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1. 发明授权

US4894380A 2-mercapto-5-pyridyl-1,3,4-oxadiazoles and 2-mercapto-5-pyridyl-1,3,4-thiadiazoles of the formula I 失效
标题翻译： 2-巯基-5-吡啶基-1,3,4-恶二唑和式I的2-巯基-5-吡啶基-1,3,4-噻二唑
公开(公告)号：US4894380A
公开(公告)日：1990-01-16
申请号：US176483
申请日：1988-03-25
申请人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger , Odd Kristiansen
发明人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger , Odd Kristiansen
IPC分类号： A01N43/82 , A01N43/824 , C07D413/04 , C07D417/04
CPC分类号： C07D413/04 , A01N43/82 , C07D417/04
摘要： The invention relates to 2-mercapto-5-pyridyl-1,3,4-oxadiazoles and 2-mercapto-5-pyridyl-1,3,4-thiadiazoles of the formula I ##STR1## wherein X is oxygen or sulfur,R' is C.sub.1 -C.sub.3 alkyl which is substituted by bromine, fluorine, C.sub.1 -C.sub.3 alkoxy or cyano; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; unsubstituted or halogen-substituted C.sub.4 -C.sub.7 alkynyl,R is C.sub.1 -C.sub.3 alkyl, unsubstituted C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkoxy which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; C.sub.3 -C.sub.7 alkynyl, C.sub.1 -C.sub.3 alkylthio, halogen, cyano, hydroxy, amino or amino which is substituted by one or two C.sub.1 -C.sub.3 alkyl groups; or is aminocarbonyl; andn is 0, 1, 2, 3 or 4,to the preparation of the compounds of formula I and to novel intermediates for the synthesis of these compounds. The compounds of formula I have nematicidal properties. The invention further relates to nematicidal compositions which contain at least one compound of formula I as active component, and to methods of using said compounds and of the compositions containing them for controlling nematodes.
摘要翻译：本发明涉及式I的2-巯基-5-吡啶基-1,3,4-恶二唑和2-巯基-5-吡啶基-1,3,4-噻二唑，其中X是氧或硫，R'是被溴，氟，C 1 -C 3烷氧基或氰基取代的C 1 -C 3烷基; 未取代或卤素取代的C 3 -C 7链烯基; 未取代的或卤素取代的C4-C7炔基，R是C1-C3烷基，未取代的C1-C3烷氧基或被卤素或C1-C3烷氧基取代的C1-C3烷氧基; 未取代或卤素取代的C 3 -C 7链烯基; 被一个或两个C 1 -C 3烷基取代的C 3 -C 7炔基，C 1 -C 3烷硫基，卤素，氰基，羟基，氨基或氨基; 或是氨基羰基; 和n为0,1,2,3或4，用于制备式I化合物和用于合成这些化合物的新中间体。式I的化合物具有杀线虫性质。本发明还涉及含有至少一种式I化合物作为活性组分的杀线虫组合物，以及使用所述化合物和含有它们的组合物控制线虫的方法。

2. 发明授权

US4861787A Nematicidal compositions 失效
标题翻译：杀线虫组合物
公开(公告)号：US4861787A
公开(公告)日：1989-08-29
申请号：US263961
申请日：1988-10-25
申请人： Ernst Beriger , Wolfgang Eckhardt , Robert Nyfeler
发明人： Ernst Beriger , Wolfgang Eckhardt , Robert Nyfeler
IPC分类号： A01N43/82 , A01N43/824 , C07D413/04 , C07D417/04
CPC分类号： C07D413/04 , A01N43/82 , C07D417/04
摘要： Novel compounds of the formula ##STR1## in which R' represents C.sub.1 -C.sub.5 -alkyl, halogen, trifluoromethyl or C.sub.1 -C.sub.3 -alkoxy;R" represents C.sub.1 -C.sub.5 -alkyl or halogen; andR"' represents C.sub.1 -C.sub.5 -alkyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms, C.sub.1 -C.sub.5 -alkenyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms, or C.sub.1 -C.sub.5 - alkynyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms;m represents 0, 1, 2 or 3 andn represents 0 or 1; andX.sub.1 and X.sub.2 each represents, independently of the other, oxygen or sulphur,as active ingredients for controlling plant parasite nematodes and for preventing damage to cultivated plants caused by nematode attack.
摘要翻译：式中，R'表示C 1 -C 5 - 烷基，卤素，三氟甲基或C 1 -C 3 - 烷氧基的新化合物＆lt; IMAGE＆gt; R“表示C 1 -C 5烷基或卤素; 和R“'表示未被取代或被1至6个卤素原子取代的C1-C5-烷基，未被取代或被1至6个卤素原子取代的C1-C5-烯基或C1-C5-炔基未被取代或被1至6个卤素原子取代; m表示0,1,2或3，n表示0或1; X1和X2各自独立地表示作为控制植物寄生线虫的活性成分的氧或硫，并且用于防止由线虫攻击引起的对栽培植物的损害。

3. 发明授权

US4861367A 2-Mercapto-5-pyrazinyl-1,3,4-oxadiazoles or 2-mercapto-5-pyrazinyl-1,3,4-thiadiazoles as nematicides 失效
标题翻译： 2-巯基-5-吡嗪基-1,3,4-恶二唑或2-巯基-5-吡嗪基-1,3,4-噻二唑作为杀线虫剂
公开(公告)号：US4861367A
公开(公告)日：1989-08-29
申请号：US172884
申请日：1988-03-25
申请人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger
发明人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger
IPC分类号： A01N43/82 , A01N43/824 , C07D413/04 , C07D417/04
CPC分类号： C07D413/04 , A01N43/82 , C07D417/04
摘要： 2-Mercapto-5-pyrazinyl-1,3,4-oxadiazoles and 2-mercapto-5-pyrazinyl-1,3,4-thiadiazoles of formula I ##STR1## wherein X is oxygen or sulfur,R' is C.sub.1 -C.sub.5 alkyl, unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or cyano; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkynyl,R is C.sub.1 -C.sub.3 alkyl, unsubstituted C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkoxy which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy; halogen, cyano, hydroxy, amino or amino which is substituted by one or two C.sub.1 -C.sub.3 alkyl groups; or is aminocarbonyl; andn is 0, 1, 2 or 3, the preparation thereof and novel intermediates for their synthesis are disclosed.The compounds of formula I have nematicidal properties. Nematicidal compositions which contain at least one compound of formula I as active ingredient, methods of using said compounds and of the compositions containing them for controlling nematodes are also disclosed.
摘要翻译： 2-巯基-5-吡嗪基-1,3,4-恶二唑和式I的2-巯基-5-吡嗪基-1,3,4-噻二唑其中X是氧或硫，R'是 C1-C5烷基，未取代或被卤素，C1-C3烷氧基或氰基取代; 未取代或卤素取代的C 3 -C 7链烯基; 未取代的或卤素取代的C3-C7炔基，R是C1-C3烷基，未取代的C1-C3烷氧基或被卤素或C1-C3烷氧基取代的C1-C3烷氧基; 卤素，氰基，羟基，氨基或被一个或两个C 1 -C 3烷基取代的氨基; 或是氨基羰基; 并且n为0,1,2或3，其制备及其合成的新中间体被公开。式I的化合物具有杀线虫性质。还公开了含有至少一种式I化合物作为活性成分的杀线虫剂组合物，使用所述化合物和含有它们的组合物用于控制线虫的方法。

4. 发明授权

US4262012A O-Methyl/ethyl-s-propyl/butyl-o-phenyl thiophosphates and dithiophosphates having an s-heterocyclic group on the phenyl ring 失效
标题翻译： O-甲基/乙基 - 正丙基/丁基邻苯基硫代磷酸酯和在苯环上具有s-杂环基的二硫代磷酸酯
公开(公告)号：US4262012A
公开(公告)日：1981-04-14
申请号：US751918
申请日：1976-12-17
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , A01N57/14 , A01N57/16 , C07F9/12 , C07F9/18 , A61K31/385 , A61K31/39 , C07D327/04 , C07D339/08
CPC分类号： C07F9/18 , A01N57/10
摘要： The invention relates to O,S-dialkyl-O-phenyl-thiophosphates and dithiophosphates of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl,R.sub.2 represents n-propyl, i-butyl or sec.-butyl,R.sub.3 and R.sub.4 each represents hydrogen, chlorine, bromine, methyl or ethyl,R.sub.5 represents a group of the formula ##STR2## X represents oxygen or sulfur, which compounds possess useful pesticidal, in particular acaricidal and insecticidal properties.
摘要翻译：本发明涉及下式的O，S-二烷基-O-苯基 - 硫代磷酸酯和二硫代磷酸酯，其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自代表氢，氯，溴，甲基或乙基，R 5表示下式的基团：X表示氧或硫，该化合物具有有用的杀虫剂，特别是杀螨和杀虫性质。

5. 发明授权

US4017612A Combatting insects and acarids with certain O-methyl/ethyl-S-propyl/butyl-O-phenyl-thiophosphates and -dithiophosphates 失效
标题翻译：用某些O-甲基/乙基-S-丙基/丁基-O-苯基 - 硫代磷酸酯和二硫代磷酸酯来防治昆虫和螨
公开(公告)号：US4017612A
公开(公告)日：1977-04-12
申请号：US578960
申请日：1975-05-19
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , A01N9/36
CPC分类号： A01N57/10 , C07F9/18
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents--OCOCH.sub.3, --O--C.sub.3 --C.sub.5 --alkenyl, --O--C.sub.3 --C.sub.5 --alkinyl, --O--C.sub.1 --C.sub.4 --alkylene-O--C.sub.1 --C.sub.4 --alkyl, --O--CH.sub.2 --CCl=CH.sub.2, --O--CH.sub.2 --CH=CHCl, ##STR2## --S--C.sub.3 --C.sub.5 --alkenyl, SCN, --CH.sub.2 --CCl=CH.sub.2, --CH.sub.2 CH=CHCl, --CHO, ##STR3## ##STR4## AND X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O -C 3 -C 5 - 烯基，-O-C 3 -C 5 - 炔基，-O-C 1 -C 4亚烷基-O-C 1 -C 4烷基，-O-CH 2 -CCl = CH 2，-O-CH 2 -CH = CHCl ，图像-S-C3-C5-烯基，SCN，-CH2-CCl = CH2，-CH2CH = CHCl，-CHO，

6. 发明授权

US3966921A Certain pesticidal phosphorus containing amidines 失效
标题翻译：某些农药含磷脒
公开(公告)号：US3966921A
公开(公告)日：1976-06-29
申请号：US574799
申请日：1975-05-05
申请人： Ernst Beriger , Odd Kristiansen , Kurt Rufenacht , Jorg Bader, deceased
发明人： Ernst Beriger , Odd Kristiansen , Kurt Rufenacht , Jorg Bader, deceased
IPC分类号： C07F9/24 , C07F9/44 , C07F9/59 , A01N9/36
CPC分类号： C07F9/591 , C07F9/2458 , C07F9/4465
摘要： Compounds of the formula ##EQU1## wherein R.sub.1 represents phenyl, or phenyl mono- to trisubstituted by halogen, mono- or disubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, nitro, cyano or trifluoromethyl, or monosubstituted by C.sub.1 -C.sub.4 -carbalkoxy,R.sub.2 represents methyl, methoxy, ethyl, ethoxy or phenyl,R.sub.3 represents hydrogen or methyl,R.sub.4 and R.sub.5 represent methyl, ethyl, n-propyl, isopropyl or allyl,X and Y represent oxygen or sulphur, orR.sub.4 and R.sub.5 with the nitrogen atom to which they are bound form the morpholino, piperidino or pyrrolidino ring, orR.sub.3 with R.sub.4 or R.sub.5 forms a 5- or 6-membered saturated ring, whereby then the group R.sub.4 or R.sub.5 not participating in the ring formation represents methyl or ethyl,A process for their manufacture and their use for the control of pests, especially for the control of phytopathogenic nematodes, are disclosed.
摘要翻译：化学式XR 2 PARALLEL R4 ANGLE PN = CN ANGLE R1Y|R5 R3其中R1表示苯基，或被卤素单取代或三取代的苯基，被C1-C4-烷基，C1-C4-烷硫基，硝基，氰基或三氟甲基，或被C1-C4-烷氧基单取代，R2代表甲基，甲氧基，乙基，乙氧基或苯基，R3代表氢或甲基，R4和R5代表甲基，乙基，正丙基，异丙基或烯丙基，X和Y 代表氧或硫，或者R 4和R 5与它们所连接的氮原子形成吗啉代，哌啶子基或吡咯烷子基环，或者R 3与R 4或R 5形成5或6元饱和环，其中R 4或 R5不参与环形成代表甲基或乙基，其制造方法及其用于控制污染物的用途，特别是用于控制生物病原体的生物体。

7. 发明授权

US3991141A O-methyl/ethyl-S-propyl/butyl-O-phenyl thiphosphates and dithiophosphates having a thioether group on the phenyl ring 失效
标题翻译：在苯环上具有硫醚基的O-甲基/乙基-S-丙基/丁基-O-邻苯二磷酸酯和二硫代磷酸酯
公开(公告)号：US3991141A
公开(公告)日：1976-11-09
申请号：US534591
申请日：1974-12-20
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , C07F9/12
CPC分类号： C07F9/18 , A01N57/10
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##SPC1##Wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents--OCOCH.sub.3, --O--C.sub.3 --C.sub.5 -alkenyl, --O--C.sub.3 --C.sub.5 -alkinyl, --O--C.sub.1 --C.sub.4 -alkylene-O--C.sub.1 --C.sub.4 -alkyl, --O--CH.sub.2 --CCl=CH.sub.2, --O--CH.sub.2 --CH=CHCl, ##EQU1##--S--C.sub.3 --C.sub.5 -alkenyl, SCN, --CH.sub.2 --CCl=CH.sub.2, --CH.sub.2 CH=CHCl, --CHO, ##SPC2##--CH=N--C.sub.1 --C.sub.4 -alkyl, --CH=N--NH--C.sub.1 --C.sub.4 -alkyl or X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：式II的硫代磷酸和二硫代磷酸酯，其中R1表示甲基或乙基，R2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O-C 3 - C5-烯基，-O-C3-C5-炔基，-O-C1-C4-亚烷基-O-C1-C4-烷基，-O-CH2-CCl = CH2，-O-CH2-CH = CHCl，-SCH2 -S-C 3 -C 5 - 烯基，SCN，-CH 2 -CCl = CH 2，-CH 2 CH = CHCl，-CHO，O -CH ANGLE，O -CH = N-C 1 -C 4烷基，-CH = C 1 -C 4 - 烷基或C 1 -C 4 - 烷基-CH = NN ANGLE和C 1 -C 4 - 烷基X代表氧或硫，其制备方法及其在害虫防治中的应用。

8. 发明授权

US3943202A O-methyl/ethyl-s-propyl/butyl-o-phenyl thiophosphates and dithiophosphates having an ether group or the phenyl ring 失效
标题翻译：具有醚基或苯环的O-甲基/乙基 - 正丙基/丁基邻苯基硫代磷酸酯和二硫代磷酸酯
公开(公告)号：US3943202A
公开(公告)日：1976-03-09
申请号：US534594
申请日：1974-12-20
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , C07F9/12
CPC分类号： A01N57/10 , C07F9/18
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##SPC1##Wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents ##EQU1## X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：式II的硫代磷酸和二硫代磷酸酯，其中R1表示甲基或乙基，R2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O-C 3 - C5-烯基，-O-C3-C5-炔基，-O-C1-C4-亚烷基-O-C1-C4-烷基，-O-CH2-CCl = CH2，-O-CH2-CH = CHCl，-SCH2 -S-C 3 -C 5 - 烯基，SCN，-CH 2 -CCl = CH 2，O -CH 2 CH = CHCl，-CHO，-CHOGLE，O O-CH 3 O-CH 3 -CHO | CH- ，O-CH 3 O-CH 3 | O-CH 3 O - -CH ANGLE |，-CH-角ANGLE，O-CH 3 O - S - OC 1 -C 4 - 烷基|，-CH ANGLE，-C ANGLE | S-OC 1 -C 4 - 烷基CH 3 SC 1 -C 4 - 烷基S- -CH ANGLE，-CH ANGLE |，SC 1 -C 4 - 烷基S- O-S- -CH ANGLE |，-CH角度，S- S- - CH 3 S-C 2 H 5 -CHORGLE |，-CH ANGLE |，S- S- -CH = N-C 1 -C 4 - 烷基，-CH = N-NH-C 1 -C 4 - 烷基或C 1 -C 4烷基 -CH = NN ANGLE C 1 -C 4 - 烷基，X代表氧或硫，它们的制备过程及其在害虫防治中的应用。

9. 发明授权

US3935233A O-methyl/ethyl-s-propyl/butyl-o-phenyl thiophosphates and dithiophosphates having an o-heterocyclic group or the phenyl ring 失效
标题翻译： O-甲基/乙基 - 正丙基/丁基邻苯基硫代磷酸酯和具有o-杂环基团或苯环的二硫代磷酸酯
公开(公告)号：US3935233A
公开(公告)日：1976-01-27
申请号：US534933
申请日：1974-12-20
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , C07D319/06 , A01N9/28
CPC分类号： C07F9/18 , A01N57/10 , Y10S514/949
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##SPC1##Wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents ##EQU1## AND X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：式II的硫代磷酸和二硫代磷酸酯，其中R1表示甲基或乙基，R2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O-C 3 - C5-烯基，-O-C3-C5-炔基，-O-C1-C4-亚烷基-O-C1-C4-烷基，-O-CH2-CCl = CH2，-O-CH2-CH = CHCl，-S -C 3 -C 5 - 烯基，SCN，-CH 2 -CCl = CH 2，O -CH 2 CH = CHCl，-CHO，-CHOGLE，OO-CH 3 O-CH 3 -CHOGLE |，-CH ANGLE |，O- CH 3 O-CH 3 | O-CH 3 O--CH ANGLE |，-CH-角ANGLE，O-CH 3 O-OC 1 -C 4 - 烷基-S -CH-，-C ANGLE |，OC 1 -C 4 - 烷基-S- C 1 -C 4烷基-S -CH-CH 2，-CH 2，-CH 2，-CH 2，-CH 2，-CH 2， SS--CH = N-C 1 -C 4 - 烷基-CH = N-NH-C 1 -C 4 - 烷基或C 1 -C 4烷基-CH = NN ANGLE C 1 -C 4烷基，X代表氧或硫，制造及其在病虫害防治中的应用。

10. 发明授权

US4140795A Pesticidal 1,3,5-triazapenta-1,4-dienes 失效
标题翻译：杀虫剂1,3,5-三氮杂-1,4-二烯
公开(公告)号：US4140795A
公开(公告)日：1979-02-20
申请号：US856369
申请日：1977-12-01
申请人： Manfred Boger , Odd Kristiansen , Ernst Beriger , Jozef Drabek , Dieter Durr , Kurt Rufenacht
发明人： Manfred Boger , Odd Kristiansen , Ernst Beriger , Jozef Drabek , Dieter Durr , Kurt Rufenacht
IPC分类号： A01N41/06 , C07C67/00 , C07C301/00 , C07C303/40 , C07C311/51 , C07C143/75 , A01N9/16
CPC分类号： A01N41/06
摘要： 1,3,5-Triazapenta-1,4-dienes of the formula ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl or cyano, and R.sub.4 represents C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, a process for their manufacture and their use in pest control.
摘要翻译：其中R 1，R 2和R 3各自表示氢，卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，三氟甲基或氰基，R 4表示C 1 -C 4烷基其是未取代的或被卤素取代的，其制备方法及其在害虫防治中的用途。

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