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    • 7. 发明授权
    • Process for forming a waterborne composite polyurethane/acrylic polymer dispersion
    • 形成水性复合聚氨酯/丙烯酸聚合物分散体的方法
    • US08153708B2
    • 2012-04-10
    • US12752372
    • 2010-04-01
    • Shanti Swarup
    • Shanti Swarup
    • C08J3/00
    • C08G18/0823C08G18/2825C08G18/4063C08G18/4238C08G18/6229
    • The present invention provides a process for forming a waterborne composite polyurethane/acrylic polymer dispersion without the use of N-methyl pyrrolidone. The process includes polymerizing a reaction mixture of polyisocyanate, polyol, and a hydroxyl and carboxylic acid functional reactant in an organic solvent medium of alkyl carbonate, then adding ethylenically unsaturated monomers and inverting the mixture into an aqueous medium. Addition polymerization is performed to yield a waterborne composite polyurethane/acrylic polymer dispersion, and any remaining alkyl carbonate is hydrolyzed. The resulting aqueous polymer dispersions are environmentally friendly and are suitable for use in coating compositions that conventionally contained similar dispersions prepared in the presence of N-methyl pyrrolidone. Comparable physical properties are observed.
    • 本发明提供了不使用N-甲基吡咯烷酮形成水性复合聚氨酯/丙烯酸类聚合物分散体的方法。 该方法包括将多异氰酸酯,多元醇和羟基和羧酸官能反应物的反应混合物聚合在碳酸烷基酯的有机溶剂介质中,然后加入烯属不饱和单体并将混合物倒入水性介质中。 进行加成聚合以产生水性复合聚氨酯/丙烯酸聚合物分散体,并且任何残留的碳酸烷基酯都被水解。 所得水性聚合物分散体是环境友好的,并且适用于常规含有在N-甲基吡咯烷酮存在下制备的相似分散体的涂料组合物。 观察到相当的物理性质。
    • 8. 发明申请
    • PROCESS FOR FORMING A WATERBORNE COMPOSITE POLYURETHANE/ACRYLIC POLYMER DISPERSION
    • 形成水性复合聚氨酯/丙烯酸聚合物分散体的方法
    • US20110245415A1
    • 2011-10-06
    • US12752372
    • 2010-04-01
    • Shanti Swarup
    • Shanti Swarup
    • C08G18/08
    • C08G18/0823C08G18/2825C08G18/4063C08G18/4238C08G18/6229
    • The present invention provides a process for forming a waterborne composite polyurethane/acrylic polymer dispersion without the use of N-methyl pyrrolidone. The process includes polymerizing a reaction mixture of polyisocyanate, polyol, and a hydroxyl and carboxylic acid functional reactant in an organic solvent medium of alkyl carbonate, then adding ethylenically unsaturated monomers and inverting the mixture into an aqueous medium. Addition polymerization is performed to yield a waterborne composite polyurethane/acrylic polymer dispersion, and any remaining alkyl carbonate is hydrolyzed. The resulting aqueous polymer dispersions are environmentally friendly and are suitable for use in coating compositions that conventionally contained similar dispersions prepared in the presence of N-methyl pyrrolidone. Comparable physical properties are observed.
    • 本发明提供了不使用N-甲基吡咯烷酮形成水性复合聚氨酯/丙烯酸类聚合物分散体的方法。 该方法包括将多异氰酸酯,多元醇和羟基和羧酸官能反应物的反应混合物聚合在碳酸烷基酯的有机溶剂介质中,然后加入烯属不饱和单体并将混合物倒入水性介质中。 进行加成聚合以产生水性复合聚氨酯/丙烯酸聚合物分散体,并且任何残留的碳酸烷基酯都被水解。 所得水性聚合物分散体是环境友好的,并且适用于常规含有在N-甲基吡咯烷酮存在下制备的相似分散体的涂料组合物。 观察到相当的物理性质。