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1. 发明授权

US06433192B1 Method for producing mixtures of 1,4-butanediol, tetrahydrofuran and &ggr;-butyrolactone 失效
标题翻译：生产1,4-丁二醇，四氢呋喃和γ-丁内酯的混合物的方法
公开(公告)号：US06433192B1
公开(公告)日：2002-08-13
申请号：US09673847
申请日：2001-06-04
申请人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
发明人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
IPC分类号： C07D30702
CPC分类号： C07D315/00 , C07C29/149 , C07D307/08 , C07C31/207
摘要： In a process for preparing 1,4-butanediol, tetrahydrofuran and &ggr;-butyrolactone by oxidation of butane to give a product stream comprising maleic anhydride, absorption of maleic anhydride from the product stream using a high-boiling alcohol to give a liquid absorption product comprising monoesters and diesters of maleic acid and also high-boiling alcohol, after-esterification of the liquid absorption product and subsequent hydrogenation of the after-esterified product in the liquid phase, the high-boiling alcohol is a polyhydric alcohol having a boiling point at atmospheric pressure of above 233° C. and the after-esterified product has an acid number of less than 30 mg KOH/g and a water content of less than 1% by weight.
摘要翻译：在通过丁烷氧化制备1,4-丁二醇，四氢呋喃和γ-丁内酯以产生包含马来酸酐的产物流的方法中，使用高沸点醇从产物流中吸收马来酸酐，得到液体吸收产物，其包含马来酸的单酯和二酯以及高沸点醇，液体吸收产物的酯化和后期酯化产物在液相中的氢化后，高沸点醇是沸点在大气压下的多元醇高于233℃的压力，后酯化产物的酸值小于30mg KOH / g，水含量小于1重量％。

2. 发明授权

US06350924B1 Method for producing 1,4-butanediol 有权
标题翻译：生产1,4-丁二醇的方法
公开(公告)号：US06350924B1
公开(公告)日：2002-02-26
申请号：US09673134
申请日：2000-10-11
申请人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
发明人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
IPC分类号： C07C2700
CPC分类号： C07D315/00 , C07C29/177 , C07D307/08 , C07C31/207
摘要： A process for preparing 1,4-butanediol and, if desired, &ggr;-butyrolactone and THF by oxidizing butane or benzene to form a product stream including maleic anhydride, absorbing maleic anhydride from the product stream with a high-boiling inert solvent in an absorption stage to give a liquid absorption product, esterifying the liquid absorption product with a C1-C5 esterifying alcohol in an esterification stage to form an esterification product comprising the corresponding diester and high-boiling inert solvent, then hydrogenating the esterification product to give a hydrogenation product which comprises the products of value, 1,4-butanediol and, if desired, &ggr;-butyrolactone and tetrahydrofuran and the esterifying alcohol and which is separated by distillation into the products of value and the esterifying alcohol, and recycling the esterifying alcohol to the esterification zone, which comprises separating the esterification product into the diester and the inert solvent by distillation under reduced pressure prior to the hydrogenation, recycling the inert solvent to the absorption stage, and hydrogenating the diester in the liquid phase over a fixed-bed catalyst.
摘要翻译：通过氧化丁烷或苯来制备1,4-丁二醇和（如果需要的话）γ-丁内酯和THF以形成包含马来酸酐的产物流的方法，在吸收中用高沸点惰性溶剂从产物流中吸收马来酸酐阶段以得到液体吸收产物，在酯化阶段用C1-C5酯化醇酯化液体吸收产物以形成包含相应的二酯和高沸点惰性溶剂的酯化产物，然后氢化酯化产物得到氢化产物其包括价值的产物，1,4-丁二醇，如果需要的话，γ-丁内酯和四氢呋喃和酯化醇，并通过蒸馏分离成产物和酯化醇，并将酯化醇再循环到酯化反应其包括通过蒸馏分离酯化产物成二酯和惰性溶剂在氢化之前在减压下进行反应，将惰性溶剂循环到吸收阶段，并在固定床催化剂中使液相中的二酯氢化。

3. 发明授权

US5965751A Process for hydrogenation of dihydrofurans to give tetrahydrofurans 失效
标题翻译：二氢呋喃氢化制得四氢呋喃的方法
公开(公告)号：US5965751A
公开(公告)日：1999-10-12
申请号：US68978
申请日：1998-05-22
申请人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
发明人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
IPC分类号： B01J37/02 , C07D307/08 , C23C14/16 , B01J23/44
CPC分类号： C07D307/08 , B01J37/0225 , B01J37/0238 , C23C14/16
摘要： In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.
摘要翻译： PCT No.PCT / EP96 / 05071 Sec。 371日期：1998年5月22日 102（e）日期1998年5月22日PCT 1996年11月18日PCT公布。第WO97 / 19939号公报日期：1997年6月5日在用氢气将2,5-和2,3-二氢呋喃催化氢化得到四氢呋喃的方法中，使用其中通过气相沉积沉积金属或多种金属的催化剂或溅射在金属丝网或金属箔上作为载体。

4. 发明授权

US06831182B2 Method for the hydrogenation of maleic anhydride and related compounds in two serial reaction zones 有权
公开(公告)号：US06831182B2
公开(公告)日：2004-12-14
申请号：US10433424
申请日：2003-06-04
申请人： Holger Borchert , Stephan Schlitter , Rolf-Hartmuth Fischer , Markus Rösch , Frank Stein , Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
发明人： Holger Borchert , Stephan Schlitter , Rolf-Hartmuth Fischer , Markus Rösch , Frank Stein , Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
IPC分类号： C07D30708
CPC分类号： C07D307/08
摘要： The present invention relates to a process for the gas-phase hydrogenation of C4-dicarboxylic acids and/or their derivatives over a catalyst based on copper oxide to give substituted or unsubstituted &ggr;-butyrolactone and/or tetrahydrofuran, which comprises, which a first reaction zone in which the C4-dicarboxylic acid and/or its derivatives is/are reacted to give a mixture comprising a substituted or unsubstituted &ggr;-butyrolactone as main product and a subsequent second reaction zone in which the substituted or unsubstituted &ggr;-butyrolactone present in the mixture from the first hydrogenation step is reacted at a temperature lower than the temperature in the first hydrogenation step to give substituted or unsubstituted tetrahydrofuran.

5. 发明授权

US06846389B2 Method for distillative separation of mixtures containing tetrahydrofuran, γ-butyrolactone and/or 1,4-butanediol 有权
标题翻译：用于蒸馏分离含有四氢呋喃，γ-丁内酯和/或1,4-丁二醇的混合物的方法
公开(公告)号：US06846389B2
公开(公告)日：2005-01-25
申请号：US10258938
申请日：2001-05-03
申请人： Gerd Kaibel , Alexander Weck , Ralf-Thomas Rahn
发明人： Gerd Kaibel , Alexander Weck , Ralf-Thomas Rahn
IPC分类号： B01D3/14 , B01D3/26 , C07C27/28 , C07C29/80 , C07C31/20 , C07D307/08 , C07D307/33 , B01D3/42
CPC分类号： C07D307/33 , B01D3/14 , B01D3/141 , B01D3/146 , C07C29/80 , C07D307/08 , Y10S203/09 , Y10S203/20 , C07C31/207
摘要： In a process for the continuous fractional distillation of mixtures comprising tetrahydrofuran, γ-butyrolactone and/or 1,4-butanediol to give at least three fractions, the fractionation is carried out in an assembly of distillation columns comprising at least one dividing wall column or at least one assembly of thermally coupled conventional distillation columns.
摘要翻译：在包括四氢呋喃，γ-丁内酯和/或1,4-丁二醇的混合物的连续分馏的方法中，得到至少三个级分，分馏在包括至少一个分隔壁塔或至少一个热偶联常规蒸馏塔的组件。

6. 发明授权

US06921830B2 Method for purifying an organic solvent for the purposes of absorption of maleic acid anhydride 失效
标题翻译：纯化有机溶剂以吸收马来酸酐的方法
公开(公告)号：US06921830B2
公开(公告)日：2005-07-26
申请号：US10475219
申请日：2002-04-22
申请人： Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
发明人： Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
IPC分类号： C07D307/60 , C07C51/215 , C07C51/44 , C07C51/573 , C07C57/145 , C07C57/15 , C07D307/36
CPC分类号： C07C51/215 , C07C51/573 , C07C57/145
摘要： In a process for purifying an organic solvent for the absorption of maleic anhydride from a gaseous mixture, in which the maleic anhydride is separated off from the solvent, a substream is taken from the solvent stream, this substream is distilled and returned to the solvent circuit, the proposed improvement comprises separating off a low-boiling fraction and a high-boiling fraction from the fraction consisting essentially of purified solvent and feeding the fraction consisting essentially of purified solvent back into the solvent stream.
摘要翻译：在从溶剂中分离马来酸酐的气体混合物中纯化用于吸收马来酸酐的有机溶剂的方法中，从溶剂流中取出一个子流，蒸馏该子流并返回溶剂回路所提出的改进包括从基本上由纯化溶剂组成的馏分中分离低沸点馏分和高沸点馏分，并将基本上由纯化溶剂组成的馏分反馈回溶剂流中。

7. 发明授权

US06054628A Reacting Grignard compounds with carbonyl compounds and ensuing hydrolysis 失效
标题翻译：用羰基化合物反应格利雅化合物，随后进行水解
公开(公告)号：US06054628A
公开(公告)日：2000-04-25
申请号：US955076
申请日：1997-10-21
申请人： Manfred Stroezel , Udo Rheude , Ralf-Thomas Rahn , Gerd Kaibel
发明人： Manfred Stroezel , Udo Rheude , Ralf-Thomas Rahn , Gerd Kaibel
IPC分类号： C07B49/00 , C07C29/124 , C07C29/40 , C07C31/00 , C07C33/02 , C07C35/18
CPC分类号： C07C29/40
摘要： In a process for carrying out an exothermal reaction, selected from the addition reaction of organomagnesium halide compounds to carbonyl compounds and the ensuing hydrolysis of the addition product, a considerable fraction of the heat liberated during the reaction is removed by evaporation of the solvent.
摘要翻译：在进行放热反应的方法中，选自有机卤化镁化合物与羰基化合物的加成反应以及随后的加成产物的水解，通过蒸发溶剂除去反应期间释放出的相当大部分的热量。

8. 发明申请

US20090143601A1 METHOD FOR PREVENTING FUMARIC ACID DEPOSITS IN THE PRODUCTION OF MALEIC ACID ANHYDRIDE 审中-公开
标题翻译：在制备马来酸酐时防止含氟酸沉积物的方法
公开(公告)号：US20090143601A1
公开(公告)日：2009-06-04
申请号：US12300571
申请日：2007-05-16
申请人： Rolf Pinkos , Gerd Kaibel , Ellen Dahlhoff , Gunther Windecker , Jens Heimann
发明人： Rolf Pinkos , Gerd Kaibel , Ellen Dahlhoff , Gunther Windecker , Jens Heimann
IPC分类号： C07D307/60
CPC分类号： C07C51/573 , C07C57/145
摘要： The present invention provides a process for preventing fumaric acid deposits in the preparation of maleic anhydride, comprising the following steps:a) absorption of a C4-dicarboxylic acid or of a derivative from a crude product mixture into an organic solvent or water as an absorbent,b) removal of the C4-dicarboxylic acid or of a derivative from the absorbent,the absorbent thus recovered being catalytically hydrogenated fully or partly and recycled fully or partly into the absorption stage (a).
摘要翻译：本发明提供了一种在制备马来酸酐中防止富马酸沉积的方法，包括以下步骤：a）将C4-二羧酸或衍生物从粗产物混合物中吸收到作为吸收剂的有机溶剂或水中 b）从吸收剂中除去C4-二羧酸或衍生物，这样回收的吸收剂被完全或部分催化氢化，或者完全或部分地再循环到吸收阶段（a）中。

9. 发明授权

US06262317B1 Process for preparing 1,4-butanediol by catalytic hydrogenation of 1,4-butinediol 有权
标题翻译：通过1,4-丁二醇的催化氢化制备1,4-丁二醇的方法
公开(公告)号：US06262317B1
公开(公告)日：2001-07-17
申请号：US09284209
申请日：1999-04-09
申请人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
发明人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
IPC分类号： C07C2700
CPC分类号： C07C29/172 , B01J8/025 , B01J8/0278 , B01J8/06 , B01J8/065 , B01J19/006 , B01J19/2465 , B01J19/249 , B01J19/26 , B01J2208/00283 , B01J2208/021 , B01J2219/00103 , B01J2219/0011 , B01J2219/00777 , B01J2219/185 , B01J2219/1943 , B01J2219/2462 , B01J2219/2469 , B01J2219/2474 , B01J2219/2477 , B01J2219/2479 , B01J2219/2481 , B01J2219/30 , B01J2219/30475 , C07C31/207
摘要： A process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butynediol comprises reacting 1,4-butynediol with hydrogen in the liquid continuous phase in the presence of a heterogeneous hydrogenation catalyst at from 20 to 300° C., a pressure of from 1 to 200 bar and values of the liquid-side volumetric mass transfer coefficient kLa of from 0.1 s−1 to 1 s−1 a) using a catalyst suspended in the reaction medium, where if a packed bubble column is employed this is operated in the upflow mode and at a ratio of gas leaving the reaction vessel to gas fed to the reaction vessel of from 0.99:1 to 0.4:1, or b) passing the liquid and gas in cocurrent in an upward direction through a fixed-bed reactor operated in the gas-circulation mode while maintaining a ratio of the gas fed to the reaction vessel to gas leaving the reaction vessel of from 0.99:1 to 0.4:1.
摘要翻译：通过1,4-丁炔二醇的连续催化氢化制备1,4-丁二醇的方法包括在非均相氢化催化剂存在下，在20-300℃下，使1,4-丁炔二醇与液体连续相中的氢反应，使用悬浮在反应介质中的催化剂，1至200巴的压力和液体侧体积传质系数kLa的值为0.1s-1至1s-1a），其中如果使用填充气泡塔，则在向上流动模式下操作，并且以从0.99:1至0.4:1的气体流入反应容器的气体的比率），使液体和气体沿向上的方向并流通过固定 - 在气体循环模式下操作的床反应器，同时保持供给反应容器的气体与离开反应容器的气体的比例为0.99:1至0.4:1。

10. 发明申请

US20140061020A1 DEVICES AND METHOD FOR CONTINUOUS DISTILLATIVE SEPARATION OF A MIXTURE CONTAINING ONE OR MORE ALKANOLAMINE(S) 有权
标题翻译：含有一种或多种烷基胺的混合物的连续分离的装置和方法（S）
公开(公告)号：US20140061020A1
公开(公告)日：2014-03-06
申请号：US14057017
申请日：2013-10-18
申请人： Willi Schmidt , Gerd Kaibel , Elke Geißler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
发明人： Willi Schmidt , Gerd Kaibel , Elke Geißler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
IPC分类号： B01D3/32
CPC分类号： B01D3/32 , B01D3/14 , B01D3/42 , C07C213/04 , C07C213/10 , Y02P20/582 , C07C215/08 , C07C215/10
摘要： Apparatus and processes for continuous distillative separation of a mixture comprising one or more alkanolamine(s) are described. The separation is performed in one or more dividing wall column(s) and the alkanolamine or the alkanolamines is/are withdrawn as a side draw stream or side draw streams (side fraction(s)).
摘要翻译：描述了包含一种或多种链烷醇胺的混合物的连续蒸馏分离的装置和方法。分离在一个或多个分隔壁柱中进行，并且链烷醇胺或链烷醇胺作为侧馏分流或侧馏分流（侧馏分）排出。

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