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    • 1. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07786313B2
    • 2010-08-31
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A1和A2各自独立地为芳族或杂芳族基团,琥珀酸酯与至少一种未取代的 或取代的芳族或杂芳族腈,该方法包括在至少一种下式化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4 C 1 -C 10烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5'-,-COO-,-CONR 5 - ,-SO- ,SO 2 - ,-SO 2 NR 5 - 或-NR 5 - 以及R 5和R 5'各自独立地为氢或直链或从C3向上任选支链的C 1 -C 30烷基,C 6 -C 10芳基或C 6 -C 24芳烷基, 这样的混合物在 有机材料和化妆品着色,以及新型二酮吡咯并吡咯颜料混合物。
    • 2. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20080287689A1
    • 2008-11-20
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/04
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为另一个 芳族或杂芳族基团,通过琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种下式的化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是线性的,或者是C 1 -C 3 - 3个以上,任选支链C 1 -C 30烷基,C 6 -C 10芳基 或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5, -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 NR 2 - 5 - 或-NR 5 - 和R 5和R 5 - 各自独立地为另一个氢或直链或者从C 3向上,任选支链C 1 -C 30烷基, C 6 -C 12芳基或C 6 -C 24 - 芳烷基,使用这种混合物 在有机材料和化妆品的着色中,以及新型二酮吡咯并吡咯颜料混合物。
    • 3. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07417154B2
    • 2008-08-26
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 2 4芳烷基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这样的混合物,以及新型二酮吡咯并吡咯颜料混合物
    • 4. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20070028807A1
    • 2007-02-08
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/02C08K5/00
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, -0-, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 12亚芳基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这种混合物,以及新型二酮吡咯并吡咯颜料混合物。
    • 6. 发明授权
    • High-molecular-weight polymeric material comprising diketopyrrolopyrrole pigments
    • 包含二酮吡咯并吡咯颜料的高分子量聚合物材料
    • US07279514B2
    • 2007-10-09
    • US10521651
    • 2003-07-08
    • Roman LenzGerardus De KeyzerOlof WallquistTaher Yousaf
    • Roman LenzGerardus De KeyzerOlof WallquistTaher Yousaf
    • C08K5/3417C07D209/00
    • C08K5/3415C08K5/0041C09B57/004C09B67/0033Y10T428/31786
    • The present invention relates to high-molecular-weight polymeric material comprising at least one diketopyrrolopyrrole pigment of formula (1) wherein R1, is hydrogen, chlorine, methyl, methoxy, CF3 or CN, R2 is hydrogen, chlorine, methyl, methoxy, CF3 or CN, A is hydrogen, chlorine, methyl, mehtoxy, CF3, CN, unsubstituted or substituted phenyl or a radical of formula (2), (2a) or (2b), wherein R5 is hydrogen, chlorine, methyl, methoxy, nitro, CF3 or CN and R6 is hydrogen, chlorine, methyl, methoxy, nitro, CF3 or CN, or R5 and R6 together with the phenyl ring to which they are bonded form an aryl or a heteroaryl and A1 is a radical of formula (2), (2a) or (2b), to the preparation of that material and to the use thereof in colour filters, and to novel diketopyrrolopyrrole pigments.
    • 本发明涉及包含至少一种式(1)的二酮吡咯并吡咯颜料的高分子量聚合物材料,其中R 1是氢,氯,甲基,甲氧基,CF 3, SUB或CN,R 2是氢,氯,甲基,甲氧基,CF 3或CN,A是氢,氯,甲基,Mehtoxy,CF 3 CN,未取代或取代的苯基或式(2),(2a​​)或(2b)的基团,其中R 5是氢,氯,甲基,甲氧基,硝基,CF 3或CN和R 6是氢,氯,甲基,甲氧基,硝基,CF 3或CN或R 5, / SUB和R 6与它们所键合的苯环一起形成芳基或杂芳基,A 1是式(2),(2a​​)的基团 )或(2b),涉及该材料的制备及其在滤色器中的应用,以及新型二酮吡咯并吡咯颜料。
    • 9. 发明申请
    • Method of colouring porous material
    • 多孔材料着色方法
    • US20050251932A1
    • 2005-11-17
    • US10525300
    • 2003-08-26
    • Jean-Marie AdamTaher YousafVictor Eliu
    • Jean-Marie AdamTaher YousafVictor Eliu
    • A61K8/49A61Q5/06A61Q5/10C07C245/24C09B67/00C09B67/36C07C245/02C09B1/00
    • A61K8/4966A61Q5/065C07C245/24C09B67/0079
    • A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    • 描述了一种着色多孔材料,特别是人发的方法,该方法包括以任何所需顺序依次或同时施用着色的材料,a)至少一种式(1)的封端重氮化合物和/或在 至少一种式(2)的化合物和/或至少一种式(3)的化合物,其中Q是未取代或取代的芳族或杂环残基,R是未取代或取代的水溶性脂族或芳族胺的基团, 并且T是未取代或取代的水溶性脂族或芳族残基,其中所述基团中的至少一个必须含有自由基赋予水溶性,和a)至少一种水溶性偶联组分, 不会发生,然后使存在于材料上的覆盖的重氮化合物与偶联组分反应。
    • 10. 发明申请
    • Writable high-capacity optical storage media containing metal complexes
    • 包含金属络合物的可写入大容量光存储介质
    • US20050008974A1
    • 2005-01-13
    • US10495678
    • 2002-11-07
    • Colin MortonTaher YousafJean-Luc BudryBeat SchmidhalterHeinz Spahni
    • Colin MortonTaher YousafJean-Luc BudryBeat SchmidhalterHeinz Spahni
    • B41M5/26C07D487/22C07F15/02G11B7/004G11B7/24G11B7/244G11B7/248G11B7/253G11B7/26C09B47/04
    • C07D487/22G11B7/248
    • The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.
    • 本发明涉及一种包括基材和记录层的光学记录介质,其中记录层包含式(I)的配合物,或其中Q 2是式(II)的配体或其互变异构体,和 R1,R2,R3,R4,R5,R6,R7和R8各自独立地为H,卤素,氰基,COOR9,CONHR9,CONR9R10,R9,OR9,SR9,NHR9或NR9R10,其中R9和R10各自 独立于其它C 6 -C 10芳基,C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基,C 3 -C 24环烯基,C 2 -C 24烯基,C 3 -C 24环烯基,C 2 -C 24炔基,C 1 -C 12杂环烷基,未取代或取代的C 1 -C 12杂环烯基, R 1和R 2,R 3和R 4,R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合,M m是具有5个碳原子的过渡金属阳离子 或6个电子,L1是具有子结构NC,PC或As-C,L2的配体,独立于L1,是另一个配体c 保持至少一个杂原子N,P,As,O,S,Se或Te,L3 - 是CN - ,SCN - ,NCS - ,OCN - ,NCO - , - N3-,L1-O - ,L1-S-,L