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1. 发明授权

US5189192A Process for preparing addition polymerization catalysts via metal center oxidation 失效
标题翻译：通过金属中心氧化制备添加剂聚合催化剂的方法
公开(公告)号：US5189192A
公开(公告)日：1993-02-23
申请号：US642111
申请日：1991-01-16
申请人： Robert E. LaPointe , Robert K. Rosen , Peter N. Nickias
发明人： Robert E. LaPointe , Robert K. Rosen , Peter N. Nickias
IPC分类号： C08F4/643 , C07F17/00 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/6592 , Y10S526/943
摘要： Addition polymerization catalysts comprising a derivative of a Group 4-8 metal compound prepared by metal center oxidation.

2. 发明授权

US5721185A Homogeneous olefin polymerization catalyst by abstraction with lewis acids 失效
标题翻译：均相烯烃聚合催化剂与路易斯酸的萃取
公开(公告)号：US5721185A
公开(公告)日：1998-02-24
申请号：US876268
申请日：1992-05-05
申请人： Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
发明人： Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
IPC分类号： C08F4/60 , C07F17/00 , C08F4/42 , C08F4/64 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08F4/65908 , C08F4/6592
摘要： A process for preparing addition polymerization catalysts having a limiting charge separated structure corresponding to the formula: LMX.sup.+ XA.sup.-, wherein: L is a derivative of a substituted delocalized .pi.-bonded group imparting a constrained geometry to the metal active site and containing up to 50 nonhydrogen atoms; M is a metal of Group 4 or the Lanthanide series of the Periodic Table of the Elements; X independently each occurrence is hydride or a hydrocarbyl, silyl or germyl group having up to 20 carbon, silicon or germanium atoms; and A.sup.- is an anion of a Lewis acid, A, having relative Lewis acidity greater than or equal to that of phenylbis(perfluorophenyl)borane, said anion being compatible with the metal cation, the steps of the process comprising contacting a derivative of a Group 4 or Lanthanide metal corresponding to the formula: i LMX.sub.2, wherein L, M, and X are as previously defined, with the Lewis acid, A, under conditions to cause abstraction of X and formation of the anion XA.sup.-.
摘要翻译：一种制备具有对应于下列通式的极限电荷分离结构的加成聚合催化剂的方法：LMX + XA-，其中：L是取代的离域π键合基团的衍生物，其赋予金属活性位点约束几何形状， 50个非氢原子; M是第4族金属或元素周期表的镧系元素; 独立地，每次出现氢化物或具有至多20个碳，硅或锗原子的烃基，甲硅烷基或甲硅烷基; A是具有大于或等于苯基双（全氟苯基）硼烷的相对路易斯酸度的路易斯酸A的阴离子，所述阴离子与金属阳离子相容，所述方法的步骤包括使在引起X的抽出和形成阴离子XA-的条件下，与路易斯酸A相对应的式4或镧系金属，其中L，M和X如前所定义。

3. 发明授权

US5321106A Addition polymerization catalyst with oxidative activation 失效
标题翻译：添加聚合催化剂与氧化活化
公开(公告)号：US5321106A
公开(公告)日：1994-06-14
申请号：US896732
申请日：1992-06-09
申请人： Robert E. LaPointe
发明人： Robert E. LaPointe
IPC分类号： C08F4/44 , C07F7/08 , C07F7/28 , C07F17/00 , C08F4/12 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F4/82 , C08F10/00 , C08F4/00
CPC分类号： C08F10/00 , C07F17/00 , C07F7/082 , C07F7/28 , C08F4/61908 , C08F4/6192 , C08F4/65908 , C08F4/6592 , Y10S526/943
摘要： Addition polymerization catalysts comprising a derivative of a Group 4 or Lanthanide metal compound prepared by oxidative activation, a process for preparation and an addition polymerization method utilizing such catalysts.
摘要翻译：包含通过氧化活化制备的第4族或镧系元素金属化合物的衍生物的加成聚合催化剂，制备方法和使用这种催化剂的加成聚合方法。

4. 发明授权

US08633123B2 Catalysts and methods for polymer synthesis 有权
标题翻译：聚合物合成的催化剂和方法
公开(公告)号：US08633123B2
公开(公告)日：2014-01-21
申请号：US13059967
申请日：2009-08-24
申请人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
发明人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
IPC分类号： B01J31/00 , B01J37/00
CPC分类号： C07F15/065 , B01J31/0239 , B01J31/0259 , B01J31/0265 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2531/0238 , B01J2531/025 , B01J2531/0252 , B01J2531/0294 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07C251/24 , C07C279/12 , C07C2601/14 , C07D213/53 , C07D487/04 , C07D487/22 , C07F9/5355 , C07F9/6561 , C07F19/005 , C08F4/80 , C08G64/34
摘要： The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
摘要翻译：本发明提供了在二氧化碳和环氧化物的共聚中具有增加的活性的单分子金属络合物。还提供了在合成聚合物中使用这种金属络合物的方法。根据一个方面，本发明提供金属络合物，其包含与辅助配位体配位的辅助催化活性的活化物质，其与配合物的活性金属中心配位。

5. 发明授权

US08575245B2 Tunable polymer compositions 有权
标题翻译：可调聚合物组合物
公开(公告)号：US08575245B2
公开(公告)日：2013-11-05
申请号：US13141532
申请日：2009-12-18
申请人： Robert E. LaPointe , Scott D. Allen , Jeffrey R. Conuel
发明人： Robert E. LaPointe , Scott D. Allen , Jeffrey R. Conuel
IPC分类号： C08L69/00 , C08K5/3415 , C08K5/59 , C08K5/19
CPC分类号： C08G64/183 , C08G64/0208 , C08G64/34 , C08K5/19 , C08L69/00
摘要： The present invention provides polycarbonate compositions having a tunable decomposition temperature. Suitable cationic additives (e.g., phosphonium, phosphazene, quaternary ammonium, guanidinium, pyridinium, arsonium, etc.) are disclosed for lowering the decomposition temperature of polymer compositions. The invention further provides methods of preparing such polymer compositions with tunable decomposition temperatures.
摘要翻译：本发明提供具有可调分解温度的聚碳酸酯组合物。公开了适合的阳离子添加剂（例如鏻，磷腈，季铵，胍，吡啶鎓，ium等）以降低聚合物组合物的分解温度。本发明还提供了制备具有可调分解温度的聚合物组合物的方法。

6. 发明授权

US5744646A Preparation of tris (pentafluorophenyl) borane 失效
标题翻译：三（五氟苯基）硼烷的制备
公开(公告)号：US5744646A
公开(公告)日：1998-04-28
申请号：US832150
申请日：1997-04-02
申请人： David R. Wilson , Robert E. LaPointe
发明人： David R. Wilson , Robert E. LaPointe
IPC分类号： C07F5/02
CPC分类号： C07F5/027
摘要： A process for preparing tris(pentafluorophenyl)borane, the steps of the process comprising: a) forming a pentafluorophenyl metal compound wherein the metal is selected from Group 11 or 12; contacting the (pentafluorophenyl) metal compound from step a) with a boron halide compound to form tris (pentafluorophenyl)borane; and c) recovering the resulting tris(pentafluorophenyl)borane.
摘要翻译：一种制备三（五氟苯基）硼烷的方法，所述方法的步骤包括：a）形成其中金属选自11或12族的五氟苯基金属化合物; 使来自步骤a）的（五氟苯基）金属化合物与卤化硼化合物接触形成三（五氟苯基）硼烷; 和c）回收所得的三（五氟苯基）硼烷。

7. 发明授权

US06716786B1 Supported catalyst comprising expanded anions 失效
标题翻译：负载催化剂包括膨胀的阴离子
公开(公告)号：US06716786B1
公开(公告)日：2004-04-06
申请号：US09631654
申请日：2000-08-03
申请人： Richard E. Campbell, Jr. , Grant B. Jacobsen , David D. Devore , Robert E. LaPointe , David R. Neithamer
发明人： Richard E. Campbell, Jr. , Grant B. Jacobsen , David D. Devore , Robert E. LaPointe , David R. Neithamer
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F5/027 , C07F5/062 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F210/14 , C08F2500/08
摘要： A composition useful as an addition polymerization catalyst comprising: A) an inert support; B) a Group 3-10 or Lanthanide metal complex; and C) an activator compound capable of causing the metal complex B) to form an active polymerization catalyst, said compound corresponding to the formula: (A*+a)b(Z*J*j)−cd, (I) wherein: A* is a cation of charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base-site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
摘要翻译：可用作加成聚合催化剂的组合物，其包含：A）惰性载体; B）3-10族或镧系元素金属络合物; 和C）能够引起金属络合物B）形成活性聚合催化剂的活化剂化合物，所述化合物对应于下式：其中：A *为电荷阳离子，a *为1至50的阴离子基团，优选为1至30个原子，不计数氢原子，还含有两个或更多个路易斯碱基位点; J *独立地每次出现与至少一个路易斯碱碱基位点配位的路易斯酸，并且任选地两个或更多个这样的J *基团可以连接在具有多个路易斯酸性官能团的部分中，j是2至12的数，a，b，c和d为1至3的整数，条件是axb等于cxd。

8. 发明授权

US06703246B1 Thermal method and apparatus 失效
标题翻译：热法和仪器
公开(公告)号：US06703246B1
公开(公告)日：2004-03-09
申请号：US10018668
申请日：2001-12-12
申请人： Theodore E. Miller , Charles A. Nielsen , Ray W. Chrisman , Robert E. LaPointe
发明人： Theodore E. Miller , Charles A. Nielsen , Ray W. Chrisman , Robert E. LaPointe
IPC分类号： G01N2520
CPC分类号： G01N25/482 , G01N25/4873
摘要： A thermal method for studying chemical responses, such as catalyzed polymerization reactions that includes the following three steps. The first step is to flow a chemical substance through a conduit, the conduit being in thermal communication with an electrical conductor, the electrical conductor being co-linear with the conduit, the electrical resistance of the electrical conductor being a function of the temperature of the electrical conductor. A length of stainless steel tubing can be used as both the conduit and the conductor. The second step is to flow electricity through the electrical conductor during the first step. The third step is to measure the electrical resistance of the electrical conductor during the second step to determine any change in the temperature of the conduit caused by a response of the chemical substance. An apparatus for studying chemical reactions that includes: a first conduit, the first conduit being an electrical conductor, the first conduit having a first end and a second end, the electrical resistance of the first conduit being a function of the temperature of the first conduit; a source of electricity, the source of electricity in electrical communication with the first conduit so that electricity can be flowed through the first conduit; a volt meter in electrical communication with the first conduit so that the voltage measured by the volt meter is an indication of the temperature of the first conduit.
摘要翻译：用于研究化学反应的热法，例如催化聚合反应，其包括以下三个步骤。第一步是通过导管流出化学物质，导管与电导体热连通，电导体与导管共线，电导体的电阻是温度的函数电导体。一段不锈钢管可用作管道和导体。第二步是在第一步中通过电导体流动电力。第三步是测量在第二步骤期间电导体的电阻，以确定由化学物质的响应引起的导管温度的任何变化。一种用于研究化学反应的装置，包括：第一导管，第一导管是电导体，第一导管具有第一端和第二端，第一导管的电阻是第一导管的温度的函数 ; 电源，与第一导管电连通的电源，使得电能够通过第一导管流动; 与第一导管电连通的电压表，使得由电压表测量的电压是第一导管的温度的指示。

9. 发明授权

US06462156B2 Catalyst activators comprising expanded anions 有权
标题翻译：包含膨胀阴离子的催化剂活化剂
公开(公告)号：US06462156B2
公开(公告)日：2002-10-08
申请号：US10097395
申请日：2002-03-13
申请人： Robert E. LaPointe
发明人： Robert E. LaPointe
IPC分类号： B01J31100
CPC分类号： C07F5/062 , C07F5/027 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： Catalyst compositions comprising a group 4 metal complex and an activator corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of charge +a, selected from the group consisting of ammonium-, sulfonium-, phosphonium-, oxonium-, carbonium-, silylium-, ferrocenium-, Ag+, and Pb+2; Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites as defined in the claims; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
摘要翻译：催化剂组合物，其包含4族金属络合物和对应于下式的活化剂：其中：A *是电荷阳离子+ a，选自铵 - ，锍 - ，鏻 - ，氧鎓 - ，碳鎓 - ，甲硅烷基 - ，二茂铁 - ，Ag +和Pb + 2; Z *是1至50个原子的阴离子基团，不计算氢原子，还包含如权利要求中定义的两个或更多个路易斯碱基位点; J * 与Z *的至少一个Lewis碱基配位的路易斯酸和任选的两个或更多个这样的J *基团可以在具有多个路易斯酸官能团的部分中连接在一起，j是2至12的数，a，b，c ，d为1〜3的整数，条件是axb等于cxd。

10. 发明授权

US06395671B2 Catalyst activators comprising expanded anions 有权
标题翻译：包含膨胀阴离子的催化剂活化剂
公开(公告)号：US06395671B2
公开(公告)日：2002-05-28
申请号：US09823650
申请日：2001-04-02
申请人： Robert E. LaPointe
发明人： Robert E. LaPointe
IPC分类号： B01J3000
CPC分类号： C07F5/062 , C07F5/027 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： A compound useful as a catalyst activator corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of charge +a, Z* is an anion group of from 1 to 50 atoms not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
摘要翻译：对应于下式，可用作催化剂活化剂的化合物：其中：A *是电荷阳离子，a * Z是不计数氢原子的1至50个原子的阴离子基团，还含有两个或更多个路易斯碱基位点; J *各自独立地为与Z *的至少一个路易斯碱碱基配位的路易斯酸，并且任选地两个或更多个这样的J *基团可以在具有多个路易斯酸官能团的部分中连接在一起，j是从2到 12和a，b，c和d是1至3的整数，条件是axb等于cxd。

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