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    • 4. 发明授权
    • Diffusion transfer photographic system utilizing substituted
phenylmercaptoazoles
    • 使用取代的苯基巯基的扩散转印照相系统
    • US4390613A
    • 1983-06-28
    • US222502
    • 1981-01-05
    • Avinash C. MehtaGeorge H. NawnLloyd D. Taylor
    • Avinash C. MehtaGeorge H. NawnLloyd D. Taylor
    • C07D257/04G03C8/00G03C8/08
    • G03C8/00Y10S430/161
    • There is disclosed a diffusion transfer photographic system wherein development of an exposed photosensitive element with an aqueous alkaline processing composition is effected in the presence of a compound represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety on said structure including substituted rings and fused rings; R is H, an alkali metal or a group which is cleavable in a photographic aqueous alkaline processing composition; and R.sub.1 is either a group which has a pKa of from about 7 to about 14 which is ionizable to an anion whereby the silver salt of the mercaptan (resulting from cleavage or ionization of --SR) is rendered more soluble in the pH range within which R.sub.1 is ionized to an anion than it is below that pH range, or a precursor of such a group.
    • 公开了一种扩散转移照相系统,其中用碱性处理组合物水溶液曝光的感光元件的显影是在式(ⅩⅧ)表示的化合物的存在下进行的,其中X表示形成核的必需的非金属原子, 所述结构上的5-或6-元杂环部分包括取代的环和稠环; R是H,碱金属或在照相水性碱性处理组合物中可裂解的基团; 并且R1是具有约7至约14的pKa的基团,其可离子化为阴离子,由此硫醇的银盐(由-SR的裂解或电离产生)在pH范围内变得更易溶于其中 R1比其低于该pH范围的阴离子电离,或这种基团的前体。
    • 9. 发明授权
    • Photographic compounds
    • 摄影化合物
    • US4946964A
    • 1990-08-07
    • US131911
    • 1987-12-11
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • Roger A. BoggsJohn B. MahoneyAvinash C. MehtaWilliam C. SchwarzelLloyd D. Taylor
    • C07D257/04G03C7/305G03C8/00
    • C07D257/04G03C7/30511G03C8/00Y02P20/55
    • There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound represented by the formula ##STR1## wherein R is --OH, --OR.sub.4, --NH.sub.2 --NHR.sub.5 or --NR.sub.4 R.sub.6 ; R.sub.1 is hydrogen, --NH.sub.2, alkyl, substituted alkyl, aryl or substituted aryl; R.sub.2 and R.sub.3 each independently is hydrogen, alkyl, aralkyl or aryl; R.sub.4 is a protecting group which can be removed in the presence of a base; R.sub.5 is an activating group which can render the neighboring hydrogen atom acidic; R.sub.6 is an electron withdrawing group which is capable of stabilizing the negative charge on the nitrogen atom which is produced upon removal of R.sub.4 upon contact with alkali; and PHOTO is a photographically useful group.The compounds provide controlled release of the photographically useful group by a base-catalyzed elimination when contacted by the aqueous alkaline processing composition.
    • 描述了一种摄影系统,其中用碱性照相显影组合物水溶液曝光的感光元件的显影是在下式表示的化合物的存在下进行:其中R是-OH,-OR4,-NH2-NHR5或 - NR4R6; R 1是氢,-NH 2,烷基,取代的烷基,芳基或取代的芳基; R2和R3各自独立地是氢,烷基,芳烷基或芳基; R4是可以在碱存在下除去的保护基; R5是可使相邻氢原子呈酸性的活化基团; R6是能够稳定在与碱接触时除去R4时产生的氮原子上的负电荷的吸电子基团; 而PHOTO是一个摄影有用的组。 当通过碱性水溶液处理组合物接触时,这些化合物通过碱催化消除提供对照相有用基团的控制释放。