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1. 发明授权

US4727186A Certain alkynyl-benzene sulfonamide intermediates useful for preparing ureas herbicides 失效
标题翻译：某些用于制备脲类除草剂的炔基 - 苯磺酰胺中间体
公开(公告)号：US4727186A
公开(公告)日：1988-02-23
申请号：US745747
申请日：1985-06-17
申请人： Rolf Schurter , Werner Fury , Willy Meyer
发明人： Rolf Schurter , Werner Fury , Willy Meyer
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/42 , C07D401/12 , C07D409/12 , C07D521/00 , C07C143/78 , C07C149/447
CPC分类号： C07D521/00 , A01N47/36
摘要： Phenylsulfonamides of Formula II ##STR1## wherein A is a radical of the formula --C.tbd.C--R;R is H, or an optionally substituted (i) C.sub.1 -C.sub.9 alkyl, (ii) C.sub.3 -C.sub.9 cycloalkyl, (iii) phenyl, or (iv) 5-or-6 membered heterocyclic ring;m is one or two;R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, or --Y--R.sub.5 ;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkenyl, --Y--R.sub.5, --COOR.sub.6, --NO.sub.2, or --CO--NR.sub.7 --R.sub.8 ;R.sub.5 and R.sub.6 are each independently C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl, or C.sub.2 -C.sub.6 alkoxyalkyl;R.sub.7 and R.sub.8 are each independently hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, or C.sub.2 -C.sub.6 alkynyl; andY is oxygen, sulfur, sulfinyl or sulfonyl bridge; or a salt thereof.
摘要翻译：式II的苯磺酰胺（II）其中A是式-C3OND C-R的基团; R为H或任选取代的（ⅰ）C 1 -C 9烷基，（ⅱ）C 3 -C 9环烷基，（ⅲ）苯基或（ⅳ）5-或6-元杂环; m是一两个; R1是氢，卤素，C1-C5烷基，C2-C5烯基或-Y-R5; R2是氢，卤素，C1-C5烷基，C2-C5烯基，C1-C4卤代烯基，-Y-R5，-COOR6，-NO2或-CO-NR7-R8; R 5和R 6各自独立地为C 1 -C 5烷基，C 2 -C 5烯基，C 2 -C 6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基; R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基; Y是氧，硫，亚磺酰基或磺酰基桥; 或其盐。

2. 发明授权

US4510325A Phenyl sulfonamides 失效
标题翻译：苯磺酰胺
公开(公告)号：US4510325A
公开(公告)日：1985-04-09
申请号：US417743
申请日：1982-09-13
申请人： Willy Meyer , Werner Fury
发明人： Willy Meyer , Werner Fury
IPC分类号： C07D239/42 , A01N41/06 , A01N43/66 , A01N47/36 , A01P13/00 , C07C20060101 , C07C67/00 , C07C301/00 , C07C311/00 , C07C311/29 , C07C313/00 , C07C317/14 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/67 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/56 , C07D251/14 , C07D251/16 , C07D251/22 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00 , C07C143/78
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.1 -C.sub.6 alkyl radical which is substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 haloalkylsulfinyl or C.sub.1 -C.sub.4 haloalkylsulfonyl, or a C.sub.2 -C.sub.6 -alkenyl radical which is unsubstituted or substituted by the above substituents, or is a C.sub.2 -C.sub.6 haloalkenyl radical,E is the methine group or nitrogen,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is 1 or 2,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲及其与胺，碱金属或碱土金属碱或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节属性。在上式中，A是被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4卤代烷基亚磺酰基或C 1 -C 4卤代烷基磺酰基取代的C 1 -C 6烷基，或未被取代或被上述取代基取代的C2-C6-烯基，或是C2-C6卤代烯基，E是次甲基或氮，X是氧，硫，亚磺酰基或磺酰基桥，Z是氧或硫，m为1或2，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基，C 1 -C 4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4分别独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷氧基，C1-C4烷硫基，C1- 最多4个碳原子的C 4卤代烷基，卤素或烷氧基烷基，R 5和R 6各自独立地为C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 7和R 8各自独立地为氢，C1- C5烷基，C 2 -C 5烯基或C 2 -C 6炔基，Y是氧，硫，亚磺酰基或磺酰基桥。

3. 发明授权

US4594097A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4594097A
公开(公告)日：1986-06-10
申请号：US745749
申请日：1985-06-17
申请人： Rolf Schurter , Werner Fory , Willy Meyer
发明人： Rolf Schurter , Werner Fory , Willy Meyer
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/42 , C07D401/12 , C07D409/12 , C07D521/00 , C07D251/50 , A01N43/70 , C07D251/52
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.
摘要翻译： N-苯基磺酰基-N'-嘧啶基脲和通式I的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团，m是1或2，Z是氧或硫，R是氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5链烯基， C1-C4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基， C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，卤素，C2-C5烷氧基烷基，-NR9R10或-O-CH2-CH2-NR9R10，R5和R6各自独立地为C1-C5烷基，C2-C5链烯基或C2 C 1-6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 9为氢，甲基或乙基，R 10为氢，C1-C4烷基，C1-C4烷氧基，甲氧基甲基，氰基甲基，氰乙基，C3-C5链烯基或C3-C6炔基，Y是氧，硫，亚磺酰基或磺酰基桥，这些化合物与胺，碱金属碱或碱地球金属碱基或季铵碱基，具有良好的出芽前和出芽后选择性除草和生长调节性质。

4. 发明授权

US4487951A N-Phenylsulfonylcarbamates 失效
标题翻译： N-苯基磺酰基氨基甲酸酯
公开(公告)号：US4487951A
公开(公告)日：1984-12-11
申请号：US571976
申请日：1984-01-19
申请人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
发明人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
IPC分类号： A01N47/24 , A01N47/08 , A01N47/22 , A01N47/36 , C07C303/36 , C07C311/16 , C07C311/53 , C07C323/67 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/16 , C07D251/22 , C07D251/40 , C07D251/46 , C07D251/52 , C07D521/00 , C07C143/83
CPC分类号： C07C311/65 , A01N47/36 , C07D239/47 , C07D239/48 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后芽后选择性，除草和生长调节性质。该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8独立地为各自为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

5. 发明授权

US4478635A N-Arylsulfonyl-N'-pyrimidinylureas 失效
标题翻译： N-芳基磺酰基-N'-嘧啶基脲
公开(公告)号：US4478635A
公开(公告)日：1984-10-23
申请号：US455175
申请日：1983-01-03
申请人： Willy Meyer , Karl Gass , Werner Topfl , Rolf Schurter , Georg Pissiotas
发明人： Willy Meyer , Karl Gass , Werner Topfl , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/46 , C07D239/69 , A01N43/54
CPC分类号： C07D239/47 , A01N47/36 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/46
摘要： The invention relates to N-arylsulfonyl-N'-pyrimidinyl ureas of the general formula ##STR1## and to the salts thereof with amines, alkali metal hydroxides or alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.In the formula, R.sub.18 is hydrogen, alkyl or alkoxy, X is an unsubstituted or substituted phenyl radical or an unsubstituted or substituted naphthyl radical, Y is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.2 -C.sub.3 alkoxyalkyl, halogen or an unsubstituted amino group and Z is oxygen or sulfur.
摘要翻译：本发明涉及通式为（I）的N-芳基磺酰基-N'-嘧啶基脲，以及其与胺，碱金属氢氧化物或碱土金属氢氧化物或季铵碱的盐。这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。式中，R 18为氢，烷基或烷氧基，X为未取代或取代的苯基或未取代或取代的萘基，Y为C1-C3烷基，C1-C3卤代烷基，C1-C3烷氧基，C1-C3卤代烷氧基，C1-C3烷硫基， C 2 -C 3烷氧基烷基，卤素或未取代的氨基，Z是氧或硫。

6. 发明授权

US4443243A N-Phenylsulfonyl-N-triazinylureas 失效
标题翻译： N-苯基磺酰基-N-三嗪基脲
公开(公告)号：US4443243A
公开(公告)日：1984-04-17
申请号：US396959
申请日：1982-07-09
申请人： Werner Fory , Karl Gass , Willy Meyer , Rolf Schurter
发明人： Werner Fory , Karl Gass , Willy Meyer , Rolf Schurter
IPC分类号： A01N47/24 , A01N47/08 , A01N47/22 , A01N47/36 , C07C303/36 , C07C311/16 , C07C311/53 , C07C323/67 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/16 , C07D251/22 , C07D251/40 , C07D251/46 , C07D251/52 , C07D521/00 , C07D251/44 , A01N43/66 , C07D251/42
CPC分类号： C07C311/65 , A01N47/36 , C07D239/47 , C07D239/48 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后芽后选择性，除草和生长调节性质。该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

7. 发明授权

US4664695A N-phenylsulfonyl-N'-pyrimidinylureas as herbicides and plant growth regulants 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基脲作为除草剂和植物生长调节剂
公开(公告)号：US4664695A
公开(公告)日：1987-05-12
申请号：US717637
申请日：1985-03-29
申请人： Rolf Schurter , Rudolph C. Thummel , Werner Topfl , Willy Meyer , Dieter Durr
发明人： Rolf Schurter , Rudolph C. Thummel , Werner Topfl , Willy Meyer , Dieter Durr
IPC分类号： C07D249/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07C311/39 , C07D207/38 , C07D207/40 , C07D207/404 , C07D239/42 , C07D239/46 , C07D239/47 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/46 , C07D251/52 , C07D275/02 , C07D521/00 , C07D239/69 , A01N43/54 , C07D401/12 , C07D417/12
CPC分类号： C07D207/404 , A01N47/36 , C07D207/38 , C07D239/42 , C07D239/47 , C07D251/16 , C07D275/02 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas of the general formula I ##STR1## and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and growth regulating properties when applied pre- and postemergence.The symbols in formula I have the following meanings:R.sub.1 is hydrogen, halogen, nitro, cyano, or an alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylcarbonyl, alkylcarbamoyl or alkoxycarbonyl group, each unsubstituted or substituted by halogen or alkoxy,R.sub.2 is hydrogen, halogen, alkyl, or an alkyl, alkoxy or alkylthio group, each unsubstituted or substituted by halogen or alkoxy,R.sub.3 is alkyl, haloalkyl, alkoxy or haloalkoxy,R.sub.4 is hydrogen, halogen, R.sub.3, alkylamino or dialkylamino,R.sub.5 is hydrogen, alkyl or alkoxy, andX is an alkenylamino, cycloalkylamino or cycloalkenylamino group which may be further substituted, or is a carbamoylamido or sulfonylamino group as defined in the description, or is a 5- or 6-membered saturated heterocyclic ring system which is bonded through the nitrogen atom and which may contain a further oxygen, sulfur or nitrogen atom in the ring and must contain at least one oxo group.
摘要翻译：具有通式I（I）的N-苯基磺酰基-N'-嘧啶基和这些化合物与胺，碱金属碱或碱土金属碱或季铵碱的盐具有良好的选择性除草和生长调节性质应用于芽前和芽后。式I中的符号具有以下含义：R 1是氢，卤素，硝基，氰基或烷基，烷氧基，烷硫基，烷基磺酰基，烷基羰基，烷基氨基甲酰基或烷氧基羰基，各自未被取代或被卤素或烷氧基取代，卤素，烷基或烷基，烷氧基或烷硫基，各自未被取代或被卤素或烷氧基取代，R3是烷基，卤代烷基，烷氧基或卤代烷氧基，R4是氢，卤素，R3，烷基氨基或二烷基氨基，R5是氢，烷基或烷氧基，X是可以被进一步取代的链烯基氨基，环烷基氨基或环烯基氨基，或者是说明书中定义的氨基甲酰氨基或磺酰氨基，或是通过氮键合的5或6元饱和杂环体系原子，并且其可以在环中含有另外的氧，硫或氮原子，并且必须含有至少一个氧代基团。

8. 发明授权

US4632695A N-phenylsulfonyl-N'-triazinylureas as herbicides and plant growth regulants 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲作为除草剂和植物生长调节剂
公开(公告)号：US4632695A
公开(公告)日：1986-12-30
申请号：US806168
申请日：1985-12-06
申请人： Rolf Schurter , Rudolph C. Thummel , Werner Topfl , Willy Meyer , Dieter Durr
发明人： Rolf Schurter , Rudolph C. Thummel , Werner Topfl , Willy Meyer , Dieter Durr
IPC分类号： C07D249/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07C311/39 , C07D207/38 , C07D207/40 , C07D207/404 , C07D239/42 , C07D239/46 , C07D239/47 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/46 , C07D251/52 , C07D275/02 , C07D521/00 , A01N43/66 , A01N43/70
CPC分类号： C07D207/404 , A01N47/36 , C07D207/38 , C07D239/42 , C07D239/47 , C07D251/16 , C07D275/02 , C07D521/00
摘要： N-Phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and growth regulating properties when applied pre- and postemergence. The symbols in formula I have the following meanings:R.sub.1 is hydrogen, halogen, nitro, cyano, or an alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylcarbonyl, alkylcarbamoyl or alkoxycarbonyl group, each unsubstituted or substituted by halogen or alkoxy,R.sub.2 is hydrogen, halogen, alkyl, or an alkyl, alkoxy or alkylthio group, each unsubstituted or substituted by halogen or alkoxy,R.sub.3 is alkyl, haloalkyl, alkoxy or haloalkoxy,R.sub.4 is hydrogen, halogen, R.sub.3, alkylamino or dialkylamino,R.sub.5 is hydrogen, alkyl or alkoxy, andX is an alkenylamino, cycloalkylamino or cycloalkenylamino group which may be further substituted, or is a carbamoylamido or sulfonylamino group as defined in the description, or is a 5- or 6-membered saturated heterocyclic ring system which is bonded through the nitrogen atom and which may contain a further oxygen, sulfur or nitrogen atom in the ring and must contain at least one oxo group.
摘要翻译：具有通式I（I）的N-苯基磺酰基-N'-三嗪基和这些化合物与胺，碱金属碱或碱土金属碱或季铵碱的盐具有良好的选择性除草和生长调节性质应用于芽前和芽后。式I中的符号具有以下含义：R 1是氢，卤素，硝基，氰基或烷基，烷氧基，烷硫基，烷基磺酰基，烷基羰基，烷基氨基甲酰基或烷氧基羰基，各自未被取代或被卤素或烷氧基取代，卤素，烷基或烷基，烷氧基或烷硫基，各自未被取代或被卤素或烷氧基取代，R3是烷基，卤代烷基，烷氧基或卤代烷氧基，R4是氢，卤素，R3，烷基氨基或二烷基氨基，R5是氢，烷基或烷氧基，X是可以被进一步取代的链烯基氨基，环烷基氨基或环烯基氨基，或者是说明书中定义的氨基甲酰氨基或磺酰氨基，或是通过氮键合的5或6元饱和杂环体系原子，并且其可以在环中含有另外的氧，硫或氮原子，并且必须含有至少一个氧代基团。

9. 发明授权

US5104440A N-phenylsulfonyl-N'-pyrimidinylureas 失效
标题翻译： N-苯基磺酰基-N'-吡啶二酮
公开(公告)号：US5104440A
公开(公告)日：1992-04-14
申请号：US697178
申请日：1991-05-08
申请人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
发明人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
IPC分类号： B01J31/24 , A01N47/36 , A01P13/00 , C07B61/00 , C07C303/22 , C07C309/29 , C07C309/30 , C07C309/44 , C07C309/86 , C07C309/87 , C07C311/15 , C07C311/16 , C07C311/29 , C07C311/53 , C07C311/54 , C07C311/58 , C07C311/65 , C07C317/10 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/69 , C07D251/16 , C07D251/42 , C07D251/46 , C07D251/52 , C07D521/00
CPC分类号： C07C311/65 , A01N47/36 , C07C309/00 , C07D239/47 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylures of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.P --C.sub.1 -C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, and R.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl, m and n are each 0 or 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

10. 发明授权

US5041603A N-phenylsulfonyl-N'-pyrimidinyl-ureas and N-phenyl-sulfonyl-N'-triazinyl ureas 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基脲和N-苯基 - 磺酰基-N'-三嗪基脲
公开(公告)号：US5041603A
公开(公告)日：1991-08-20
申请号：US464578
申请日：1990-01-12
申请人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
发明人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
IPC分类号： B01J31/24 , A01N47/36 , A01P13/00 , C07B61/00 , C07C303/22 , C07C309/29 , C07C309/30 , C07C309/44 , C07C309/86 , C07C309/87 , C07C311/15 , C07C311/16 , C07C311/29 , C07C311/53 , C07C311/54 , C07C311/58 , C07C311/65 , C07C317/10 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/69 , C07D251/16 , C07D251/42 , C07D251/46 , C07D251/52 , C07D521/00
CPC分类号： C07C311/65 , A01N47/36 , C07C309/00 , C07D239/47 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 -C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 or 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

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