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1. 发明授权

US06602967B1 Use of deaminatively-generated carbocation as polymerization initiators 有权
标题翻译：使用脱氨生成的碳阳离子作为聚合引发剂
公开(公告)号：US06602967B1
公开(公告)日：2003-08-05
申请号：US09615250
申请日：2000-07-13
申请人： Ron W. Darbeau , Mark S. Delaney , Ulku Ramelow
发明人： Ron W. Darbeau , Mark S. Delaney , Ulku Ramelow
IPC分类号： C08F404
CPC分类号： C08F4/00 , C08F136/08
摘要： Deaminatively generated carbocations to initiate addition polymerization are disclosed. The high reactivity of the carbocation allows initiation of polymerization with virtually all alkenes, alkynes, alicyclic and aromatic monomers, regardless whether multisubstituted or conjugated. In addition, the carbocation initiates a polymerization reaction that generates an extremely high molecular weight polymer. In particular polystyrene of viscosity average molecular weight of approximately 106 was obtained.
摘要翻译：公开了脱氨基生成的引发加成聚合的碳阳离子。碳阳离子的高反应性允许几乎所有烯烃，炔烃，脂环族和芳族单体的聚合开始，无论多取代或共轭。另外，碳阳离子开始产生极高分子量聚合物的聚合反应。特别是得到粘均分子量约为106的聚苯乙烯。

2. 发明授权

US4363747A Metallocarborane precursor and catalyst 失效
标题翻译：金属环硼烷前体和催化剂
公开(公告)号：US4363747A
公开(公告)日：1982-12-14
申请号：US273731
申请日：1981-06-15
申请人： M. Frederick Hawthorne , Mark S. Delaney
发明人： M. Frederick Hawthorne , Mark S. Delaney
IPC分类号： B01J31/24 , C07C45/50 , C07F15/00 , B01J31/12
CPC分类号： B01J31/2404 , B01J31/2291 , C07C45/50 , C07F15/0073 , B01J2231/321 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J31/165
摘要： An extraordinarily active carborane catalyst for use in hydrogenation, hydroformulation and isomerization reactions. The new catalyst is a modification of known metallocarborane catalysts having a transition metal symmetrically bonded to the pentagonal face of a dicarborane cage with two triphenylphosphine ligands and one hydrogen ligand occupying the remaining transition metal ligand sites. The new alkene-metallocarborane replaces one of the triphenylphosphine ligands with a lower chelating or bridging alkene which is bound to both the transition metal and the carborane cage.The alkene-metallocarborane catalyst may be used as a homogenous catalyst or may be bound to a suitable polymer support for use as a heterogeneous catalyst. The catalyst has been found to be among the most highly reactive catalysts known to date. It is believed the high reactivity of the new catalyst is due to the in situ irreversible hydrogenation of the alkene side chain to produce an open coordination site on the transition metal atom.
摘要翻译：用于氢化，加氢成型和异构化反应的非常活泼的碳硼烷催化剂。新催化剂是已知的具有二碳硼烷笼的五边形面对称地键合过渡金属的金属多异氰酸酯催化剂的改性，其具有两个三苯基膦配体和一个占据剩余的过渡金属配体位点的氢配体。新的烯烃 - 金属环硼烷用与螯合或桥连烯烃结合的过渡金属和碳硼烷笼两者替代三苯基膦配体之一。烯烃 - 金属环硼烷催化剂可以用作均匀的催化剂，或者可以与合适的聚合物载体结合，用作非均相催化剂。已经发现催化剂是迄今为止已知的最高反应性催化剂。据信，新催化剂的高反应性是由于烯烃侧链的原位不可逆氢化以在过渡金属原子上产生开放的配位点。

3. 发明授权

US4668746A Initiator and method for polymerizing ethylene and preparing block copolymers containing ethylene 失效
标题翻译：用于聚合乙烯并制备含乙烯的嵌段共聚物的引发剂和方法
公开(公告)号：US4668746A
公开(公告)日：1987-05-26
申请号：US831679
申请日：1986-02-21
申请人： Mark S. Delaney , William B. Marshall , James L. Brewbaker
发明人： Mark S. Delaney , William B. Marshall , James L. Brewbaker
IPC分类号： C08F4/48 , C08F10/00
CPC分类号： C08F10/00
摘要： A complex of an alkyllithium compound and 1,2-dipyrrolidinoethane is useful as an initiator for the polymerization of ethylene and ethylene block copolymers.
摘要翻译：烷基锂化合物和1,2-二吡咯烷基乙烷的络合物可用作乙烯和乙烯嵌段共聚物的聚合引发剂。

4. 发明授权

US4659685A Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound 失效
标题翻译：含有负载的钛化合物和至少一种其它负载的有机金属化合物的非均相有机金属催化剂
公开(公告)号：US4659685A
公开(公告)日：1987-04-21
申请号：US840165
申请日：1986-03-17
申请人： William M. Coleman, III , Gregory F. Schmidt , Richard E. Campbell, Jr. , Mark S. Delaney
发明人： William M. Coleman, III , Gregory F. Schmidt , Richard E. Campbell, Jr. , Mark S. Delaney
IPC分类号： C08F4/619 , C08F4/6192 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61904 , C08F4/61912 , C08F4/61916 , C08F4/61925 , Y10S526/941 , Y10S526/943
摘要： Catalyst compositions are disclosed which are a combination of a supported titanium compound such as titanium tetraisopropoxide supported on magnesium dichloride and at least one other supported metallic catalyst such as dicyclopentadienyl zirconium dichloride supported on alumina and a cocatalyst such as aluminoxane. These catalysts are useful in the polymerization of .alpha.-olefins.
摘要翻译：公开了催化剂组合物，其是负载在二氯化镁上的负载钛化合物如四异丙醇钛和负载在氧化铝上的至少一种其它负载的金属催化剂如二环戊二烯基二氯化锆和诸如铝氧烷之类的助催化剂的组合。这些催化剂可用于α-烯烃的聚合。

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