023A Olefin polymer compositions containing polyorganosiloxanes and the use thereof in the production of film material and polyorganosiloxanes 失效
标题翻译：含有聚有机硅氧烷的烯烃聚合物组合物及其在薄膜材料和聚有机硅氧烷生产中的应用
公开(公告)号：US5003023A
公开(公告)日：1991-03-26
申请号：US497592
申请日：1990-03-22
申请人： George N. Foster , Herbert E. Petty , Charles H. Blevins, II , Roswell E. King, III
发明人： George N. Foster , Herbert E. Petty , Charles H. Blevins, II , Roswell E. King, III
IPC分类号： C08G77/38 , C08L23/02
CPC分类号： C08G77/38 , C08L23/02
摘要： The present invention relates to olefin polymer compositions which can be extruded into film material characterized by improved stability and optical properties. In particular, this application is directed olefin polymer compositions containing specific polyorganosiloxanes bearing a hydroxyl functionality.
摘要翻译：本发明涉及可以挤出成薄膜材料的烯烃聚合物组合物，其特征在于其改进的稳定性和光学性质。特别地，本申请是含有具有羟基官能团的特定聚有机硅氧烷的烯烃聚合物组合物。

5. 发明授权

US06872764B2 Stabilized gamma irradiated polyolefins 失效
标题翻译：稳定的γ照射聚烯烃
公开(公告)号：US06872764B2
公开(公告)日：2005-03-29
申请号：US10372751
申请日：2003-02-24
申请人： Roswell E. King, III
发明人： Roswell E. King, III
IPC分类号： C08K5/16 , C08K5/51 , C08K5/3435 , C08K5/1535 , C08K5/3477
CPC分类号： C08K5/16 , C08K5/51 , C08L23/02
摘要： Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.
摘要翻译：包含二元受阻胺/羟胺或硝酮或氧化胺或苯并呋喃酮体系或三元受阻胺/羟胺或硝酮或氧化胺或苯并呋喃酮/有机亚磷酸酯或亚膦酸盐体系的某些基本上无酚类抗氧化剂的稳定剂体系对于保护是特别有效的聚烯烃抵抗γ照射的有害影响。聚烯烃制品如医疗包装，医院服装，布帘，纺织和无纺布纤维制品，手术器具，吹塑成型I.V。瓶子，皮下注射器，针罩，实验室用品如托盘，漏斗，培养皿和过滤器以及与卫生有关的物品可以用γ射线灭菌并且根据本发明是稳定的。

6. 发明授权

US5521237A Alkanolamine esters of acyclic phosphites in polyolefin compositions 失效
标题翻译：聚烯烃组合物中无环亚磷酸酯的烷醇胺酯
公开(公告)号：US5521237A
公开(公告)日：1996-05-28
申请号：US254203
申请日：1994-06-06
申请人： Raymond Seltzer , Wha Chen , Roswell E. King, III , Paul Odorisio , Rita Pitteloud , Sai P. Shum
发明人： Raymond Seltzer , Wha Chen , Roswell E. King, III , Paul Odorisio , Rita Pitteloud , Sai P. Shum
IPC分类号： C09K15/32 , C07B63/04 , C07F9/141 , C07F9/145 , C08K5/52 , C08K5/524 , C08K5/526 , C08L101/00 , C10M137/02 , C10M137/04 , C10N30/10
CPC分类号： C10M137/02 , C07B63/04 , C07F9/1411 , C07F9/145 , C08K5/526 , C10M2223/04 , C10M2223/042
摘要： Selected alkanolamine esters of acyclic phosphites are particularly effective as process stabilizers for polyolefins providing for melt flow stabilization and resistance to discoloration during said processing.
摘要翻译：非极性亚磷酸酯的选择的链烷醇胺酯作为聚烯烃的工艺稳定剂是特别有效的，其提供熔融流动稳定性和在所述加工过程中耐变色性。

7. 发明授权

US5236514A Purging composition for cleaning thermoplastic processing equipment 失效
标题翻译：清洗组合物用于清洗热塑性加工设备
公开(公告)号：US5236514A
公开(公告)日：1993-08-17
申请号：US785145
申请日：1991-10-29
申请人： Pak S. Leung , Philbert E. Ramdatt , Roswell E. King, III
发明人： Pak S. Leung , Philbert E. Ramdatt , Roswell E. King, III
IPC分类号： C11D3/14 , C11D3/20 , C11D3/36 , C11D3/37 , C11D11/00
CPC分类号： B29C47/0877 , C11D11/0041 , C11D3/14 , C11D3/2079 , C11D3/362 , C11D3/37 , B29C47/0009
摘要： A purging composition is provided which is useful for cleaning thermoplastic processing equipment. The composition is composed of the following components in the following concentrations:______________________________________ Component Percent by Weight ______________________________________ Adsorbate 0.05 to 5 Matrix resin 49.5 to 99.5 Abrasive (optional) 0 to 50 ______________________________________ The composition can also contain a carrier resin having a melting point different from that of the matrix resin.
摘要翻译：提供清洗组合物，其可用于清洁热塑性加工设备。该组合物由以下组分组成： - 组分重量百分数 - 吸附剂0.05至5 - 矩阵树脂49.5至99.5 - 含量（任选）0至50 - 该组合物还可含有具有熔点不同于基体树脂。

8. 发明授权

US4931492A Olefin polymer compositions containing polyorganosiloxanes and the use thereof in the production of film material and polyorganosiloxanes 失效
标题翻译：含有聚有机硅氧烷的烯烃聚合物组合物及其在薄膜材料和聚有机硅氧烷生产中的应用
公开(公告)号：US4931492A
公开(公告)日：1990-06-05
申请号：US322968
申请日：1989-03-17
申请人： George N. Foster , Herbert E. Petty , Charles H. Blevins, II , Roswell E. King, III
发明人： George N. Foster , Herbert E. Petty , Charles H. Blevins, II , Roswell E. King, III
IPC分类号： C08G77/38 , C08L23/02
CPC分类号： C08G77/38 , C08L23/02 , C08L23/06
摘要： The present invention relates to olefin polymer compositions which can be extruded into film material characterized by improved stability and optical properties. In particular, this application is directed olefin polymer compositions containing specific polyorganosiloxanes bearing a hydroxyl functionality.
摘要翻译：本发明涉及可以挤出成薄膜材料的烯烃聚合物组合物，其特征在于其改进的稳定性和光学性质。特别地，本申请是含有具有羟基官能团的特定聚有机硅氧烷的烯烃聚合物组合物。

9. 发明授权

US07022390B2 Polyester and polyamide compositions of low residual aldehyde content 失效
公开(公告)号：US07022390B2
公开(公告)日：2006-04-04
申请号：US11009843
申请日：2004-12-02
申请人： Paul A. Odorisio , Stephen M Andrews , Dario Lazzari , Dirk Simon , Roswell E. King, III , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Müller , Urs Hirt
发明人： Paul A. Odorisio , Stephen M Andrews , Dario Lazzari , Dirk Simon , Roswell E. King, III , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Müller , Urs Hirt
IPC分类号： B29D22/00 , C08K5/00
CPC分类号： C08K5/32 , C08K5/053 , C08K5/17 , C08K5/34 , C08L23/0861 , C08L29/04 , C08L33/26 , C08L67/02 , C08L77/00 , C08L101/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1383 , Y10T428/1393 , Y10T428/1397 , Y10T428/31786 , C08L2666/04
摘要： A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.

10. 发明授权

US06908650B2 Polyester and polyamide compositions of low residual aldehyde content 失效
公开(公告)号：US06908650B2
公开(公告)日：2005-06-21
申请号：US10202380
申请日：2002-07-24
申请人： Paul A. Odorisio , Stephen M Andrews , Dario Lazzari , Dirk Simon , Roswell E. King, III , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Müller , Urs Hirt
发明人： Paul A. Odorisio , Stephen M Andrews , Dario Lazzari , Dirk Simon , Roswell E. King, III , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Müller , Urs Hirt
IPC分类号： A23L1/00 , B29D22/00 , C08G63/78 , C08K5/16 , C08K5/17 , C08K5/32 , C08K5/34 , C08L67/02 , C08L77/00
CPC分类号： C08K5/32 , C08K5/053 , C08K5/17 , C08K5/34 , C08L23/0861 , C08L29/04 , C08L33/26 , C08L67/02 , C08L77/00 , C08L101/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1383 , Y10T428/1393 , Y10T428/1397 , Y10T428/31786 , C08L2666/04
摘要： A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.

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