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    • 1. 发明授权
    • Catalyst activators comprising expanded anions
    • 包含膨胀阴离子的催化剂活化剂
    • US06462156B2
    • 2002-10-08
    • US10097395
    • 2002-03-13
    • Robert E. LaPointe
    • Robert E. LaPointe
    • B01J31100
    • C07F5/062C07F5/027C08F4/6592C08F4/65927C08F10/00C08F210/16Y10S526/943C08F4/65908C08F210/14C08F2500/12C08F2500/08
    • Catalyst compositions comprising a group 4 metal complex and an activator corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of charge +a, selected from the group consisting of ammonium-, sulfonium-, phosphonium-, oxonium-, carbonium-, silylium-, ferrocenium-, Ag+, and Pb+2; Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites as defined in the claims; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
    • 催化剂组合物,其包含4族金属络合物和对应于下式的活化剂:其中:A *是电荷阳离子+ a,选自铵 - ,锍 - ,鏻 - ,氧鎓 - ,碳鎓 - ,甲硅烷基 - ,二茂铁 - ,Ag +和Pb + 2; Z *是1至50个原子的阴离子基团,不计算氢原子,还包含如权利要求中定义的两个或更多个路易斯碱基位点; J * 与Z *的至少一个Lewis碱基配位的路易斯酸和任选的两个或更多个这样的J *基团可以在具有多个路易斯酸官能团的部分中连接在一起,j是2至12的数,a,b,c ,d为1〜3的整数,条件是axb等于cxd。