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1. 发明申请

US20050096406A1 Reactive diluents and alkyd resin coating compositions 审中-公开
标题翻译：活性稀释剂和醇酸树脂涂料组合物
公开(公告)号：US20050096406A1
公开(公告)日：2005-05-05
申请号：US10504239
申请日：2003-02-25
申请人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
发明人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
IPC分类号： C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C09D4/00 , C09D5/00 , C09D7/00 , C09D7/12 , C09D11/02 , C09D11/10 , C09D167/08 , C08G2/00
CPC分类号： C09D11/101 , C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C07C2601/08 , C07C2602/22 , C09D167/08
摘要： The invention relates to new reactive diluents of the formulae (Ia, Ib, Ic, Id, Ie) and to an alkyd coating composition comprising them. In a preferred embodiment R1 and R2 are hydrogen; R3 is (meth)acryloyloxy-methyl or phenyl para substituted by vinyl, R4 is phenyl or phenyl para substituted by vinyl or (meth)acryloyloxy; or a substituted phenyl residue of the formula —C6H4CH2—W, wherein W is (meth)acryloyloxy, or an aliphatic residue of the formula —CH2—Y-A, wherein Y is a bond, O—C1-C12alkylene, wherein the alkylene linker is linear or branched and may be interrupted once or more than once by oxygen, A is hydroxy, C1-C6alkoxy, acetoxy, (meth)acryloyloxy, or a phthalate- or maleate-residue; R5 is hydrogen; n is 1; X is —(CH2)—. The invention further relates to a solvent-based or water-based alkyd coating composition comprising 0.3 to 10 wt. % of a mono-, bis- or trisacylphosphinoxide photoinitiator, especially Irgacure 819.
摘要翻译：本发明涉及式（Ia，Ib，Ic，Id，Ie）的新型反应性稀释剂和包含它们的醇酸树脂涂料组合物。在优选的实施方案中，R 1和R 2是氢; R 3是（甲基）丙烯酰氧基 - 甲基或被乙烯基取代的对苯基，R 4是苯基或被乙烯基或（甲基）丙烯酰氧基取代的对苯基; 或式-C 6 H 2 CH 2 -W的取代的苯基，其中W是（甲基）丙烯酰氧基或脂族基式-CH 2 -YA的残基，其中Y是一个键，OC 1 -C 12亚烷基，其中亚烷基接头是直链的或分支，并且可以被氧中断一次或多于一次，A是羟基，C 1 -C 6烷氧基，乙酰氧基，（甲基）丙烯酰氧基或邻苯二甲酸酯 - 或马来酸盐残基; R 5是氢; n为1; X是 - （CH 2） - 。本发明还涉及一种溶剂型或水性醇酸涂料组合物，其包含0.3至10wt。％的单，双或三酰基次膦酰基光引发剂，特别是Irgacure 819。

2. 发明申请

US20060160950A1 Pigment compositions with modified ATRP copolymer dispersants 有权
标题翻译：具有改性ATRP共聚物分散剂的颜料组合物
公开(公告)号：US20060160950A1
公开(公告)日：2006-07-20
申请号：US11387020
申请日：2006-03-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08L53/00 , C08K5/07 , C08K5/16
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are prepared by atom transfer radical polymerisation (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

3. 发明申请

US20050004317A1 Pigment compositions with modified atrp copolymer dispersants 审中-公开
标题翻译：具有改性的atrp共聚物分散剂的颜料组合物
公开(公告)号：US20050004317A1
公开(公告)日：2005-01-06
申请号：US10495519
申请日：2002-11-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08F2/38 , C08F4/40 , C08F293/00 , C08K3/00 , C08K5/00 , C08L53/00 , C09D7/12 , C09D11/02 , C09D17/00 , C09D153/00 , C09J11/00
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigment. The block copolymers are prepared by atom transfer radical polymerization (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

4. 发明申请

US20080280070A1 Coating Compositions Containing Levelling Agents Prepared by Nitroxyl Mediated Polymerisation 有权
标题翻译：包含由硝酸酯介导的聚合制备的流平剂的涂料组合物
公开(公告)号：US20080280070A1
公开(公告)日：2008-11-13
申请号：US10581137
申请日：2004-12-01
申请人： Ralf Knischka , Clemens Auschra , Andreas Muhlebach , Sevgi Zeren
发明人： Ralf Knischka , Clemens Auschra , Andreas Muhlebach , Sevgi Zeren
IPC分类号： C09D133/10 , B05D3/00 , C09D133/24 , C09D133/02
CPC分类号： C09D5/033 , C08L57/12 , C08L2201/00 , C09D7/47
摘要： The present invention relates to coating compositions containing a polymeric or copolymeric levelling agent, which has been prepared by nitroxyl-mediated polymerisation. Further aspects are a process for the preparation of smooth surface coatings and the use of said polymer or copolymer as levelling agent in coating compositions. Yet another aspect are specific ethylenically unsaturated monomer compositions from which copolymers can be obtained by atom transfer radical polymerisation or nitroxyl mediated polymerisation, which copolymers are useful as levelling agents in coating compositions. Still another aspect is the use of poly-tert.-butyl acrylate or poly-tert.butylmethacrylate as a levelling agent in powder coating compositions.
摘要翻译：本发明涉及包含通过硝酰基介导的聚合制备的聚合物或共聚物流平剂的涂料组合物。另外的方面是制备光滑表面涂层的方法以及所述聚合物或共聚物作为涂料组合物中的流平剂的用途。另一方面是特定的烯键式不饱和单体组合物，其可通过原子转移自由基聚合或硝酰基介导的聚合获得共聚物，该共聚物可用作涂料组合物中的流平剂。另一方面是在粉末涂料组合物中使用聚丙烯酸叔丁酯或聚 - 叔丁基甲基丙烯酸酯作为流平剂。

5. 发明申请

US20090076198A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090076198A1
公开(公告)日：2009-03-19
申请号：US11665627
申请日：2005-10-17
申请人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
发明人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
IPC分类号： B32B5/16 , C08K5/00 , C08K5/34 , C08K5/45 , C08K5/15 , C08K5/51 , C08K5/53 , B05D3/02
CPC分类号： C09D7/63 , C01P2002/84 , C01P2002/88 , C01P2004/64 , C08K9/06 , C09C1/3081 , C09C1/40 , C09C1/407 , C09D7/48 , Y10T428/2982
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.
摘要翻译：本发明公开了在表面上包含共价结合的式（I）基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3纳米颗粒，其中通式符号如权利要求1中所定义。这些官能化纳米颗粒是例如在有机材料中用作稳定剂和/或增容剂，或作为预聚物或预交联制剂中的光引发剂，或用作表面涂料组合物中涂料的增强剂和耐划伤性改进剂。

6. 发明申请

US20070093576A1 Reinforced coatings with improved scratch resistance 审中-公开
标题翻译：具有改善耐刮擦性的增强涂层
公开(公告)号：US20070093576A1
公开(公告)日：2007-04-26
申请号：US10574766
申请日：2004-10-06
申请人： Martin Albrecht , Tunja Jung , Andreas Muhlebach
发明人： Martin Albrecht , Tunja Jung , Andreas Muhlebach
IPC分类号： B60C1/00
CPC分类号： C08K3/01 , C08K3/36 , C09D7/60 , C09D7/61 , C09D7/67 , C09D7/68
摘要： The instant invention discloses a coating composition comprising a) an organic film-forming binder, and b) an inorganic additive of small particle size dispersed in an aqueous or alcoholic solvent prepared by a process which comprises the hydrolysis of a metal alcoholate or a compound of the formula (I) in which R1 is C1-C8alkyl, C5-C8cycloalkyl, phenyl or C1-C4alkyl substituted phenyl; R2 is C1-C8salkyl, and n is 0, 1, 2 or 3; with a base. These coatings for protecting surfaces are reinforced and show improved scratch resistance.
摘要翻译：本发明公开了一种涂料组合物，其包含a）有机成膜粘合剂，和b）分散在水溶液或醇溶剂中的小粒径的无机添加剂，该无机添加剂通过包括水解金属醇化物或其中R 1是C 1 -C 8烷基，C 5 -C 6烷基的式（I）苯基或C 1 -C 4烷基取代的苯基; C 1 -C 4烷基取代的苯基; R 2是C 1 -C 8烷基，n是0,1,2或3; 与一个基地。这些用于保护表面的涂层被加强并显示出改善的耐划伤性。

7. 发明授权

US6162883A Catalyst mixture and polymerizable composition 失效
标题翻译：催化剂混合物和可聚合组合物
公开(公告)号：US6162883A
公开(公告)日：2000-12-19
申请号：US155561
申请日：1998-09-30
申请人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
发明人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
IPC分类号： B01J31/24 , C08G61/08 , C08G61/12 , C09D145/00
CPC分类号： C08G61/12 , C08G61/08 , Y10T428/2991 , Y10T428/2993 , Y10T428/31678
摘要： A mixture of at least one thermal carbene-free ruthenium catalyst A and at least one thermal ruthenium carbene catalyst B, both of which initiate the ring-opening metathesis polymerization on their own, said catalysts being present in a weight ratio of A to B from 10:1 to 1:10. By adding this mixture even in small amounts, the ring-opening metathesis polymerization of strained cycloolefins can be effectively catalyzed.
摘要翻译： PCT No.PCT / EP97 / 01579 Sec。 371日期：1998年9月30日 102（e）1998年9月30日PCT PCT 1997年3月27日PCT公布。公开号WO97 / 38036 日期1997年10月16日将至少一种不含热不卡宾的钌催化剂A和至少一种热钌卡宾催化剂B的混合物二者自身引发开环易位聚合，所述催化剂以重量比存在的A到B从10：1到1:10。通过少量加入该混合物，可以有效催化应变环烯烃的开环易位聚合。

8. 发明授权

US6100323A Curable composition comprising a diels-alder-adduct of cyclopentadiene and a filler 失效
标题翻译：包含环戊二烯的二醇 - al - 加合物和填料的可固化组合物
公开(公告)号：US6100323A
公开(公告)日：2000-08-08
申请号：US812231
申请日：1997-03-06
申请人： Frans Setiabudi , Andreas Muhlebach , Yoshiaki Naganuma
发明人： Frans Setiabudi , Andreas Muhlebach , Yoshiaki Naganuma
IPC分类号： C07C2/50 , C08G61/08 , C08L65/00 , H01B3/30 , C08J3/28
CPC分类号： H01B3/30 , C08G61/08
摘要： A composition, comprising(a) a Diels-Alder-adduct of cyclopentadiene,(b) a catalyst for the ring-opening metathesis polymerisation, and(c) 2-95% by weight of a filler, based on the entire composition,the filler containing at least 0.5% by weight of a basic adsorbent, based on the entire composition,gives cured products having excellent mechanical and electrical properties and is particularly suitable as coating material for electrical and electronic components.
摘要翻译：一种组合物，其包含（a）环戊二烯的狄尔斯 - 阿尔德加合物，（b）用于开环易位聚合的催化剂，和（c）基于整个组合物的2-95重量％的填料，含有至少0.5重量％碱性吸附剂的填料基于整个组合物，得到具有优异的机械和电学性能的固化产物，并且特别适合作为电气和电子部件的涂料。

9. 发明授权

US5861443A Polymerizable composition and process for polymerizing cyclical olefins 失效
标题翻译：用于聚合循环烯烃的可聚合组合物和方法
公开(公告)号：US5861443A
公开(公告)日：1999-01-19
申请号：US836422
申请日：1997-05-14
申请人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Muhlebach
发明人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Muhlebach
IPC分类号： B05D7/24 , B32B27/32 , C08F2/48 , C08G61/00 , C08G61/08 , C08G61/12 , C09D165/00 , C08F32/00 , C08F34/00
CPC分类号： C08G61/12 , C08G61/08
摘要： Process for the photocatalytic polymerization of a cyclical olefin or at least two different cyclical olefins in the presence of a metal compound as the catalyst, which is characterized in that a photochemical ring-opening metathesis polymerization is carried out in the presence of a catalytic amount of at least one carbene-free, bivalent-cationic ruthenium or osmium compound which contains at least one phosphine group, at least one photolabile ligand, and optionally neutral ligands bonded to the metal atom, a total of 2 or 3 ligands being bonded, and which contains acid ions for balancing the charge. The process can also be carried out by first carrying out the irradiation and ending the polymerization by heating. The process is suitable, for example, for the preparation of thermoplastics shaping compounds and the production of coatings and images in relief.
摘要翻译： PCT No.PCT / EP95 / 04362 Sec。 371日期1997年5月14日 102（e）日期1997年5月14日PCT提交1995年11月6日PCT公布。 WO96 / 16103 PCT出版物日期1996年5月30日在金属化合物作为催化剂存在下，循环烯烃或至少两种不同的环状烯烃的光催化聚合方法，其特征在于光化学开环易位聚合在催化量的至少一种不含有碳原子的二价阳离子钌或锇化合物，其含有至少一个膦基，至少一个光不稳定配体和任选的与该金属原子结合的中性配体，总共有2或3个配体是并且含有用于平衡电荷的酸性离子。该方法也可以首先进行照射并通过加热结束聚合。该方法适用于例如制备热塑性塑料成型化合物以及缓解涂料和图像的生产。

10. 发明授权

US5391681A Curable compositions based on epoxy resins or mixtures of epoxy resins and polyisocyanates containing trisimidazolyl triazines 失效
标题翻译：基于环氧树脂的固化组合物或含有三咪唑基三嗪的环氧树脂和多异氰酸酯的混合物
公开(公告)号：US5391681A
公开(公告)日：1995-02-21
申请号：US68376
申请日：1993-05-27
申请人： Andreas Muhlebach , Peter Flury
发明人： Andreas Muhlebach , Peter Flury
IPC分类号： C07D403/14 , C07D521/00 , C08G18/00 , C08G18/20 , C08G18/58 , C08G18/65 , C08G59/40 , C08G59/50 , C08G59/68 , C08L63/00 , C08G59/00 , C08K5/29 , C08K5/3445 , C08K5/3492 , C08L75/00
CPC分类号： C07D403/14 , C07D231/12 , C07D233/56 , C07D249/08 , C08G18/003 , C08G18/2081 , C08G18/58 , C08G59/4028 , C08G59/686 , C08G2270/00
摘要： Curable compositions based on epoxy resins or a mixture of epoxy resins and polyisocyanates and containing at least one compound of formula I: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently of one another hydrogen, alkyl, aryl, arylalkyl or halogen, and R.sub.2 together with R.sub.3 and R.sub.5 together with R.sub.6 and R.sub.8 together with R.sub.9 may each also represent a fused benzene ring.The compositions have high reactivity and at the same time good storage stability.
摘要翻译：含有至少一种式I化合物的环氧树脂或环氧树脂和多异氰酸酯的混合物的固化组合物：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8和R 9各自为独立地是氢，烷基，芳基，芳基烷基或卤素，并且R 2与R 3和R 5以及R 6和R 8与R 9一起可以各自表示稠合苯环。该组合物具有高反应性，同时具有良好的储存稳定性。

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